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Investigation of Electrochemical Nanostructuring with Ultrashort Pulses by Using Nanoscale Electrode



 Electrochemical machining (ECM) is a non-traditional machining method
for the metal material based on the principle of anode electrochemical dissolution which has been
used in micro/nano fabrication with advantages as not influenced by materials intensity and hardness,
no residual stress and no heat treatment born on the surface of the workpiece. Several researches and
applications have shown that the surface quality can be improved effectively during the electrochemical
machining by using ultrashort pulse power supply.



 This paper presents a potential of electrochemical machining at the nanometer scale. First, a
transient charging double layer mathematical model is developed to describe electrochemical
nanostructuring of metallic materials with ultrashort (nanosecond) voltage pulses. And then, by using
finite element method (FEM), the analysis model of electrochemical interface between poles is established
to give a more realistic analysis of the comparison of transient currents at different separations
between the tool and workpiece. Second, a nanoscale electrode is an essential tool in electrochemical
nanostructuring. In this paper, electrodes with diameters of several ten to hundred nanometers are
successfully prepared by the liquid membrane electrochemical etching. Finally, by using the nanometer
scale electrodes above and the ultrashort pulse power supply, several nanostructures with
physical dimension of several hundred nanometers are fabricated on nickelbased superalloys.



 Using the optimal machining parameters, a tool electrode with 230 nm in diameter is obtained
from the initial tungsten rod radius of 100 μm. By using 0.05 M H2SO4 solution, the pulse
generator with 1μs in period, 100 ns in pulse on-time and 4 V in voltage, a micro/nano groove with
the depth of 150 nm and maximum entrance width of 3 μm is obtained.




 Nanoscale electrodes with diameters of several ten to hundred nanometers is obtained
successfully demonstrating that the liquid membrane electrochemical etching is a very effective
method to fabricate nanoscale electrode. Several nanostructures with physical dimension of several
hundred nanometers can be fabricated successfully demonstrating that ECM with ultrashort pulses is
a highly promising nanostructuring technology.