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A Theoretical Investigation of the Configurations (3d + 4s)6 4p in Neutral Manganese (Mn i).

Experimental levels of the configurations (3d + 4s)64p in Mn i were compared with corresponding calculated values. On fitting 228 experimental levels by means of 20 free parameters an rms error of only 170 cm-1 was obtained. It was shown that the correction parameters β and T were not significant.