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A STUDY OF CHEMILUMINESCENCE FROM REACTIONS OF PEROXYOXALATE ESTERS, HYDROGEN PEROXIDE, AND 7-AMINO-4-TRIFLUOROMETHYLCUMARIN

The chemiluminescence arising from the reaction of bis(2,4,6-trichlorophenyl)oxalate (TCPO) and bis(2,4-dinitrophenyl)oxalate (DNPO) with hydrogen peroxide in the presence of 7-amino-4-trifluromethylcumarin (ATFMC) have been studied. The influences of stirring solution, nature of peroxyoxalate and solvent properties on the resulting chemiluminescence were investigated. The relationship between the chemiluminescence intensity and concentrations of TCPO and ATFMC are reported.