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Physico-Chemical Studies in Non-Aqueous Solvents

The equivalent conductance of some 1:1 electrolytes has been measured in the concentration range 1—100 IO-4 mole litre-1 in JV-methylacetamide (NMA) at 40° and the data have been analysed by the Shedlovsky and FuossOnsager equations for completely dissociated electrolytes. The transference numbers of KSGN and AgC'lOn have been measured in the concentrations 0.03—0.17 and 0.02—0.07 mole litre-1 respectively at 40°. The limiting cation transference numbers of these salts have been obtained by Longsworth's method. Ionic mobilities, effective ionic radii and solvation numbers of various ions have been determined. A comparison of the solvation number data in amide solvents reveals that NMA is aprotic towards electrolytes which may be due to the structure of the solvent.