{'fraction_non_alphanumeric': 0.04041720990873533, 'fraction_numerical': 0.028683181225554105, 'mean_word_length': 5.4, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 0, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
An ultra-stable hafnium phosphonate MOF platform for comparing the proton conductivity of various guest molecules/ions.

A porous hafnium-phosphonate MOF was synthesized using imidazole ionic liquids (ILs), namely PHOS-100(Hf), which has exceptional chemical stability in aqueous environments, even fuming acids. Its rigid framework with permanent porosity makes PHOS-100 an ideal candidate as a platform to fill with different functional guests such as acidic HCl, H2SO4, or H3PO4. The as-synthesized ILs@PHOS-100 exhibits significant humidity-dependent proton conductivities, increasing by four orders of magnitude from 45% RH to 95% RH at 25 °C. After post-treatment with strong acids, the acids@PHOS-100 show enhanced proton conduction at low relative humidities.