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Impact of Kerogen Heterogeneity on Sorption of Organic Pollutants. 1. Sorbent Characterization

The overall goal of the present study was to establish correlations between organic pollutant sorption and physicochemical properties of kerogen materials. Three coal samples, each representing a typical kerogen type, were used as the starting materials. A thermal technique was employed to treat the kerogen materials under seven different temperatures ranging from 200 to 500C to simulate different diagenetic history. These samples were systematically characterized for their chemical compositions, functionalities, physical rigidity, and optical properties. The results showed that the chemical, spectroscopic, and optical microscopic properties of each kerogen series changed consistently as a function of treatment temperature or kerogen maturation. The oxygen‐to‐carbon atomic ratio decreased from 0.29, 0.12, and 0.07 for the original lignite (XF0), fusinite (HZ0), and lopinite (LP0) samples, respectively, to 0.07, 0.06, and 0.04 for XF7, HZ7, and LP7, respectively, that underwent the highest temperature treatment. The hydrogen‐to‐carbon atomic ratio exhibited similar reducing trend, which is consistent with the aromaticity increasing from 45 to 58% of the original samples to 76 to 81% of highly mature samples. Under the fluorescence microscope, the organic matrix changed from yellow (original lignite sample) and red‐brown (original lopinite sample) to colorless for the samples of higher maturation. The measured reflecting index increased from the original samples to the highly mature samples. Moreover, the original and the slightly matured samples exhibited very different chemical compositions and structural units among the three types due to the difference in their source materials. As the kerogen maturation increased, such differences decreased, indicating highly mature kerogen became homogenized regardless of the source material.