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Halogen ions modified Ag NPs for ultrasensitive SERS detection of Polycyclic aromatic hydrocarbons.

Rapid ultrasensitive detection of trace polycyclic aromatic hydrocarbons (PAHs) is essential and significant for pollution control due to their hazard, persistence, and the wide distribution in the environment. Therefore, rapid detection of PAHs is critical for controlling pollution and protecting the ecology. Considering the advantages of Surface-enhanced Raman spectroscopy (SERS), a simple and reliable SERS method was proposed for detecting PAHs in water in this work. Three chemicals, namely NaCl, KBr, and KI, were chosen to modify Ag NPs for phenanthrene (Phe) detection, and Ag NPs modified with KBr (Ag-BrNPs) show the best SERS response. The mixing sequence and the concentration of KBr were optimized. The addition order of mixing KBr and Ag NPs before Phe solution is best, and the optimal concentration of KBr was 20 mM. Under the optimal condition, the limit of quantification for Phe, pyrene (Pyr), and anthracene (Ant) were 10-6 M, 10-7 M, and 10-7 M, respectively. Mixed PAHs (Phe, Pyr, and Ant) in spiked water samples have been identified and quantified successfully. The proposed method has good application prospects in environmental pollution monitoring.