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Synthesis And Thermolysis Of Metal Complexes Containing Energetic Ligands

Nitramine ligands have very rarely been employed in metal complex chemistry. This paper describes several new metal-nitraminato compounds of Cu(II), Ni(II) and Pd(II) and their crystal structures. Some of the compounds are potentially interesting as nitramine burn-rate catalysts. To this end, gas product speciation studies were conducted on the compounds under conditions of high heating rate thermolysis. Selected results are described.