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The influence of silicon on hyperfine magnetic fields in Zr(Fe1-xSix)2 measured for x<or=0.17 by Mossbauer spectroscopy

Mossbauer (57Fe) spectroscopy has been used to study the Laves phase compounds Zr(Fe1-xSix)2 for x<or=0.17. It has been found that the mean values of the hyperfine magnetic field, isomer shift and quadrupole splitting decrease with increasing Si concentration. The dependence of the hyperfine magnetic field on the number of Si atoms as nearest and next-nearest neighbours of 57Fe has been established.