{'fraction_non_alphanumeric': 0.031512605042016806, 'fraction_numerical': 0.01610644257703081, 'mean_word_length': 5.133047210300429, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 0, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
Fe2 N/S/N Codecorated Hierarchical Porous Carbon Nanosheets for Trifunctional Electrocatalysis.

Construction of multifunctional highly active earth-abundant electrocatalysts on a large scale is a great challenge due to poor control over nanostructural features and limited active sites. Here, a simple methodology to tailor metal-organic frameworks (MOFs) to extract highly active multifunctional electrocatalysts on a large scale for oxygen reduction (ORR), oxygen evolution (OER), and hydrogen evolution reaction (HER) is presented. The N, S codoped Fe2 N decorated highly porous and defect-rich carbon nanosheets are grown using MOF xerogels, melamine, and polyvinylpyrollidone. The resulting catalyst exhibits excellent activity for ORR with an onset (0.92 V) and half-wave (0.81 V) potential similar to state-of-the-art Pt/C catalysts. The catalyst also shows outstanding OER and HER activities with a small overpotential of 360 mV in 1 m KOH and -123 mV in 0.5 m H2 SO4 at a current density of 10 mA cm-2 , respectively. Excellent catalytic properties are further supported by theoretical calculations where relevant models are built and various possible activation sites are identified by first-principles calculations. The results suggest that the carbon atoms adjacent to heteroatoms as well as Fe2 -N sites present the active sites for improved catalytic response, which is in agreement with the experimental results.