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Models for Conductance Measurements in Quality Assurance of Water Analysis

Models for the prediction of conductance in nonbrine water samples through the measurement of ionic concentrations and other parameters are compared. Such predictions are often used for quality assurance purposes by comparing them with actual measurements to determine whether gross analysis errors have been made. A currently recommended method for making such predictions is a semiempirical relaxation that adapts the Debye-Huckel-Onsager equation to mixed electrolyte systems by incorporation. The limitations of this model are examined, and extensions to it are considered