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Construction of Bifunctional Co/H-ZSM-5 Catalysts for the Hydrodeoxygenation of Stearic Acid to Diesel-Range Alkanes.

Bifunctional Co/H-ZSM-5 zeolites were prepared by a surface organometallic chemistry grafting route, namely, by the stoichiometric reaction between cobaltocene and the Brønsted acid sites in zeolites. The catalyst was applied to a model reaction of the catalytic hydrodeoxygenation of stearic acid (SA). The cobalt species existed in the form of isolated Co2+ ions at the exchange positions after grafting, transformed to CoO species on the surface of the zeolite, stabilized inside the zeolite channels upon calcination in air, and finally reduced by hydrogen to homogeneous clusters of metallic cobalt species approximately 1.5 nm in size. During this process, the Brønsted acid sites of the H-ZSM-5 zeolites were preserved with a slightly reduced acid strength. The as-prepared bifunctional catalyst exhibited an approximately 16 times higher activity for the hydrodeoxygenation of SA (2.11 gSA  gcat-1  h-1 ) than the reference catalyst (0.13 gSA  gcat-1  h-1 ) prepared by solid-state ion exchange and a high C18 /C17 ratio of approximately 24. The remarkable hydrodeoxygenation performance of the bifunctional Co/H-ZSM-5 was owed to the effective synergy between the uniformed metallic cobalt clusters and the Brønsted acid sites in H-ZSM-5. The simplified reaction network and kinetics of the SA hydrodeoxygenation catalyzed by the as-prepared bifunctional Co/H-ZSM-5 zeolites were also investigated.