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Inner 4d-subshell photoabsorption spectrum of Sb I

Several strong features have been observed in the 450-250 aa wavelength region of the photoabsorption spectrum of neutral antimony. On the basis of the Hartree-Fock and least-square-fitted calculations they were ascribed to electronic excitation from the inner 4d subshell to outer 5s25p3np orbitals, followed by photoionisation. Seventeen lines were assigned to the 5s25p3-4d95s25p4 transition array and 16 lines to the 5s25p3-4d95s25p3np (n)5) transition array. The ionisation limit has been estimated at 324000+or-500 cm-1 (40.16+or-0.01 eV). The attribution of five observed transitions to two other core-excited configurations has been proposed.