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The puzzle of the nematic-isotropic phase transition

The low value of , where is the nematic-isotropic phase transition temperature and denotes the virtual transition temperature, is a long-standing puzzle in the physics of liquid crystals. The present review presents experimental and theoretical results on this long-standing problem. New experimental and theoretical results for the critical behaviour in the isotropic phase of nematogens are reviewed. We calculate in a unified approach the low value of , at both critical and tricritical points. The possibility of tricritical behaviour at the nematic-isotropic transition is also discussed by means of Landau theory. The various predictions are compared with the available experimental results.