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Complementary branching ratios by satellite excitation.

It is shown that if a state autoionizes to produce a fraction, B, of products in an excited ionic state, then one can obtain the complementary fraction, 1‐B, by exciting the character of a different autoionizing state, but at the location of the first state’s resonance. This structure will appear as a satellite to the second state with a branching ratio that depends on the first state only. This behavior is illustrated using the 6pns and 6pnd autoionizing states of barium.