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Exact solution of the spin-s Heisenberg chain with generic non-diagonal boundaries

The off-diagonal Bethe ansatz method is generalized to the high spin integrable systems associated with the su(2) algebra by employing the spin-s isotropic Heisenberg chain model with generic integrable boundaries as an example. With the fusion techniques, certain closed operator identities for constructing the functional T-Q relations and the Bethe ansatz equations are derived. It is found that a variety of inhomogeneous T-Q relations obeying the operator product identities can be constructed. Numerical results for two-site s=1 case indicate that an arbitrary choice of the derived T-Q relations is enough to give the complete spectrum of the transfer matrix.


Introduction
Among integrable quantum spin chains, the su(2)-invariant spin-s Heisenberg chain is particularly interesting due to its relationship to the Wess-Zumino-Novikov-Witten (WZNW) models [1,2,3,4] and lower dimensional super-symmetric quantum field theories [5] such as the super-symmetric sine-Gordon model [6], the fractional statistics [7] and the multichannel Kondo problem [8,9,10] when it couples to an impurity spin. The s = 1 integrable spin chain model was firstly proposed by Zamalodchikov and Fateev [11]. Its generalization to arbitrary s cases was subsequently constructed via the fusion techniques [12] based on the fundamental s = 1 2 representations of the Yang-Baxter equation [13,14]. Those observations allow one to diagonalize the models with periodic boundary conditions in the framework of algebraic Bethe ansatz method (for example, see [15]). On the other hand, the discovery of the boundary Yang-Baxter equation or the reflection equation [16,17] directly stimulated the studies on the exact solutions of the quantum integrable models with boundary fields.
However, in a long period of time, the Bethe ansatz solutions could only be obtained for either constrained boundary parameters [20] or special crossing parameters [21] associated with spin- 1 2 chains or with spin-s chains [33,34,35,36]. Recently, based on the fundamental properties of the R-matrix and the K-matrices for quantum integrable models, a systematic method for solving the eigenvalue problem of integrable models with generic boundary conditions, i.e., the off-diagonal Bethe ansatz (ODBA) method was proposed in [37] and several long-standing models [37,38,39] were then solved.
Subsequently, the nested-version of ODBA for the models associated with su(n) algebra [40], the application to the integrable models beyond A-type [41] and the thermodynamic analysis based on the ODBA solutions [42] were developed. We remark that two other promising methods, namely, the q-Onsager algebra method [43] and the separation of variables (SoV) method [31,44] were also used to approach the spin- 1 2 chains with generic integrable boundaries. Especially, the eigenstate problem for such kind of models with generic inhomogeneity was first approached via the SoV method [31]. A set of Bethe states for was then constructed in [45] and a method for retrieving the Bethe states based on the inhomogeneous T − Q re-lation [37] and the SoV basis [31] was developed in [46]. The latter method allows one to reach the homogeneous limit of the SoV eigenstates 3 and provides a clear connection among the SoV approach, the algebraic Bethe Ansatz and the ODBA.
