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Hydrochemistry and environmental isotopes (18O, 2H, 3H, 3He/4He) of groundwater and floodwater in the great area of Hurghada, Eastern Desert of Egypt

Porous and fractured aquifers exist in the area of Hurghada, Eastern Desert of Egypt, whose recharge processes through the common flash floods are not identified. Hydrochemical parameters, stable isotopes 18O, 2H and tritium in floodwater and groundwater were applied in the area subject to study. Additionally, He isotopes were investigated in the deep wells in the faulted zone at the Abu Shaar Plateau. 3H activity in all sampled points lies below the detection limit excluding a recent recharge component in groundwater. However, the hydrochemical ratios and the stable isotope signature confirm that the shallow wells and springs (Red Sea Hills group) are being recharged from modern precipitation. The hydrochemical parameters of the deep wells at the Abu Shaar Plateau (coastal plain group) confirm another origin for the ions rather than the modern precipitation. Together with the 18O and 2H values, the Br/Cl ratio of this group confirms the absence of seawater intrusion component and the role of the fault as a hydraulic barrier. These 18O and 2H values deviate from the GMWL confirming an evaporation effect and colder infiltration conditions and reveal strongly a possible mixing with the Nubian Sandstone in the region. The 3He/4He ratio confirms a mantle contribution of 2% from the total He components.


Introduction
Groundwater is the only available freshwater resource in areas far from the River Nile valley. Its contribution in the water demand of Egypt was estimated at 7% in the time between 1999 and 2002 (Margat et al. 2006). Brackish groundwater in the Eastern Desert is widely used for drinking and irrigation in the remote areas and for the desalinization in the touristic facilities along the Red Sea coast. New agriculture lands irrigated with deep groundwater can be observed recently in some areas along the Red Sea coast. Groundwater occurrence, its chemical and stable isotopes properties in this area have been investigated by several studies (Hefny et al. 1992;Nada et al. 1996;El-Sadek et al. 1998). Some of these studies mentioned that groundwater in the area of the Eastern Desert is of paleometeoric origion and the Nubian sandstone aquifer discharges groundwater into alluvial sediments through faults complex (Sultan et al. 2007) and the upper aquifers of Quaternary and Miocene Sandstone are partially recharged from the flash flood (Awad et al. 1996;El-Sadek et al. 1998;Sultan et al. 2007). Several studies have applied the noble gas technique in groundwater investigations in the Eastern and Western Desert of Egypt. Sturchio et al. (1996) investigated the thermal groundwater discharged from springs along the Gulf of Suez where Helium was analyzed in Hammam Faroun with an estimation of 3.5% of magmatic He. Sturchio et al. (2004) investigated groundwater age of the Nubian sandstone aquifer at five oases in the Western Desert of Egypt using Kr 81 . Aeschbach-Hertig et al. (2006) investigated the recharge and the paleometric temperature of groundwater in the area of Nile Delta using s spectrum of noble gases.
The investigation area is located between Hurghada city in the south and Wadi Melaha Oasis in the north at the Red Sea coast of Egypt (Fig. 1). Abu Shaar Plateau exists around 22 km south of Wadi Melaha Oasis and 5 km west of El Gouna (Fig. 1). At the fault zone which separates this plateau from the coastal plain (Klitzsch and Linke 1983) several wells were drilled between 1994 and 2000 (Kleinendorst 2004) to pump brackish water to supply El Gouna area. Moving southwards to the area extended between El Gouna to 36 km SW of Hurghada city, several springs and shallow wells (Fig. 1) provide small communities in the Eastern Desert with water. The springs and some wells exist in the basement rock formed by Precambrian fractured granite while other wells are in the Quaternary alluvial deposits which settled between the basement hills. Deep wells used mainly to irrigate new agriculture farms can be observed in the area of Wadi Om Dehas (Fig. 3). In Wadi Melaha Oasis north of El Gouna ( Fig. 1) a permanent spring and a stream could be detected.
The purpose of this study is to investigate the processes which influence the hydrochemistry of groundwater and their stable isotopes values in the area and weather the flash floods which are common in the region contribute to the groundwater recharge.

