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Scaled particle theory analysis of extractive distillation

This work investigates the improved relative volatility at infinite dilution due to the addition of salt for extractive distillation processes. Analysis of the fundamental equations of scaled particle theory provides the relationship between the salting coefficient and the relative volatilities at infinite dilution with and without salt. A salting coefficient k s was obtained using scaled particle theory for separating non polar systems. For separating polar systems, the results correspond with a qualitative analysis of the salting coefficient. The results agree with experimental values.