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Optical absorption spectra of Ag8 and Ag20 in solid neon

Ag8+ and Ag20+ have been produced by sputtering, mass selected in a quadrupole mass filter and deposited at 30 eV landing energies together with neon on a 5 K sapphire surface. The cluster ions are neutralized during the deposition process. In contrast to the other rare gases (Xe, Kr, Ar) no fragmentation has been detected. The absorption spectra show results very similar to the system Agn/Ar but are better resolved in the case for Ag8. The spectra are compared to gas phase photodepletion data and Nan.