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Photofragment Imaging of Carbon Cluster Cations: Explosive Ring Rupture.

Carbon cluster cations (Cn+) produced by laser vaporization are mass selected and photodissociated at 355 nm. Multiphoton dissociation of smaller ions leads to the elimination of neutral C3, as in previous work, whereas larger clusters exhibit more varied fragmentation channels. Photofragment velocity-map imaging detects significant kinetic energy release (KER) in the various n - 3 cation fragments. Small cations (n = 6 or 7) with linear structures produce moderate KER, whereas larger cations (n = 10, 11, 12, 15, or 20) having monocyclic ring structures produce much higher KER values. Such high KER values are unanticipated, as optical excitation should produce a wide distribution of internal energies. These carbon clusters have a surprising ability to absorb multiple photons of ultraviolet radiation, achieving a state of extreme excitation prior to dissociation. The remarkable nonstatistical distribution of energy is apparently influenced by the significant ring strain that can be released upon photodissociation.