The high spin models with periodic [11,12,15] and diagonal [47,48,49] boundaries have been extensively studied. Even the most general integrable boundary condition (corresponding to the non-diagonal reflection matrix) for the spin-1 model has been known for many years [50], the exact solutions of the models with non-diagonal boundaries were known only for some special cases such as the boundary parameters obeying some constraint [33] or the crossing parameter taking some special value (e.g., roots of unity) [34,35]. In this paper, we show that the ODBA method can also be applied to the su(2)-invariant spin-s chain with generic crossing parameter and generic integrable boundaries 4 . The outline of the paper is the following: Section 2 serves as an introduction to some notations and the fusion procedure. In Section 3, after briefly reviewing the fusion hierarchy [33] of the high spin transfer matrices we derive certain closed operator product identities for the fundamental spin-( 1 2 , s) transfer matrix by using some intrinsic properties of the high spin R-matrix (R (s,s) (u)) and K-matrices (K ±(s) (u)). The asymptotic behavior of the transfer matrix is also obtained. Section 4 is devoted to the construction of the inhomogeneous T − Q relations and the corresponding Bethe ansatz equations (BAEs). Taking the spin-1 XXX chain as an example, we present numerical results for the model with some small number of sites, which indicate that an arbitrary choice of the derived T − Q relations is enough to give the complete set of spectrum of the transfer matrix. In section 5, we summarize our results and give some discussions. In Appendix A, we prove that each solution of our functional equations can be parameterized in terms of a variety of inhomogeneous T − Q relations and therefore that different T − Q relations only indicate different parameterizations but not new solutions. 3 It should be emphasized that the Bethe-type eigenstates of the spin-1 2 XXX chain with generic boundaries had challenged for many years and were conjectured in [45] and derived in [46] very recently after the discovery of the inhomogeneous T − Q relation in [37]. Only together with the very inhomogeneous T − Q relation, the SoV state [31] might be transformed into a Bethe state which possesses a well-defined homogeneous limit. 4 A hierarchy procedure for the isotropic open chain constructed with higher dimensional auxiliary spaces and each of its N quantum spaces are all spin-1 2 (i.e., two-dimensional) was proposed in [51].
2 Transfer matrices for the spin-s XXX spin chain 2.1 Fusion of the R-matrices and the K-matrices The R-matrix satisfies the following quantum Yang-Baxter equation (QYBE) [13,14] R (l 1 ,l 2 ) 12 Here and below we adopt the standard notations: for any matrix A ∈ End(V ), A j is an embedding operator in the tensor space V ⊗ V ⊗ · · ·, which acts as A on the j-th space and as identity on the other factor spaces; R ij (u) is an embedding operator of R-matrix in the tensor space, which acts as identity on the factor spaces except for the i-th and j-th ones.
12 (u) defined in spin-1 2 (i.e., two-dimensional) auxiliary space and spin-s (i.e., (2s + 1)-dimensional) quantum space is given by [12] R ( 1 2 ,s) where η is the crossing parameter, σ are the Pauli matrices and S are the spin-s realization of the su(2) generators. For the simplest case, i.e., s = 1 2 case the corresponding R-matrix reads Besides the QYBE (2.1), the R-matrix (2.3) also enjoys the following properties, Unitary relation : R Crossing relation : R PT-symmetry : R Fusion conditions : R (u)P 12 with P 12 being the permutation operator and t i denotes transposition in the i-th space. Using the fusion procedure [12] the spin-( 1 2 , s) R-matrix R ( 1 2 ,s) 12 (u) can be obtained by the symmetric fusion of the spin- where P + {1···2s} is the symmetric projector given by (2.10) Similarly, from the spin-( 1 2 , s) R-matrix we can also extend the auxiliary space from 1 2 to j to obtain the spin-(j, s) R-matrix by the symmetric fusion We remark that the R-matrices in the products (2.11) and (2.9) are in the order of increasing k. One can demonstrate that the fused R-matrices (2.2) and (2.9) also satisfy the associated QYBE (2.1) with the help of (2.8). Direct calculation shows that the spin-(s, s) R-matrix can be given by [12] where P (l) is a projector acting on the tensor product of two spin-s spaces and projects the tensor space into the irreducible subspace of spin-l (i.e., (2l + 1)-dimensional subspace).
In particular, the fundamental spin-( 1 2 , s) and the fused spin-(s, s) R-matrix possess the following important properties  The projector P (0) projects the tensor product of two spin-s spaces to the singlet space, namely, Having defined the fused-R matrices, one can analogously construct the fused-K matrices by using the methods developed in [47,52] as follows. The fused K − matrices (e.g the spin-j In this paper we adopt the most general non-diagonal spin- where p − and α − are some boundary parameters. It is noted that the products of braces {a} (u) matrices satisfy the following reflection equation [16,33] R (j,s) The fused dual reflection matrices K +(j) [17] are given by Particularly, the fundamental one K +( 1 2 ) (u) is where p + and α + are some boundary parameters.

