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Isothermal Membrane Phenomena in Ionic Melts

We develop the formulae for the dissipation function and the linear phenomenological laws for isothermal membrane processes in ionic melts containing two components and three ion constituents. We only use measurable quantities. In particular, we discuss the internal transport numbers and the expression for the electric potential difference in terms of the electric current and of the pressure and composition differences. Saxén's relation for electroosmosis and the equations for the electromotive force of membrane concentration cells are special cases of the last expression. On the whole, the formulae for ionic melts are more complex than those for electrolyte solutions.