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Molar Volume of Fcc Phase in the Ni-Cr-Mo System

The molar volume of fcc phase in the Ni-Cr-Mo system has been evaluated by means of the CALPHAD approach based on experimental data from the literature. The molar volumes of the non-stable fcc Cr and Mo were determined by extrapolating volume data from several stable solid solutions combined with the first-principles calculation results. A set of parameters has been obtained and can give a reasonable description of most experimental data on molar volume.