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Propagation behaviour of general and localised corrosion of carbon steel in simulated groundwater under aerobic conditions

Abstract Carbon steel is one of the candidate overpack materials for geological disposal of high-level radioactive waste in Japan. Corrosion of carbon steel is classified into two types: general corrosion and localised corrosion. In this study, propagation of general and localised corrosion (pitting corrosion and crevice corrosion) were investigated by immersion tests of carbon steel under the aerobic conditions. The results of the immersion tests showed that the corrosion growth rate was strongly dependent on the environmental conditions and type of steel. However, the upper limit of the pitting factor, the ratio between the maximum corrosion depth and the average corrosion depth, was determined approximately using only average corrosion depth. Based on the experimental and literature data, an empirical model that predicts the maximum corrosion depth of an overpack from average corrosion depth was developed by applying the extreme value statistical analysis using the Gumbel distribution function.