Geological and tectonic settings of the study area
The study area is located at the southwestern border of the Gulf of Suez. The rifting in the Gulf of Suez evolved in the Late Oligocene and Miocene and is to a minor extent still active (Bosworth et al. 2005). Faults and fractures zones (ENE-WSW) strike the different blocks in the area which resulted from the subsidence of the Red Sea Graben (Bosworth and Taviani 1996). The stratigraphy in the investigated area can be divided into three major sedimentary units (Klitzsch and Linke 1983): represented in Tpl Pliocene (shallow marine and continental clastic rocks) and Q, QG, S, W Quaternary (gravel plain, sabkha deposits, alluvial fan and wadi deposits. The basement in the north of the Eastern Desert, where the study area is located, is relics of the Neoproterozoic orogeny (Stern and Hedge 1985). The magmatic rocks are separated into two groups, granitoids and volcanic (Greilling et al. 1988). The rocks are exposed to the surface in the mountainous areas of the Red Sea Hills, forming very steep and high mountain ridges. The Red Sea Hills in the area are formed by Precambrian crystalline basement (acidic plutons and ophiolite formations) (Greilling et al. 1988;Hadidi 2016). Paleozoic and Mesozoic discordant layers are mostly continental and shallow marine sandstones (Alsharhan 2003), including the Nubian sandstone, which is known as the most productive aquifer in the western desert (Thorweihe and Heinl 2002) but disconnected from those sources in the Eastern desert.
The sedimentary environment changed in the beginning of Cretaceous times and gradually moved from continental to the marine environments of the Eocene, which is dominated by thick limestone formations.
Tertiary is the time of the main phase of uplifting (Miocene) and mostly sedimentary rocks are originated in the syn-rift period.
The syn-rift sediments in the investigation area range from siliciclastic in the Early and Middle Miocene (coarse conglomeratic fan deltas, close to active fault systems and uplifted blocks, to the distal fine-grained clastic material) to shallow marine limestones and evaporates in the Late Miocene (Bosworth and McClay 2001).
After Hadidi (2016) and Linke (1986) halite which is intersected with sulphate and carbonates (evaporates units Tev, Fig. 1) form thick evaporitic sequence is responsible for the high salinities in the deep brines of the Red Sea. The halite has been washed out near the surface and the evaporates consist mainly of gypsum and anhydrite.
Post-rift strata overlying most of the syn-and pre-rift deposits. The Pliocene and Quaternary soft rocks mainly consist of fanglomeratic gravels and sands (Bosworth 1996) with locally very huge thicknesses. The coarse-grained layers, deposits of evaporates, limestones and marls are widely spread and separate different lithologically and hydrogeological units.
The Abu Shaar Plateau consists mostly of carbonatic formations of the Middle Miocene ( Fig. 1) and is located along the main fault system in direction NW-SE. Very steep slopes differentiate the plain from the mountainous areas which highest elevations reaches more than 200 m a.s.l. (Gebel Abu Shaar). To the north crystalline basement outcrops at the surface. The area of the coastal plain is shallow (5 and 20 m.a.s.l). It consists of the Late-Rift sequences of the Pliocene and Quaternary, which are composed of alluvial fan and wadi deposits (QW), gravel plain deposits (QG), sabkha deposits (Qs) and shallow marine clastics (Tpl and Q) with thicknesses up to several 100 m (Hadidi 2016;Klitzsch and Linke 1983).

Hydrogeology
The classification of aquifers is according to the tectonic phases distributes the aquifers system into basement, prerift, syn-rift and post-rift aquifers. All aquifers are present in the study area.
The mountainous area of the Red Sea Hills is dominated by magmatic basement aquifer represents the pre-rift aquifer. These rocks form fractured aquifers which can be of greater thicknesses and good transmissivities in fault zones (Salah and Alsharhan 1996). The basement aquifer can be connected to springs and old wells along the basement faults delineate water resources (Hadidi 2016). The availability of aquifers of the pre-rift phase is limited.
The Syn-rift aquifers of pre-Miocene and Miocene are present at the Abu Shaar Plateau west of El Gouna. The carbonatic formations are conductive and can be karistified (Hadidi 2016).
The post-rift aquifers of Pliocene and Quaternary are present in the coastal plains and east to Abu Shaar in the area of El Gouna and Om Dahes valley (Fig. 1). The shallow porous aquifers are separated by thin silty layers. The aquifers consist of sandy, locally fine grained and silty parts, often interlaced by gravel and coarse sands (Hadidi 2016). The extensive geophysical exploration carried out by Sultan Fig. 1 Geological map of the area modified after Klitzsch andLinke (1983) (coordinate system: ETRS, 1989 UTM 36N, epsg-code: 25836, also in the following maps) et al. (2011) shows structures and relation to groundwater in the coastal plain of the Egyptian Red Sea coast and in parts of the Red Sea Hills. An important focus was the measurements along the NE and SW ridge of wadi Melaha (Fig. 1). Three deep depressions in this area were delineated that seem to be important for the storage of groundwater. Tectonic structures link these depressions. The deepest depression west of Abu Shaar Mountain has an estimated depth of 2340 m. The topographic altitude of the area is between 120 and 200 m.a.s.l while the coastal plain has a topographic altitude between 0 and 70 m. The hydraulic role of the faults will be discussed in Sect. 5.

Climatology
The climate in the Eastern Desert of Egypt is arid and generally characterized by hot summers and moderate winters. Most of climate stations which are installed in the Eastern Desert are located at the coastal line and they reflect the coastal effect which moderates the temperature (Hadidi 2016). The climate data presented in Fig. 2 were obtained from a climate station located at the Red Sea coastal plain (27.43 E, 33.66 N) which is located on an elevation of 4 m.a.s.l. The calculated monthly averages are based on a measuring period between March 2014 and January 2019 with a time interval of 10 min.
The seasonal trend shows the highest temperatures between June and August (> 30 °C) and the lowest in December and January (< 20 °C). The relative humidity with an annual average of 47% also shows a weak seasonal variation with a minimum between May and August (average 45%) and a maximum between October and December (average of 50%).
Sporadic precipitation events take place in winter months (between October and April) having durations of a few minutes to few hours. During 2014 and 2018, three events with a precipitation > 10 mm occurred and could be recorded in El Gouna weather station (08/09-03-14: 33 mm, 25-10-15: 10 mm, 27-10-16: 20 mm). These events led to flash floods in the Red Sea Hills and the coastal plain (Hadidi 2016;Saber et al. 2020). Five other events with precipitation < 1 mm without floods were recorded additionally. The precipitation and flood events could partially be sampled for chemical analyses (Sect. 4.1, Table 1).
Evaporation data from the region were reported by Awad et al. (1996) with a maximum annual mean value in June with 10.11 mm/day and a minimum in December with 6.11 mm/day.

