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Theoretical approach to estimate Molecular Polarizability and Diamagnetic Susceptibility of 6O.CB and 10O.CB Mesogens

296 DOI: 10.37398/JSR.2022.660131 Abstract: In the present work, phase transition temperatures of hexyloxy and decyloxy cyanobiphenyl liquid crystal compounds are recorded by using Differential Scanning Calorimeter. These temperatures are needed in determining molecular polarizabilities by theoretical approaches viz, Lippincott δ function and Molecular vibration techniques. The molecular polarizabilities attained by the above two approaches are found to be same. The mean Polarizability and diamagnetic susceptibility depend on the number of free electrons which participate in magnetic and optical interactions. Based on these concepts the diamagnetic susceptibilities are evaluated by Rao’s and Pascal’s methods. In both these cases the diamagnetic susceptibility is found to be comparable.