Fused transfer matrices
In a similar way to that developed by Sklyanin [17] for the spin-1 2 case, one can construct a transfer matrix t (j,s) (u) whose auxiliary space is spin-j ((2j + 1)-dimensional) and each of its N quantum spaces are spin-s ((2s + 1)-dimensional) following the method in [33], for any j, s ∈ { 1 2 , 1, 3 2 , . . .}. The fused transfer matrix t (j,s) (u) can be constructed by the fused R-matrices and K-matrices as follows [17,33] {a} (u) are the fused one-row monodromy matrices given by Here {θ j |j = 1, . . . , N} are arbitrary free complex parameters which are usually called the inhomogeneous parameters. The QYBE (2.1), the reflection equation (2.19) and its dual version lead to that these transfer matrices with different spectral parameters are mutually Therefore t (j,s) (u) serve as the generating functionals of the conserved quantities.
3 Fusion hierarchy and operator identities

Operator identities
Let us fix an s ∈ { 1 2 , 1, 3 2 , . . .}, i.e., each of the N quantum spaces is described by a spin S ((2s + 1)-dimensional). The fused transfer matrices {t (j,s) (u)} given by (2.23) obey the following fusion hierarchy relation [47,52,33] where we have used the convention t (0,s) = id. The coefficient function δ (s) (u) related to the quantum determinant is given by Using the recursive relation (3.1), we can express the fused transfer matrix t (j,s) (u) in terms of the fundamental one t ( 1 2 ,s) (u) with a 2j-order functional relation as follows: For example, the first three fused transfer matrices are given by Keeping the very properties (2.13)-(2.15) in mind and following the method developed in [40,41], after a tedious calculation, we find that the spin-(s, s) transfer matrix satisfies the following operator identities, 6 The R-matrix (2.2) and the K-matrices (2.18) and (2.22) imply that the transfer matrix t ( 1 2 ,s) (u) possesses the following properties: The analyticities of the spin-( 1 2 , s) R-matrix and spin-1 2 K-matrices and the property (3.9) imply that the transfer matrix t ( 1 2 ,s) (u), as a function of u, is a polynomial of degree 2N + 2. The fusion hierarchy relation (3.1) gives rise to that all the other fused transfer matrix t (j,s) (u) can be expressed in terms of t ( 1 2 ,s) (u) (see (3.3)). Therefore, the very operator identities (3.7) lead to N constraints on the fundamental transfer matrix t ( 1 2 ,s) (u). Thus the relations (3.7) and (3.8)-(3.10) are believed to completely characterize the eigenvalues of the fundamental transfer matrix t ( 1 2 ,s) (u) (as a consequence, also determine the eigenvalues of all the transfer matrices {t (j,s) (u)}).

Functional relations of the eigenvalues
The commutativity (2.25) of the fused transfer matrices {t (j,s) (u)} with different spectral parameters implies that they have common eigenstates. Let |Ψ be a common eigenstate of these fused transfer matrices with the eigenvalues Λ (j,s) (u) t (j,s) (u)|Ψ = Λ (j,s) (u)|Ψ . (3.11) The fusion hierarchy relation (3.1) of the fused transfer matrices allows one to express all the eigenvalues Λ (j,s) (u) in terms of the fundamental one Λ ( 1 2 ,s) (u) by the following recursive Here Λ (0,s) (u) = 1 and the coefficient function δ (s) (u) is given by (3.2). The very operator identities (3.7) imply that the eigenvalue Λ (s,s) (u) satisfies the same relations 7 The properties of the transfer matrix t ( 1 2 ,s) (u) given by (3.8)-(3.10) give rise to that the corresponding eigenvalue Λ ( 1 2 ,s) (u) satisfies the following relations 14)  [37] to determine the spectrum of the corresponding transfer matrix. The eigenstates associated with each solution of the resulting relations were constructed in [31] in the framework of the SoV method. In such a sense, each solution corresponds to a correct eigenvalue of the transfer matrix. Since all the eigenvalues of the transfer matrix belong to the solution set of (3.12)-(3.17), we conclude that in the spin-1 2 case our functional relations characterize the spectrum completely. It is remarked that the corresponding Bethe states were given in [45,46]. These Bethe states have well-defined homogeneous limits and allows one to study the corresponding homogeneous open chain directly. For the spin-1 case, the numerical results in subsection 4.2 for N = 2 case also suggest that the equations (3.12)-(3.17) indeed give the complete spectrum of the transfer matrix.
