{'fraction_non_alphanumeric': 0.0367504835589942, 'fraction_numerical': 0.01644100580270793, 'mean_word_length': 5.46875, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 0, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
One-step preparation of sulfur-doped porous g-C3N4 for enhanced visible light photocatalytic performance.

Nonmetal doping is a convenient method to adjust the visible light photocatalytic activity of graphitic carbon nitride (g-C3N4). Herein, highly active sulfur-doped porous g-C3N4 (C3N4-S) was successfully prepared by one-step calcination using thiourea and melamine as the precursors. C3N4-S exhibited excellent photocatalytic performance for the degradation of Rhodamine B (RhB) under visible light irradiation. C3N4-S not only promoted the separation of photogenerated electron-hole pairs, but also enhanced electron transfer, resulting in a great improvement in the photocatalytic efficiency. Based on capture experiments and DMPO spin-trapping ESR spectra, the superoxide radical (˙O2-) was proved to be the predominant active species and the possible photocatalytic mechanism of C3N4-S was proposed. The photocatalytic mechanism of RhB degradation over C3N4-S was further explored using high-resolution mass spectra (HRMS).