Water sampling: chemical and isotopes analytics
Samples from rainfall, floodwater, groundwater, and seawater were analyzed in the time between 2014 and 2019 to investigate the origin and quality of groundwater in the investigation area. The intense precipitation event of March 2014 and the resulting flash flood could be sampled at several locations (rainwater samples R1-R3, floodwater samples F1-F3, Fig. 3, Table 1). The field parameters have not been measured during this sampling (Askar 2014;Hadidi 2016). The rain gauges where samples R1, R2, R3 have been manually installed in the mountain ridge (Fig. 3). Rain depth at R1 was measured on 03-03-2014 with 7 mm, while the rain depth on 09-03-2014 in R2 and R3 locations was measured with 32 and 47 mm, respectively (Hadidi 2016 Table 1). Beside the field parameters which were measured in all samples, the alkalinity was also determined in the field. Groundwater samples have been collected from the existing springs and wells in the study area. The samples were divided into two regional groups: The coastal plain group (samples P1-P9) which includes 20 wells, nine of them were sampled for this study (Tables 1 and 2). They are located 5 km west of El Gouna and they will be referred as "deep wells" in the rest of this study. These wells were drilled in the time between 1990 and 2000 and belong to the aquifer of Pre-Miocene and Miocene with carbonatic-silicastic sequences which belong to the syn-Rift units. Information records about the well constructions data aren't available. The locations of the wells were determined using a GPS device with accuracy of ± 5 m. Measuring the water table in the field was not possible due to the permanent pumping. Well heads are not referenced to a vertical datum. The wells have depths between 30 and 140 m (Table 1) and are used for water supply and irrigation purposes. The Red Sea Hills group (samples H1-H10) which belongs to wells (four shallow dug wells with depth from 10 to 33 m and one drilled deep well), four springs and a permanent stream of Wadi Malaha Oasis (Table 1). The springs H2, H8, H9 belong to the crystalline basement of the Red Sea Hills. H4, H5 belong to Melaha spring and stream of an oasis at the north of El Gouna, Fig. 1. All these springs have low flow rate which could not be quantified in the field. Samples H3, H6, H7 in this group belong to dug wells exist in the wadi sediments of the late-Rift units. H1 is a drilled well of 300 m depth and irrigate a citrus farm. Four additional wells adjacent to H1 were detected during the sampling campagna but could not be sampled. H10 belong to a well of 15 m depth drilled in the basement on a fracture. The parameters EC, T, pH were measured at each sampling location using WTW portable devices. Total and carbonate hardness was measured in the field using gran titration. For all samples of rainwater, floodwater sampled in and after 2016 and groundwater, anion and cations samples were filtered in the field using 0.45 µm filter and filled into 50 ml bottles. The cation and anion samples were acidified by adding 0.2 ml of HNO 3 and 0.2 ml of bacteria acid C4H8N2S, respectively. NO 3 , SO 4 , Cl and Br were analyzed using a Metrohm ® 881 Compact Ion Chromatograph pro-Anion -MCS. Major cations (Ca, Mg, Na, and K) were analyzed using an Agilent ® 715 ICP-OES. All analyses were performed at a laboratory on the El Gouna campus of the Technical University of Berlin, Egypt.
Nine samples from the coastal plain group, eight samples from the Red Sea Hills group, one rainfall sample were collected for determining the stable isotopes (  The L1102-i is based on the WS-CRDS (wavelengthscanned cavity ring down spectroscopy) technique (Gupta et al. 2009). Measurements were calibrated by the application of linear regression of the analyses of IAEA calibration material VSMOW, VSLAP and GISP. The stable isotope ratios of oxygen and hydrogen are expressed in the conventional delta notation (δ 18 O, δD) in permil (‰) versus VSMOW. For each sample, six replicate injections were performed and arithmetic average and standard deviations (1sigma) calculated. The reproducibility of replicate measurements is generally better than 0.1 ‰ for oxygen and 0.5 ‰ for hydrogen.
Seven samples from the coastal plain group were collected to analyze the tritium 3 H and the noble gas Helium He. Groundwater from the Red Sea Hills group could not be sampled for He. All dug wells and springs in this group are open and have contact with the air. Therefore, only samples for 3 H were taken from this group. For this purpose, each sample was filled into one 1000 ml bottle. The measurements were carried out by applying the electrolytic enrichment using Liquid Scintillation Counting (LSC) in Hydroisotop Laboratory, Schweitenkirchen Germany. Values are reported in tritium units (TU) where 1 TU equals an activity of 0.119 Bq/L (IAEA 1992) and tritium half-life time is (4500 ± 8) days (≈12.3 years) (Lukas and Unterwegers 2000). The detection limit is 0.5 TU.
For 3 H and He sampling in the coastal plain group, each sample was filled into two 40 ml gas tight copper tubes.
The sampling was performed by connecting the groundwater coming out of the wells to a transparent flexible tube which is in turn connected with the copper pipe. The other end of the copper pipe was connected as well to another transparent tube. This sampling procedure enables the sampler to prevent mixing the air bubbles with groundwater. The tube was flushed at least ten times before filling it with sampled groundwater. The pipe two ends were screwed properly. In the same time, and for each well which was sampled for He, another bottle of 1000 ml size was filled with groundwater for the 3 H analysis. Tritium measurements of the coastal plain group were carried out together with He and Ne at the Institute of Environmental Physics, laboratory of noble gases, University of Bremen, Germany. The measurement method was developed by Sultenfuss et al. (2009) and has precision of ± 3% with a detection limit of 0.015 TU for 500 g water (storage time 3 months).
After gas extraction in the laboratory, Ne and He isotopes were purified in a two level cryo system at 25 and 14 K. 4 He, 20 Ne, and 22 Ne were measured with a Quadrupole mass spectrometer (Pfeiffer QMG 112). After separation from Ne, 3 He, and 4 He were analyzed with a high-resolution sector field mass spectrometer (MAP 215-50). The typical precision for He and Ne concentration is better than 1%. Ne is measured to determine the atmospheric He component. Salt corrections were made assuming an initial equilibrium in fresh water.