Eigenvalues of the fundamental transfer matrix Following the method developed in [37], let us introduce the following inhomogeneous where m is a non-negative integer and the functions a (s) (u), d (s) (u), F (s) (u) and the constant c are given by  Combining the above equations and the fusion hierarchy relations (3.12), we can evaluate Λ (s,s) (u), Λ (s− 1 2 ,s) (u) and Λ ( 1 2 ,s) (u) at the points θ j , θ j + η 2 and θ j − ( 1 2 + s)η respectively , (4.9) , (4.10) . (4.11) The above equations give rise to indicating that the T − Q relation (4.1) indeed satisfies the very functional identities (3.13).
From the explicit expression (4.1) one may find that there might be some apparent simple poles at the following points: As required by the regularity of the transfer matrix, the residues of Λ ( 1 2 ,s) (u) (4.1) at these points must vanish, which leads to the following BAEs +c (λ j (λ j + η)) m+1 F (s) (λ j ) = 0, j = 1, . . . , 2sN + m − 2M, (4.14) where the functions a (s) (u), d (s) (u), F (s) (u) and the constant c are given by (4.2)-(4.5) respectively and the associated Q(u) function is The 2sN parameters {λ j } satisfy the resulting BAEs , (4.19) where The resulting BAEs read On the other hand, if 2sN is odd, the minimal m becomes m = 1 and the corresponding number of the Bethe parameters {µ j } is 2sN + 1. The associated T − Q relation is where Q 1 (u) is still given by (4.20) but with M 1 = 2sN + 1 and the resulting BAEs now become Similarly as in [27], the three discrete variables {ǫ i } are required to obey the following relation Alternatively, let us make the following T − Q ansatz for the eigenvalue Λ ( 1 2 ,s) (u) where F (s) (u) is given by ( can be diagonalized simultaneously, the algebraic Bethe ansatz method can be applied [36]. In this particular case one can choose ǫ 1 = −1, ǫ 2 ǫ 3 = −1 and therefore c = 0. The corresponding T − Q ansatz (4.27), under the similar analysis as that in [37], is naturally reduced to the conventional one [36] obtained by the algebraic Bethe ansatz.

Spin-1 case
In this subsection we illustrate the completeness of the Bethe ansatz solutions obtained in the previous subsection. For the case of s = 1 2 , which corresponds to the spin-1 2 XXX spin chain and the corresponding transfer matrix is t ( 1 2 , 1 2 ) (u), our result is reduced to that obtained in [37]. The completeness of the Bethe ansatz solution was already studied in [37,51,54].
Here we provide numerical evidence for the s = 1 case, which corresponds to the isotropic Fateev-Zamolodchikov (or Takhtajan-Babujian) model [11,15] with general non-diagonal boundary terms. In terms of the basis {|l |l = 1, 0, −1} given by the corresponding spin-(1, 1) R-matrix R (1,1) (u) defined in (2.11) is where the non-vanishing entries are The spin-1 K-matrix defined by (2.17), in terms of the basis {|l |l = 1, 0, −1}, is given by where the matrix elements are , The dual spin-1 K-matrix K +(1) (u) can be given by the above K-matrix through the correspondence (2.20).
