{'fraction_non_alphanumeric': 0.05235204855842185, 'fraction_numerical': 0.01896813353566009, 'mean_word_length': 4.995454545454545, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 1, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
Chemical vapour generation of transition metal volatile species for analytical purposes: determination of Zn by inductively coupled plasma-optical emission spectrometry.

Volatile species of Zn were generated by merging acidified aqueous samples and sodium tetrahydroborate(III) solution in a continuous flow system. The gaseous analyte was subsequently introduced via a stream of Ar carrier into the inlet tube of the plasma torch. Inductively coupled plasma optical emission spectrometry (ICP-OES) was used for detection. The operating conditions (chemical and physical parameters) and the concentrations of different inorganic (hydrochloric, nitric) and organic acids (acetic, citric, oxalic, tartaric) were evaluated for the efficient generation of Zn vapour. A detection limit (3sigma(blank)) of 4.6 ng mL(-1) was achieved. The precision (RSD) of the determination was 6.9% at a level of 250 ng mL(-1) and 4.7% for 1000 ng mL(-1) (n = 10). The efficiency of the generation process was estimated to be close to 50% in HCl. The possible interferent effect of transition metals (Cd, Co, Cu, Cr, Fe, Mn, Ni), hydride forming elements (As, Ge, Pb, Sb, Se) and Hg on Zn signal was examined. The method was validated by the determination of Zn in a certified reference material (CRM), NIST 1643d trace elements in water.