Soil samples and XRD analytics
Two soil samples of clay collected from the alluvial fan of Wadi Bili Fig. 1 were analyzed using D2 Phaser. The wadi mud sample was collected from the protection depression where the flood water is collected after heavy rainfalls. The second sample was taken from a drilling location in the area of El Gouna at a depth of one meter under the surface. The samples have been crushed into a powder (< 63 µm) and finally analyzed in the institute of applied geochemistry at the Technical University of Berlin, Germany.

Hydrochemical development
The hydrochemical processes and the development of the water quality from precipitation to floodwater and groundwater are discussed by means of δ 18 O, δD and the dissolved ions (Sect. 4.2).

Separation of helium components
The three components of atmosphere, mantle, and crust can be separated according to the simplified model of (Castro 2004;Aeschbach-Hertig 2005;Kaudse 2014): where R s = 3 He s / 4 He s is the mixture ratio of the He isotopes in the sampled water, c, m and a refers to the ratios R in the crust, mantle, and atmosphere.
Using 3 He/ 4 He ratios for the single components R A , R c , R m , Eq. (1) can be written as: With Xi relative share of 4 He i in the single fractions Xc + Xm + Xa = 1 and the crustal share Xc can be expressed as Xc = 1-Xm-Xa. Applying this in Eq. 2 results in X m is mantle fraction of 4 He but not of 3 He. The mantle fraction of 3 He y can be essentially calculated as (Aeschbach-Hetig 2005): The ratio R m = 3 He m / 4 He m of the mantle component could be derived from analyses of the Red Sea Deep water from (Winckler et al. 2001) (R m : 1.3 × 10 -5 , R m /R a = 9.2, with R a 3 He/ 4 He ratio of the atmosphere 1.38 × 10 -6 ). The ratio R c = 3 He c / 4 He c of the crustal component was assumed to be a crustal average 2 × 10 -8 (R c /R a = 0.0145) (Mamyrin and Tolstikhin 1984). The fractions of Earth mantle and Earth crust of the coastal plain group samples are discussed in Sect. 4.3.

Noble gas equilibrium temperatures
Excess air and the equilibrium temperature can be determined using the Ne concentrations in groundwater (Aeschbach-Hertig et al. 1999). The groundwater content of noble gases includes the gas content derived from the atmosphere and the atmospheric content which is called excess air and this component get less in the heavy gases (Kaudse 2014). In addition to 3 He, 4 He, 21 Ne has been analyzed in the samples of the coastal plain group (Table 2). Ne analysis is usually made to estimate the degassing or excess air in the sample. The atmospheric content of noble gas in the rainfall is dependent on the temperature, the salinity and pressure , therefore, the reconstruction of these conditions is possible using the concentrations of noble gases in the aquifer (Bath et al. 1979 (3) -Hertig et al. (1999), the initial concentration of the atmospheric noble gases in groundwater is given by The C eq i is the equilibrium concentration which is dependent on the temperature T, salinity S and pressure P.
Henry's law describes the partitioning at the air-water interface in term of the concentrations gas in air and water are proportional to each other's.
After Kipfer et al. (2002), this equation is formulated for each gas depending on the partial pressure and the equilibrium concentration: The partial pressure P i of the gas depends on the total pressure of the air P tot which is corrected for the water vapor content e w (T), and the mole fraction Zi of the gas in the dry air Ozima and Podosek 1983;Weiss 1970;Weiss and Kyser 1978): The local barometric altitude effect on the atmospheric pressure is influenced by the local and the sea level pressure: where the P tot together with the saturation vapor pressure should be corrected.
Depending on this model, the atmospheric equilibrium concentrations for He and Ne of the rainfall in dependency of air temperature and topographic altitude can be reconstructed. Table 1 shows the chemical and stable isotopes 18 O, 2 H results for the sampled wells and springs in addition to the rain and floodwater samples. Table 2 shows the analytical results of 3 H and He isotopes.

Analytical results
The electrical conductivities of all groundwater samples are in the range of brackish water. The values in the deep wells (7.3-19.6 mS/cm) of the coastal plain group differ (10) P tot (h) = P sl tot .e −h∕h atm , from those in the Red Sea Hills group (1.2-4.8 mS/cm) with the exception of H4, H5 and H10. Temperature T differs between the two groups too. While the Red Sea Hills group reflects the air temperature, a thermal influence with elevated temperatures up to 38 °C (Table 1) can be recognized.

