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Electrochemical Synthesis of M:DNA Nanohybrids

Metal - DNA (M:DNA) nanohybrids have shown promise as functional nanomaterials in several practical applications. In this paper, electrochemical synthesis of metal - DNA nanohybrids is explored. First, metal ions (M n+ ) are attached to the sugar - phosphate backbone of calf thymus DNA. The metal - ion doped DNA (M n+ :DNA) is then deposited on a substrate by layer-by-layer deposition, drop casting or electrostatic deposition. This is followed by electrocherical reduction of the metal ion to form M: DNA. Ag + :DNA/Ag:DNA is chosen as a model system to perform in-depth study. Future directions for this work are also provided.