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Electron-Rich π-Extended Diindolotriazatruxene-Based Chemosensors with Highly Selective and Rapid Responses to Nitroaromatic Explosives.

A series of electron-rich π-extended diindolotriazatruxene-based compounds DIT, 4Py-DIT (bearing pyrene units) and 4PyF-DIT (bearing fluorene units) have been explored and investigated as fluorescence chemosensors. Quantitative analysis through fluorescence titrations showed that the resulting DIT molecules exhibited highly selective response to electron-deficient nitroaromatic explosives. The calculated Stern-Volmer quenching constants (>4.0×103  M-1 ) revealed that these sensors were much more sensitive in solution compared to most of the existing small-molecule fluorescence chemosensors based on pyrene, triphenylene, triphenylamine, and triazatruxene skeletons. Fluorescence quenching showed that the sensors adsorbed on paper were sensitive to explosives in the solid, solution, and vapor phases, with fast response times of about 10 s. Moreover, these chemosensors are reusable for the detection of nitroaromatic compounds as they recover their fluorescence intensity after quenching.