Stable isotopes
The northern Red Sea A sample from the northern Red Sea (S1 Table 1) was taken in El Gouna in October 2016 (blue pyramid in Fig. 4) Fig. 4. (light blue squares). The LMWL plot as an evaporation line with a slope less than 8 and crosses the GMWL at approximately δ 18 O ‰/δ 2 H ‰: − 0.3/7 which represents the isotopic values of the mean weighted local precipitation (Gibson et al. 1993). The d-excess of the LMWL (+ 9.9) indicates evaporation at a relative humidity of approximately 75% (Pfahl and Sodemann 2014). One rainfall sample in El Gouna could be taken for isotopic analyses in February 2018, R5, weak rainfall event 23-2-18 9:00 pm-24-2-18 1:00 am, ≈3 mm). The cumulative sample was taken overnight in an open vessel and collected next day. The sample is influenced by evaporation (conditions: temperature 17.5-22.3 °C, relative humidity: 60-82%). A floodwater sample could be taken from Wadi Araba area in February 2019. (Table 1, F7, 3 days after a rainfall event). This sampled location is approximately 170 km far to the north. The samples R5 and F7 are plotted in Fig. 4 and reported in Figs. 1 and 3.
To complete the isotopic record of precipitation, additional data from the Red Sea area and its surrounding were taken from literature: Two data were reported by Awad et al.  (2019) δ 18 O ‰/δ 2 H ‰: 0.88/12.6. In general, these data (yellow rhombs in Fig. 4a) and the floodwater sample F7 (dark blue square in Fig. 4a) plot close to the LMWL. The analyses from the Sinai Peninsula (Abdel Samie and El-Sadek 2001) that represents the source of the local groundwater recharge (Eissa et al. 2013) plot closer to the EMWL the Eastern Meteoric water line (Gat and Carmi 1970) which implies inland conditions and a more arid vapor source. The precipitation sample from El Gouna (R5, Table 1) differs strongly from the LMWL and GMWL and plot on an evaporation line. Regarding an average relative humidity of 70% during the evaporation process (increased humidity during and after the event), the slope of this evaporation line can be approximated with 4.98 (Gonfiantini 1986). Assuming a steady evaporation at 70% humidity, the initial water would plot where the 70% evaporation line crosses the LMWL (Bowen et al. 2018).
Evaporation processes Beside the precipitation sample (R5) also other samples show evaporation effects (Table 1): the stream of the Oasis Wadi Melaha H5, the dug well in Elojaira H10 and the superficial water of Red Sea S1 shown in Fig. 4a.
The source of evaporated stream water sample H5 is sample H4, the spring of Wadi Melaha. The concentration of the conservative parameters Cl and Br are increased by factors of 2.8 and 3.2 from H4 to H5 (Table 1), which means the water loss of the primary solution caused by evaporation is 65-68% (neglecting the sparse precipitation). The slope of the evaporation line between H4 and H5 is 4.74, what can be related to a relative humidity of ≈60% (Gonfiantini 1986). This humidity value is reliable for the air above a watershed in this Oasis. The average isotopic composition of the evaporated water can be calculated to δ 18 O: − 10.1‰, δ 2 H: − 69.4‰.
The slope δ 18 O/δ 2 H of the rainfall samples R5 considering the average Cairo weather station rain (δ 18 O: − 1.44‰, δ 2 H: − 4.19‰) as the origin rain. The slope of the evaporation line between R5 and Cairo sample to the GMWL is 4.99 what can be related to a humidity of 70%. This humidity is reliable for an evaporation process above the open Sea. For the dug well Elojaira exist only the evaporated samples H10. In addition, this sample is the only one that shows a Tritium activity above the detection limit (0.7 TU, see Table 2). The well is located in the Red Sea Hills approximately 15 km from the coast (Fig. 3). Using an average relative humidity of 50% (annual average in the coastal area is 47%, Sect. 2.3) results in a slope of 4.45 of the evaporation line in δ 2 H/δ 18 O relation (Gonfiantini 1986). The primary solution can be extrapolated to more depleted water in a range δ 18 O: from − 6.5 to − 5‰ and in δ 2 H: from − 35 to − 45‰ (probably close to isotopic composition of the wells H1 and P8). Comparing with the enrichment in Wadi Malaha (H4, H5) and the Red Sea (S1) the water loss due to evaporation might be in a range of 40-50%, and the solution is concentrated by a factor 1.8-2.
Groundwater Groundwater samples can be differentiated in several groups: 1. Samples drop close to the LMWL: In the range of the actual precipitation data (δ 2 H > − 20, δ 18 O > − 4) Red Sea Hills group (red squares in Fig. 4a

Samples of group 1 can be related to infiltration waters of modern precipitation under warm infiltration conditions.
Samples of group 2 are of intermediate waters that consist of different mixtures between water from group 1 and 3.
Samples of group 3 represent fossil groundwater with an increased depletion of the stable isotopes and a clear deviation from the LMWL.
Representing the relationship between 2 H and d-excess in Fig. 4b (excluding the evaporated samples H5 and H10) supports the separation of the three groups. The d-excess of group 1 is similar to this of the floodwater. Samples of group 2 plot on a line with H8 and H9 and the deep wells of group 3 seem to have differences in d-excess and indicate colder recharge conditions and more humidity.

