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Investigate the influence of halloysite and activated carbon mixtures in phytostabilization of Pb-contaminated soil with Lolium perenne L.

Abstract A pot experiment was conducted to investigate the effects of halloysite and activated carbon mixtures on the biomass and distribution of macronutrients (Mg, K, Ca, Na, P) in ryegrass grown in Pb-contaminated soil. The soil was spiked with four different levels of lead contamination, i.e. 0 (control), 200, 400, 800 mg·kg−1 were applied in an analytical grade Pb(NO3)2 solution mixed thoroughly with the soil. Raw halloysite (3%) and activated carbon (1% relative to soil mass) mixtures were used to reduce the effect of soil lead contamination. Ryegrass of the Bokser variety was harvested after 42 days, and soil samples were collected for laboratory tests. The mixture of sorbents applied in the experiment which turned out to be most effective at doses of lead amounting to 400 and 800 mg·kg−1 of soil, with the increase in the yield of ryegrass being the highest. Increasing contamination of soil with lead in the series without the mixture of sorbents increased the contents of phosphorus, sodium, calcium and magnesium in ryegrass. The applied mixture of halloysite and activated carbon changed the macronutrient concentration in ryegrass, with the greatest changes found in that of potassium and sodium.