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Differential capacitance of the Ga subgroup metals caused by reorientation of solvent molecules on the metal surfaces and its dependence on the charge

By the example of the Ga metals in water, dimethyl sulfoxide, and dimethylformamide, the nature of the influence exerted by the electrode charge σ on the differential capacitance C M s,0 , which is due to reorientation of solvent molecules on the electrode surface caused by specific interaction of the molecules with metals, is analyzed. The absolute value of C M s,0 as a function of σ is shown to pass through a minimum in each solvent. The charge that correspond to |(C M s,0 ) σmax | can be adopted as a measure of the metal lyophilicity. The preferential orientation of the solvents studied at the Ga metals is determined at σ=0