Concentrations of selected major and trace elements
To follow the development of concentration which increases during the rainfall events, after reaching the ground surface and in the aquifers, Schoeller diagram was used for the four water groups in Fig. 5a.
The lowest concentrations are found in rainwater. The rainwater is dominated by Cl, SO 4 , Na, and Ca in a range between 0.1 and ≈ 1 mmol/l. In areas close to the sea, the uptake of sea-spray is remarkable, shifting rainwater composition towards seawater. As shown in Sect. 4.2.1 by means of the stable isotopes, the sample R5 is evaporated and concentrated by a factor 1.5-2. In addition, other samples might be influenced by evaporation and are consequently concentrated (e.g. R1, R4) and the concentration of the unevaporated rainwater is lower. The floodwater samples have increased concentration compared to the rainwater samples. The dominating ions are Cl, SO 4 , Na, and Ca in the range of ≈1-10 mmol/l. The distribution of the ions is relatively similar to the rainwater samples. These increased concentrations are related to evaporation and to the water/rocks interaction and the uptake of terrestrial salts resulting from variablbe rocks compositions which exist in the study area (eg. NaCl, CaSO 4 ×2H 2 O, CaCO 3 ).
Sample F7 (the only one with analyses of the stable isotopes) does not show evaporation effects (Sect. 4.2.1), therefore the concentration here is related only to the water/ rocks interaction. The terrestrial chlorides and sulfates at the surface are the result of evaporating rainwater, and close to the coast of transported sea spray.
The samples from groundwater Red Sea Hills show a broader scattering of the concentrations. Samples of groups 1 are dominated by Cl, SO 4 , Na, and Ca in a range of of ≈1 to ≈54 mmol/l. The elevated F concentration results from the uptake of apatite and fluorite which were detected in the XRD analysis. Deviations from the general pattern which characterizes this group can be observed in the concentrations of the evaporated samples (H5, H10) in Wadi Melaha spring and Elojaira well (H10) and the samples belong to H1, H4. H1 and H4 samples show comparable concentrations to the coastal plain group with elevated concentrations in all ions. Their concentrations of Br and F are similarly elevated as in the coastal plain group and confirm that these samples are probably mixed with water from the deep wells.
Piper diagram in Fig. 5b was used to represent the distribution of groundwater groups. HCO 3 and Cl positions in the diagram were exchanged for a better representation. While the coastal plain group shows a tendency of increasing salinity, the Red Sea Hills samples are very scattered indicating the different lithologies of the hosting rocks. The ratios of SO4/Cl and (Ca + Mg)/(Na + K) indicate two subgroups in the coastal plain group (Jahnke et al. 2019). The distribution pattern confirms that seawater and the coastal plain group are not in hydraulic connection despite of the intensive pumping in this area. The different Br/Cl ratios (Edmunds 1996) between this group (3.3-4.3 × 10 −3 ) and seawater (1.4-1.55 × 10 −3 ) indicate as well that no mixing with seawater take place in these wells (Jahnke et al. 2019).
To quantify the chemical development from rain to flood and groundwater averages of the parameters of the hydrochemical groups were calculated (based on logarithmic values). The balanced changes of the averaged concentrations from rainwater to the other groups are shown in Fig. 6.
From rainwater to floodwater, an averaged increase occurs of the concentrations of Cl, SO 4 , Na, and Ca of around 3-3.5 mmol/l, for K and Mg of ca. 0.3 and 0.6 mmol/l, respectively. No significant increase can be detected for Br and F. The concentration differences are small and might be related to the strong scattering and the sparse data in both groups. The flood water samples were collected during or shortly after the precipitation events, so that evaporation play only a minor role and the increase in the concentrations is related to an uptake of terrestrial salt, dust and sea spray (all flood water samples were taken relatively close to the coast in distances 5-10 km). The development is dominated by an uptake of ca. 3 mmol/l NaCl and CaSO 4 (gypsum) and carbonate minerals (calcite, dolomite).
The waters of the Red Sea Hill group show the same tendencies as floodwater for Ca, Mg, K, and SO 4 . The average concentrations of Cl and Na are increased by 15 ca. mmol/l compared to rainwater and 12 mmol/l compared to the flood water. In addition, a small but detectable increase of Br and F occurs. Based on the hydrochemical results, the groundwater of the Red Sea Hills seems to be an infiltrated flood water with an additional uptake of NaCl (mixing with NaCl-rich solutions or solution of NaCl).

