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Phase Relationships in Sea Ice as a Function of Temperature

Quantitative measurements of the liquid water phase in a sample of sea ice were made with a nuclear magnetic resonance spectrometer. The measurements are used to compute the phase relationships in sea ice as a function of temperature. A model for sea-water based upon a mixture of seven binary salts is used for these computations. The n.m.r. measurements are related to the solvation water which is associated with each binary salt. This solvation water is bound to the salt in a pseudo-crystalline structure, with the amount of water determined by the eutectic concentration of the salt. The results are given in tabular form and differ somewhat from previously published tables. Two controversial hydrated salts were added to the table, based on the n.m.r. data.