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Synthesis and Luminescence Properties of a Blue-Emitting Sr3NaLu(PO4)3F:Eu2+ Phosphor

A novel blue-emitting Sr3NaLu (PO4)3F:Eu2+ phosphor for white light-emitting diodes (w-LEDs) have been successfully prepared via the solid-state reaction. The crystal structure and phase of the prepared phosphors were investigated using X-ray diffraction (XRD). The band gap of Sr3NaLu (PO4)3F was estimated to be about 5.79 eV from the diffuse reflection spectrum. The Sr3NaLu (PO4)3F:0.05Eu2+ phosphor exhibits an intense and broad excitation band ranging from 200 to 450 nm in the near ultraviolet region and produces a bright blue emission band with the CIE chromaticity coordinates of x = 0.133 and y = 0.148 under the excitation of 365 nm, which were ascribed to the 4f-5d transitions of Eu2+. Moreover, the fluorescence decay curves were also investigated in detail. All the results suggest that Sr3NaLu (PO4)3F:Eu2+ might be a promising blue-emitting phosphor used in w-LEDs.