The eigenvalue Λ ( 1 2 ,1) (u) in the homogeneous limit (i.e., θ j → 0) reads where we have chosen m = 0 and the functions a (1) (u), d (1) (u), F (1) (u) are given by The constant c is given by (4.5). The three Q-functions are parameterized by 2N parameters {λ j |j = 1, . . . , 2N − 2M} and {µ j |j = 1, . . . , 2M} (with M a non-negative integer) as The 2N parameters {λ j |j = 1, . . . , 2N − 2M} and {µ j |j = 1, . . . , 2M} satisfy the following BAEs The eigenvalue Λ (1,1) (u) can be constructed from the fundamental one Λ ( 1 2 ,1) (u) given by (4.32)-(4.35) by using the relation (3.12) as follows The Hamiltonian of the spin-1 XXX open chain with the generic non-diagonal boundary terms is given by The eigenvalues of the Hamiltonian (4.42) thus read .  Table 1 for M = 0 and Table 2 for M = 2, respectively. The eigenvalues of the Hamiltonian obtained by solving the BAEs are exactly the same to those obtained by the exact diagonalization of the Hamiltonian. The eigenvalues Λ ( 1 2 ,1) (u) of the transfer matrix t ( 1 2 ,1) (u) are shown in Figure 1. Again, the curves of Λ ( 1 2 ,1) (u) calculated from the BAEs and the T −Q relations coincide exactly with those from the exact diagonalization of the transfer matrix t ( 1 2 ,1) (u). The numerical results strongly suggest that a fixed M is enough to give the complete spectrum of the transfer matrix. Table 1: Solutions of the BAEs (4.39)-(4.40) for N = 2, M = 0, η = 1, p + = 0.1, p − = 0.2, α + = 0.3 and α − = 0.4. n indicates the number of the energy levels and E n is the corresponding eigenenergy. The energy E n calculated from the Bethe roots is exactly the same to that from the exact diagonalization of the Hamiltonian (4.42).

Conclusions
The spin-s XXX chain with the generic non-diagonal boundary terms specified by the most general non-diagonal K-matrices given by (2.17)-(2.22) has been studied by the off-diagonal Bethe anstz method. Based on the intrinsic properties of the fused R-matrices and Kmatrices, we obtain the closed operator identities (3.7) of the fundamental transfer matrix t ( 1 2 ,s) (u). These identities, together with other properties (3.8)-(3.10), allow us to construct an off-diagonal (or inhomogeneous) T − Q equation (4.1) of the eigenvalues of the transfer matrix and the associated BAEs (4.14)-(4.15). It should be emphasized that there are a variety of forms of the inhomogeneous T −Q relations such as (4.16), (4.19) and (4.22). Each of them should give the complete spectrum of the transfer matrix. Taking the spin-1 XXX chain as an example, we give the numerical evidence for two-site s = 1 case. We note that the method developed in the present paper can also be applied to the integrable models with cyclic representations such as the lattice sine-Gordon model, the τ 2 model, the relativistic Toda chain and the chiral Potts model with generic integrable boundary conditions.
For the spin-1 2 case, the Bethe states corresponding to the T − Q relation (4.16) were constructed in [46] (also conjectured in [45]) with the helps of the SoV basis proposed in [31].
It is interesting that the resulting Bethe states directly induces the homogeneous limits of the SoV states constructed in [31]. Following the similar procedure, the eigenstates for the spin-s open chains might be constructed with a similar basis proposed in [55] 11 .
(i.e., Q(−u − η) = Q(u)) of degree 4sN with a known coefficient of the term u 4sN , for each solution Λ(u) of (3.12)-(3.17) one can always choose the function Q(u) of form (4.17) such that the following equations hold: choose its values at some extra m points to be zero such that the associated T − Q satisfied.