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Design and synthesis of organic sensitizers with enhanced anchoring stability in dye-sensitized solar cells

Abstract D-π-A dyes have received a special attention in the field of dye-sensitized solar cells (DSSCs). In this kind of molecules, the acceptor group (A) generally acts as an anchor, enabling the adsorption of the dye onto the metal oxide substrate (TiO2) and providing a good electron injection. The search for new anchors represents a critical factor for the development of improved DSSCs and in recent years has been a very active research field. This mini-review focuses especially on our work on pyridine-derived anchoring groups for D-π-A dyes, with a special regard on the preparation and characterization of three different families of dyes and a critical evaluation of their stability and efficiency.