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A New Destruxin as Inhibitor of Vacuolar‐Type H+‐ATPase of Saccharomyces cerevisiae

In the course of our screening efforts to discover small molecules as selective inhibitors of vacuolar‐type H+‐ATPase of Saccharomyces cerevisiae, we have identified eight active destruxins, 1–8, from the fungus Metarhizium anisopliae. The structures were elucidated by extensive 1D‐ and 2D‐NMR spectroscopy, and MS spectrometry. One of these compounds, 8, a regioisomer of chlorohydrin destruxin E (7), is a new destruxin.