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The Reaction of NH2+O2 at High Temperatures

The reaction of NH 2 + O 2 was investigated behind incident shock waves in the temperature range of 1450-2300 K at densities between 2.10 −6 to 5.10 −6 mol cm −3 . The rate constant of the reaction of NH 2 + O 2 forming products was determined by following the decay of NH 2 concentration using laser absorption to be κ 1 = (2.2 ± 0.5).10 14 exp (−(105 ± 10) kJ mol −1 R T) cm 3 /mol s. Investigations of the possible radical products (NH, OH, O and H) showed that the contribution of the radical forming channels in the overall reaction is less than 15%. The channel leading to NO + H 2 O is expect to be the main reaction path