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Oscillations and chaos in CO+O(2) combustion.

The gas-phase reaction between carbon monoxide and oxygen (in the presence of small amounts of hydrogen) shows bistability and oscillatory behavior. Typically, the oscillatory ignition has a period-1 relaxation waveform. The limit cycle is born at a saddle-node loop and terminates via a supercritical Hopf bifurcation. For a mean residence time of 8 s there is a period-doubling to a period-2 solution followed by period-halving to quasisinusoidal period-1 oscillations. At longer residence times, more period-doublings forming a full cascade to chaos with subsequent periodic windows are observed. The chaotic attractor has an underlying single-humped next maximum map.