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Bhatia-Young Model Calculations of the Thermodynamic Properties of TKEBS-Based Binary Liquid Mixtures

Abstract The simplified random phase approximation Bhatia-Young model has been used to evaluate the properties of mixing and the concentration fluctuations of the binary liquid mixtures of TKEBS with cyclohcxane. carbon tetrachloride and benzene. At this level of description the details of the potentials are not important; only the values of the long-wavelength limit of the average effective ordering pair potential and its temperature derivative are required. In the three mixtures the constituent molecules are assumed to be globular in shape.