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Rapid I-/I3 - diffusion in a molecular-plastic-crystal electrolyte for potential application in solid-state photoelectrochemical cells.

High current-carrying capacity and rapid, liquidlike diffusion were achieved in a dye-sensitized solar cell (DSSC) based on the plastic-crystalline electrolyte succinonitrile and the I − /I 3 − redox couple (see diagram). This could lead to the development of true solid-state DSSCs without conventional organic-liquid electrolytes, which can cause problems with long-term device stability.