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Anionic Effect on Enhancing the Stability of a Solid Electrolyte Interphase Film for Lithium Deposition on Graphite.

Graphitic carbons and their lithium composites have been utilized as lithium deposition substrates to address issues such as the huge volume variation and dendritic growth of lithium. However, new problems have appeared, including the severe exfoliation of the graphite particles and the instability of the solid electrolyte interphase (SEI) film when metallic lithium is plated on the graphite. Herein, we enhance the stability of the SEI film on the graphite substrate for lithium deposition in an electrolyte of lithium bis(fluorosulfonyl)imide (LiFSI) dissolved in the carbonate solvent, thereby improving the lithium plating/stripping cycle on it. The FSI- anion was found to be responsible for the formation of a compact SEI film under the lithium plating potential and could protect the graphite substrate. These findings refresh the understanding of the SEI stability and provide a suggestion on the design and development of electrolytes for the lithium batteries.