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Canting angle dependence of single-chain magnet behaviour in chirality-introduced antiferromagnetic chains of acetate-bridged manganese(III) salen-type complexes.

Canted antiferromagnetism (AFM) is considered an effective tool for designing single-chain magnets (SCMs) in homometallic chain systems. The family of manganese(iii) (MnIII) salen-type Schiff-base complexes is an outstanding building-unit candidate for designing SCMs because such complexes possess relatively large uniaxial magnetic anisotropy in the out-of-plane direction. However, SCM behaviour in simple alternating chains based on monomeric MnIII salen-type complexes has not been studied extensively. Herein, we report the SCM behaviour of canted AFM in an alternating chain of an acetate-bridged MnIII salen-type complex.