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Adsorption and Reduction of Cr(VI) Together with Cr(III) Sequestration by Polyaniline Confined in Pores of Polystyrene Beads.

The simultaneous reduction and sequestration of Cr(VI) from wastewater is desirable as a cost-effective and environmentally friendly approach. In this study, we execute a one-step facile synthesis strategy on polyaniline (PANI) composites based on aniline adsorption and polymerization on pores of millimeter-scale polystyrene balls (PANI@PS). The well-defined PANI@PS increased the removal capacity of Cr(VI) by 5.4 times, going from 43.6 (bulky PANI) to 233.7 mg g-1 near neutral pH (6.0) instead of the pH 1-3 documented in other reports, which was higher than that of many reported adsorbents due to its porous structure, numerous interaction sites, and confinement effects in the polymer. Most importantly, PANI@PS could efficiently sequester positive Cr(III) after reducing Cr(VI) to Cr(III) due to its negative surface created by confinement effects confined to the nanopores of PS. Conversely, positively charged bulky PANI repelled electrostatically positive Cr(III); thus, additional precipitation or adsorption treatments were needed in practical applications. Moreover, a coating of PANI can protect PS, as a substrate and a composite, from irreversible damage due to the strong oxidation capacity of Cr(VI), which is another major concern in adsorbing strong oxidants using polymers. A novel strategy to regenerate the exhausted PANI@PS was efficiently executed based on the electrochemical redox reversibility of PANI. Finally, the comprehensive adsorption/reduction/sequestration of Cr on PANI@PS was elucidated in detail.