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Experimental and Scale Analysis of a Solid/Liquid Phase Change Thermal Energy Storage System

ABSTRACT A detailed experimental study has been carried out to evaluate the heat transfer performance of a solid/liquid phase-change thermal energy storage system. The phase-change material, 99% pure eicosane with a melting temperature of 36.5°C, was contained in a vertically oriented test cylinder that was cooled or heated at its outside boundary, resulting in radially inward freezing or melting, respectively. Detailed quantitative time-dependent temperature distributions and melt-front motion and shape data were obtained. In the freezing case study, a mathematical model was developed based on a one-dimensional analysis, which considered heat conduction as the only mode of heat transfer. In the melting case study, a heat transfer scale analysis was used to help interpret the data and development of heat transfer correlations. In the melting scale analysis, conduction heat transfer in the solid and natural convection heat transfer in liquid were considered. Comparison of experimental data with scale analysis predictions of the solid-liquid interface position and temperature distribution was performed. The analytical results agreed, in the worst case, within 10% of the experimental results in both melting and freezing cases. In the case of melting, scale analysis results agreed within 5% (after initial superheat disappeared in 50 minutes) with experimental results, and experimental results confirm the existence of four melting regions.