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Dependence of the configurational entropy on amorphous structures of a hard-sphere fluid.

The free energy of a hard-sphere fluid for which the average energy is trivial signifies how its entropy changes with packing. The packing η_{f} at which the free energy of the crystalline state becomes lower than that of the disordered fluid state marks the freezing point. For packing fractions η>η_{f} of the hard-sphere fluid, we use the modified weighted density functional approximation to identify metastable free energy minima intermediate between uniform fluid and crystalline states. The distribution of the sharply localized density profiles, i.e., the inhomogeneous density field ρ(x) characterizing the metastable state is primarily described by a pair function g_{s}(η/η_{0}). η_{0} is a structural parameter such that for η=η_{0} the pair function is identical to that for the Bernal random structure. The configurational entropy S_{c} of the metastable hard-sphere fluid is calculated by subtracting the corresponding vibrational entropy from the total entropy. The extrapolated S_{c} vanishes as η→η_{K} and η_{K} is in agreement with other works. The dependence of η_{K} on the structural parameter η_{0} is obtained.