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Calculating the Dissociation Constant of Weak Electrolytes by Measuring the Conductivity

In chemistry and biochemistry, a dissociation constant is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, such as when a complex falls apart into its component molecules or when a salt splits up into its component ions. Dissociation constants play an important role in reactions and chemical kinetics. This paper studies dissociation constant calculations and the chemical kinetic determination of weak electrolytes by measuring conductivity. The study is illustrated by hexamine production. Hexamine (C6H|2N4) was produced from aqueous ammonia hydroxide (NH4OH) and aqueous formaldehyde (CH2O) in a batch reactor, at different temperatures. The reaction was observed by measuring a weak electrolyte's conductivity, in our case, ammonia hydroxide. The dissociation constant, concentration, and kinetic parameters of the ammonia hydroxide's reaction (reaction rate constant, rate order, and activation energy) were determined. The dissociation constant of formaldehyde and ammonia hydroxide was determined using experimental parameters.