{'fraction_non_alphanumeric': 0.03302752293577982, 'fraction_numerical': 0.010091743119266056, 'mean_word_length': 5.572289156626506, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 0, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
2D sp2 Carbon-conjugated Porphyrin Covalent Organic Framework for Cooperative Photocatalysis with TEMPO.

2D (two-dimensional) covalent organic frameworks (COFs) are receiving ongoing attention in semiconductor photocatalysis. Herein, we present a photocatalytic selective chemical transformation by combining sp 2 carbon-conjugated porphyrin-based covalent organic framework ( Por-sp 2 c-COF ) photocatalysis with TEMPO catalysis illuminated by 623 nm red light-emitting diodes (LEDs). Highly selective conversion of amines into imines were swiftly afforded in minutes. Specifically, the π-conjugation of porphyrin linker leads to extensive absorption of red light; the sp 2 -C=C- double bonds linkage ensures the stability of Por-sp 2 c-COF under high concentration of amine. More importantly, we found that crystalline framework of Por-sp 2 c-COF is pivotal for cooperative photocatalysis with TEMPO. This work foreshadows that the outstanding hallmarks of COFs, particularly crystallinity, could be exploited to address energy and environmental challenges by cooperative photocatalysis.