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Fabrication and characterization of nano-particulate PtCo media for ultra-high density perpendicular magnetic recording

The year-on-year growth in areal recording density maintained now for half a century by the hard disk industry has required a corresponding reduction in the size of the magnetic grains comprising the storage media employed. Grain dimensions are now such that the performance of materials which thus far have served the industry well can no longer be maintained as further reduction in their volume risks breaching the superparamagnetic limit with the attendant loss of data integrity. The high magnetocrystalline anisotropy of the Ll0 phase of PtCo allows particles as small as 4 nm diameter to remain magnetically stable in the elevated temperature environment typical of disk drive systems. A non-interacting dispersion of nanomagnetic particles suspended in an inert non-magnetic host such that each has its anisotropy axis directed perpendicular to the surface of the medium now constitutes the new ideal for a recording medium. Fabrication by a novel combination of conventional sputtering and thermal processing technologies of a medium closely approximating this ideal is demonstrated. An optimized two-stage fabrication process produces a near mono-dispersion of particles with magnetic activation volumes centred about 5 × 10−26 m−3 and crystallized in the L10 phase with an orientated tetragonal structure. The characteristics of this medium are discussed as a function of composition and crystalline structure. In the absence of a thermally assisted recording head, experiments are conducted on a degraded form of the medium that is shown to support perpendicular recording at linear densities in excess of 240 kfci (D50 point).