{'fraction_non_alphanumeric': 0.05654761904761905, 'fraction_numerical': 0.03125, 'mean_word_length': 5.533980582524272, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 0, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
A New Polymeric Barium-Iron (III) Complex with Chain and Large Ring Structure

The compound {[Ba6(Phen)12(CF3COO)6{Fe(CN)6}2(H2O)8]·6 H2O}n (1) (Phen = 1,10-phenanthroline) has been synthesized and structurally characterized. In the crystal structure, the two consecutive Ba centres are bridged through trifluoroacetate groups and also via cyano groups of [Fe(CN)6]3− and form the zigzag chain resulting the formation of 24-membered ring structure. The Ba-centres are 8-fold coordinated with distorted cubic geometry. Six H2O molecules per asymmetric unit remain in the structure without any direct interaction with the metal atoms but they act in hydrogen bond formation.