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Lanthanide and yttrium uranosilicates : Synthesis and characterization

The first lanthanide and yttrium uranosilicates of composition A I I I (HSiUO 6 ) 3 . 10H 2 O (A I I I = Y, Ln) were synthesized hydrothermally using deposition from solution. The structure and properties of the uranosilicates were studied using X-ray diffraction, IR spectroscopy, and thermal analysis. Various crystal hydrates of the uranosilicates were identified. Their thermostability and thermolysis were studied.