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A macroscopic consitutive model on induced anisotropy for polymers with weighting functions

The alignment of polymer chains is a well known microstructural evolution effect due to straining of polymers. This has a drastic influence on the macroscopic properties of the initially isotropic material, such as a pronounced strength in the loading direction of stretched films. Experiments on strain induced anisotropy at room temperature are analyzed by optical measurements. For modeling the effect of strain induced anisotropy a macroscopic constitutive model is presented. As a key idea, weighting functions are introduced to represent a strain‐softening/hardening‐effect to account for induced anisotropy. These functions represent the ratio between the total strain rate and a structural tensor. In this way, material parameters are used as a sum of weighted direction related quantities. In the finite element examples we simulate the cold‐forming of amorphous thermoplastic films below the glass transition temperature subjected to different re‐loading directions. (© 2014 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim)