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Equilibrium structure of monomeric GaCl3 and InCl3 from combined analysis of gas electron diffraction and vibrational spectroscopic data

Abstract The equilibrium structures of monomeric gallium and indium trichloride have been determined in harmonic approximation by means of the combined analysis of gas electron diffraction intensities and vibrational frequencies. The molecules are planar and have r h e (M-Cl) distances of 2.100(3) and 2.275(3) for GaCl 3 and InCl 3 , respectively. Force constants are also obtained for both molecules.