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Liquid-liquid Distribution of Selected Derivatives of Benzoic Acid in 1-Octanol-Toluene-Water Systems

The influence of 1-octanol on liquid-liquid distribution of chloro and methoxy derivatives of benzoic acid in toluene-water systems was presented. The values of partition constant (Kp) and dimerization constant (K d ) of investigated acids were calculated. It was found that raising of 1-octanol concentration in the mixture with toluene increases partition constants and decreases dimerization constants of the carboxylic acid.