Tritium/ 3 Helium/ 4 Helium
The 3 H content and the concentrations of Helium isotopes 3 He and 4 He, Ne and the ratio 3 He/ 4 He are listed in Table 2.
In the Red Sea Hills group, 3 H could be detected only in H10 in Elojaira and the rest shows activity < 0.55 TU indicating This sample as it was mentioned reflects a strong evaporation effect and the well is not protected and has a diameter of 3.5 m. Since 3 H can enter the aquifer only via rain or flood events, the well might have received rain or floodwater through the flash floods events and this can be the reason behind the detection of 3 H. The activity of 3 H in all wells of the coastal plain group is less than the detection limit 0.03 TU meaning the component of He trit (Fontes 1983;Lucas and Unterwegers 2000) does not exist in the total 3 He (Poreda et al. 1988). The absence of this component leads to the conclusion that the existing of terrigenic He is a result of U and Th decay in the earth crust and earth mantle (Schlosser et al. 1989). The atmospheric ratio symbolized as Ra is equal to (1.384 ± 0.006)0.10 -6 (Clarke et al. 1976). The 3 He/ 4 He ratio of crustal helium is in a range from 1.10 -8 to 3.10 -8 corresponding to ≈ 0.01Ra (Mamyrin and Tolstikhin 1984) and the upper mantle is characterised by a 3 He/ 4 He ratio of ≈10 -5 or ≈ 8Ra (Graham 2002;Kaudse, 2014). By the application of this ratios, the separation of Helium components into crustal He and mantle He is possible as presented by Aeschbach-Hertig (2005) (Sect. 3.2.2). The ratios 3 He/ 4 He and Ne/He were calculated for each sampled location ( Table 2). The ratio 3 He/ 4 He ranges between 0.15 Ra in well P5 and 0.5 Ra in P6 and consequently higher than the typical crust ratio ≈ 0.01Ra indicating a contribution from the mantle. The mixing between terrigenic He components in groundwater is illustrated in Fig. 7. In the case of pure mixture of radiogenic and mantle He and absence of He trit , the samples will drop between the radiogenic line and the mantle line. Because of their higher 3 He/ 4 He rather than the radiogenic line, the samples from the deep wells in the coastal plain group drop over the radiogenic helium line and indicate consequently a contribution of He from the mantle. Applying the approach suggested by Aeschbach-Hertig (2005), the He mantle was calculated with a value around 2% in all samples. The concentrations of Li which may play a role in elevating the radiogenic He ratio range in the coastal plain group range between 0.05 and 0.35 mg/l. No real correlation can be recognised between the 3 He/ 4 He ratio and the Li concentrations (Fig. 8)

Noble gas equilibrium temperatures
Unlike the He concentrations in groundwater, the Ne concentrations do not increase in groundwater therefore it can used as a tracer to reconstruct the conditions (T, P) in the catchment area. The catchment area of the coastal plain group aquifer is not known and since the 3 H was not detected in this water, the flow path of the groundwater should be far from the recharge place or the residence time of groundwater in the underground is very long. In both cases, the altitude and the temperature of the rainfall are not known; therefore, a wide margin for altitude of 50-500 m.a.s.l and for temperature 5-30 °C was chosen to calculate the infiltration temperature and the altitude of the recharge for the samples of this group (Fig. 9). The equilibrium temperature which was simulated assuming that the infiltration altitude is 500 m.a.s.l is between 13 and 30 °C indicating a wide range and less plausibility. 13 °C would go consistently with the temperatures calculated from the stable isotopes condensation conditions. 25-30 seems to be very warm for the infiltration conditions which were assumed for the rainy period in Egypt (Thorweihe 1982;Schneider 1986;Awad et al. 1996). For an equilibrium infiltration temperature of 20 °C, the topographic altitude would be in a range between 100 and 1000 m.a.s.l.
Since only He and Ne were measured in this study, the reconstruction of the paleoclimate data requires the application of more noble gases where the influence of the excess air can be compensated through the number of the measured noble gases. The studies which have been applied in this appraoch resulted higher temperatures than given from the 18 O and 2 H. Even having data from all noble gases analysed (Beyerle et al. 2002;Lavastre et al. 2010;Lehmann et al. 2003;Pinti et al. 1997), this method seems not to be reliable dealing with fossil water. Even for younger water, the method lacks of evidence compared with classical stable isotopes. Temperature diffrences of five degrees were mentioned in several studies (Andrews and Lee 1979;Beyerle et al. 1998).

