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Temperature-adaptive radiative coating for all-season household thermal regulation

Description A passive turnoff Passive radiative cooling technology uses the infrared atmospheric window to allow outer space to be a cold sink for heat. However, this effect is one that is only helpful for energy savings in the warmer months. Wang et al. and Tang et al. used the metal-insulator transition in tungsten-doped vanadium dioxide to create window glass and a rooftop coating that circumvents this problem by turning off the radiative cooling at lower temperatures. Because the transition is simply temperature dependent, this effect also happens passively. Model simulations suggest that these materials would lead to energy savings year-round across most of the climate zones in the United States. —BG A smart radiative coating automatically switches thermal radiation power in response to ambient temperature. The sky is a natural heat sink that has been extensively used for passive radiative cooling of households. A lot of focus has been on maximizing the radiative cooling power of roof coating in the hot daytime using static, cooling-optimized material properties. However, the resultant overcooling in cold night or winter times exacerbates the heating cost, especially in climates where heating dominates energy consumption. We approached thermal regulation from an all-season perspective by developing a mechanically flexible coating that adapts its thermal emittance to different ambient temperatures. The fabricated temperature-adaptive radiative coating (TARC) optimally absorbs the solar energy and automatically switches thermal emittance from 0.20 for ambient temperatures lower than 15°C to 0.90 for temperatures above 30°C, driven by a photonically amplified metal-insulator transition. Simulations show that this system outperforms existing roof coatings for energy saving in most climates, especially those with substantial seasonal variations.