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Observation of Strong J-Aggregate Light Emission in Monolayer Molecular Crystal on Hexagonal Boron Nitride.

J-aggregates are widely used in studies of light-matter interaction and organic optoelectronic devices. Although J-aggregates film can be fabricated on salt by epitaxial growth method, the size is limited on hundreds nanometer. In this work, with hexagonal boron nitride (h-BN) as substrate, highly crystalline J-aggregate ultrathin films of N, N'-ditridecylperylene 3,4,9,10-tetracarboxylic diimide (PTCDI-C13) are achieved by physical vapor transport method. Significant bathochromically shifted absorption band and narrowed 0-0 transition are observed in the monolayer PTCDI-C13 crystal on h-BN. The exciton coherence number Ncoh of monolayer J-aggregate film extracted from the photoluminescence spectrum is up to 15 at T = 140 K, which is higher than that of the epitaxially grown layer on salt. Beyond the first molecular layer, the multilayer crystal on h-BN is dominated by H-aggregates. Further study shows that that the first molecular layer on h-BN adopts the highly ordered face-on configuration, while the overlayers adopt the edge-on motif. As a comparison, only H-aggregate PTCDI-C13 ultrathin films are found on SiO2 substrates, but no J-aggregates. The results suggest that high quality J-aggregates can be prepared by utilizing appropriate substrates via physical vapor transport.