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Crossover from tricritical to critical end point behavior in free-standing smectic films.

We study the smectic to nematic (SmA-N) phase transition taking place at the center of a free-standing film that exhibits enhanced surface order due to the anchoring promoted by a surrounding gas. The usual McMillan mean-field approach predicts that the SmA-N transition in bulk samples can be continuous or discontinuous (first or second order) depending on the molecular geometry, with a tricritical point separating these two regimes. Here we show that the additional orientational order imposed by the surface anchoring stabilizes the surface-induced smectic and nematic phases, leading to the breakdown of the tricritical point and to the emergence of a critical end point. We report the full phase diagram, which depicts four distinct structures as the film thickness is reduced.