Discussion
Following the marine-atmosphere isotope model of Craig and Gordon (1965), a Raleigh distillation at 75% relative humidity of the northern Red Sea would result in vapor of the homogenous layer with δ 18 O and δ 2 H values of approximately − 11 and − 80‰, respectively. Precipitation formed from this vapor has isotope values of δ 18 O: − 2‰ and δ 2 H: − 10‰. Rainout depletes the vapor and at 50% relative humidity the isotope values in the cloud layer would be δ 18 O‰/δ 2 H‰: − 15 and − 118‰. The determined isotope values of the precipitation fit well to the precipitation data and data of the groundwater group 1 (Sect. 4.2.1 groundwater) in Fig. 4a. Hence the northern Red Sea is most likely the main reservoir for vapor formation and precipitation in the research area.
The Red Sea water shows a deviation from the SMOW (Table 1: S1: δ 18 O: 2.3‰; δ 2 H: 11.6‰), which is typical for the northern part of the Red Sea, compare e.g. (Andrié and Merlivat 1989), (Table 1, Sect. 4.2.1, the northern red Sea). The concentrations of the conservative parameters Cl and Br are increased by factor of ≈1.14 comparing to standard seawater, so the loss of water by evaporation is ≈13%. A linear correlation exists between salinity and 18 O and δ 2 H so the enrichment is related to evaporation processes (Andrié and Merlivat 1989). The slope δ 2 H /δ 18 O to the SMOW is 4.99 what can be related to a humidity of 70%, is reliable for an evaporation process above the open Sea.
The mean weighted local precipitation (δ 18 O‰/δ 2 H‰: − 0.3/7) taken from the LMWL-GMWL intersection is Fig. 9 Estimation of equilibrium pressure and temperature in groundwater samples of the coastal plain enriched in comparison to values from the theoretical determined precipitation after Craig and Gordon (1965). The deviation between the two indicates that sub-cloud evaporation of falling raindrops that enriches the precipitation falling to the ground, play a role.
Mixtures of groundwater of group 1 and 2 (Sect. 4.2.1, groundwater) are not necessarily obvious. The springs of Om Dalfa (Sample H8 and H9) lie within the basement rock of the Red Sea Hills. The isotope values of these springs are depleted in comparison to values of sample H2 that is also situated in the basement rock. An explanation of this deviation was brought up by Sultan et al. (2011) who found depleted groundwaters within subsided blocks that connected aquifers bearing fossil and modern groundwaters in a research area north west of of El Gouna. In Fig. 4a, sample H1 and P8 deviate from the position of the fossil groundwater from group 3 (Sect. 4.2.1, groundwater). The trend towards the LMWL and the minor deviation in δ 18 O and δ 2 H compared to the fossil groundwaters imply a minor influence from modern groundwaters. The spring of Melaha (Sample H4) plot within the fossil groundwaters of group 3 of the deep wells (see Fig. 4a). Despite its location near by the Red Sea it is neither influenced by modern groundwaters nor by seawater intrusion since this would result in enriched isotope values. Evaporation of the emerging water from the Melaha spring produces enriched stream water (Sample H5). Interpolation of a evaporation line with 60% relative humidity connects sample H4 with sample H5 in Fig. 4a confirming the direct link between the two.
The coastal plain group wells show a different chemical evolution pattern and different groundwater temperatures. The group itself shows in Fig. 5b differences in the concentrations between the northern part and the southern part along the short distance (Jahnke et al. 2019). The EC value decreases from well P4 (19.6 mS/cm) to well P7 (7 mS/cm). The higher salinity in the northern wells can be explained through the possible mixing with the spring water (sample H4). The fault system seems to have different hydraulic conductivities along the locations of the wells. The less hydraulic conductivity is evident with the lower yield of the northern wells in the coastal plain. The lower salinity in the southern wells can be explained with a better conductivity of the faults linking the deep depressions SW of Abu Shaar as proven by Sultan et al. (2011). It is to expect that no seawater intrusion influences the deep wells because of the barrier function of the faults along the Red Sea margin. As long as a gradient exists in the groundwater table between the deep wells and the big sediment accumulations in Wadi El Melaha, the deep wells will be supplied. Winckler et al (2001) investigated three deep brine locations at different depths along the Red Sea: the young southern spreading part known as Discovery Deep (Cochran et al. 1986), the central transition part or Atlantis II Deep and the northern part or Kebrit Deep. The three deeps are located at a distance of around 450 km. The investigated area is west to the Kebrit Deep which is located between 23°20′ N and 29°57′ N and represents the pre stage of seafloor spreading in development of the continental margin (Bonatti 1985;Winckler et al. 2001). The mantle He contribution with 9% in Kebrit deep brine accumulates according to Winckler et al. (2001) migrates from deeper sedimentary or crustal horizons. The Ra for this brine has values in the range between 1.06.10 -6 and 1.69.10 -6 . In contrast to the spreading zones in the centre of the Red Sea Graben system, the strike slip fault of its shoulder west of Hurghada has a much lower permeability because it is under pressure. Consequently, the amount of He from the mantle may not exceed the analysed 2%. Figure 10 shows the Abu Shaar Fault which runs parallel to the deep wells in the coastal plain group. The block east of the fault is part of the Red Sea Graben system and slipped some hundred meters down. Due to the pressure the fault is a barrier and the groundwater flowing from east to west following the morphological gradient is rising up along the fault. Sea water intrusion in wells east of the fault would be difficult. West of Abu Shaar mountains, the NNW striking Wadi Melah extending 60 km to the north and ending south of Abu Shaar takes place and it could be the main area for inflow. An oasis did exist in former time in front of Abu Shaar Mountain with a captured spring (Bir Abu Shaar) described and shown on a picture ( Fig. 2; Madgwick et al. 2016). The fault continues southward and run off from the Red Sea hills recharges the porous aquifers west of the fault mainly at the mountain foot from a 7-8 years precipitation event. The recharge for the shallow wells seems to be dependent on rising groundwater too, as it cannot pass the impermeable barrier.

Conclusion
The main concluding remarks are as follows: The collected floodwater in the area is mainly influenced by the rainwater/rock interaction and reflects the variability of rocks in the region which influence concentrations of the sampled water. 3 H activity at all sampled locations is under the detection limit. The stable isotopes and hydrochemical parameters confirm that groundwater in the region is either recharged from modern precipitation, a mixture of groundwater recharged by modern precipitation and fossil groundwater or fossil groundwater. The deep wells of the coastal plain group with elevated temperatures up to 38 °C show a higher geothermal gradient at the fault zone of Abu Shaar Plateau. The magmatic He ratio of 2% confirms that the fault at the sampled wells transports deep hot water to the aquifer. There is no evidence for marine water intrusion in all deep wells west of the Red Sea which are located parallel to the fault along Abu Shaar Plateau and further south. This confirms the role of the fault at this location as a barrier against the ingress of seawater from the Red Sea. Further research may more precisely delineate more precise the recharge areas and help understand the groundwater flow pathways in determining their age.