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Dielectric relaxation of a new metal containing films of poly-[CumSalpn-1.3]

Thus, the results presented allow the conclusion that the dielectric behavior of the studied polymer complexes is closely related to their molecular and electronic structures. The behavior of dielectric spectra reflects intermolecular interactions between individual structural units, involving the metal center, and the azomethine C=N group. When the poly[CumSalpn] films are polarized by applying electric bias at low frequencies of the measuring field, the frequency dispersion of dielectric parameters and conductivity in an alternating electric field is clearly defined. The obtained data can be useful for the choice of the monomer architecture in order to obtain a supramolecular metal-containing polymer with the optimum electrical properties.