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EXAFS-Studies on 1,2-Dibromocyclohexane and 1,2-Dibromoethane in Organic Solvents — an Attempt to Determine Solvent Induced Conformational Changes

The extended X-ray absorption fine structure (EXAFS) of bromine has been used to study the different conformations of 1,2-dibromoethane and trans-l,2-dibromocyclohexane dissolved at 300 K in a variety of organic liquids with different polarity. It was the purpose of this study to investigate the solvent-solute interaction and to test the accessible range of distances in liquid disordered systems using EXAFS as a structural tool. Following standard procedures for data interpretation we found no significant dependence of conformation changes on the type of solvents in contrast to other spectroscopic methods.