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Semiempirical/CI of the Excited States Characterization of Retinal Molecules

We report results from a semiempirical investigation of the charge distribution and dipole moments of the ground state and first excited states of the all - trans and 13- cis retinoic aldehydes. We also calculate the theoretical absorption spectra of these molecules at the INDO/S-CI level with geometrices fully optimized by the PM3/CI method.