{'fraction_non_alphanumeric': 0.04938271604938271, 'fraction_numerical': 0.003527336860670194, 'mean_word_length': 5.241758241758242, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 0, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
Palladium-Catalyzed Regioselective Diarylation of o-Carboranes By Direct Cage B-H Activation.

Palladium-catalyzed intermolecular coupling of o-carborane with aromatics by direct cage B-H bond activation has been achieved, leading to the synthesis of a series of cage B(4,5)-diarylated-o-carboranes in high yields with excellent regioselectivity. Traceless directing group -COOH plays a crucial role for site- and di-selectivity of such intermolecular coupling reaction. A Pd(II)-Pd(IV)-Pd(II) catalytic cycle is proposed to be responsible for the stepwise arylation.