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Studies on hydrogen embrittlement of nitrogen containing austenitic alloys

Abstract The influence of hydrogen on the mechanical properties of four austenitic CrNiMo and CrMn alloys with nitrogen contents up to 0.57 wt-% were investigated concerning their resistance against hydrogen embrittlement in correlation to nitrogen content, chemical composition, and hydrogen diffusivity and solubility. Tensile tests were carried out at room temperature and at strain rates between 10-4 and 10-6 s-1 with simultaneous hydrogen charging and after precharging to different hydrogen contents. The mechanical properties have been found to be dependent on both strain rate and hydrogen content in the material. Simultaneous hydrogen charging and mechanical testing have accelerated the failure process owing to a faster hydrogen uptake especially at low strain rates. Hydrogen has shown a softening effect in the elastic range of the stress strain curve, which becomes more pronounced with decreasing strain rate. The favoured mechanism of hydrogen damage of alloys with high nitrogen contents seems to be the hydrogen enhanced localised plasticity mechanism. A correlation between hydrogen embrittlement and stress corrosion cracking has been discussed. It has been established that both the damaging processes in nitrogen containing steels are influenced by the same mechanism.