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Relative mobility of screw versus edge dislocations controls the ductile-to-brittle transition in metals

Significance This work uncovers the mystery of ductile-to-brittle transition (DBT) in body-centered cubic (BCC) metals. Temperature-dependent dislocation mobility and dislocation nucleation have been proposed as the potential factors responsible for the DBT. However, there is no compelling explanation as to why the smooth/gradual temperature-dependent kink-pair formation always gives rise to an abrupt DBT. We discover that the ratio of screw dislocation velocity to edge dislocation velocity is a controlling factor responsible for the DBT. A sufficiently high relative mobility is a prerequisite for the coordinated movement of screw and edge segments to sustain dislocation multiplication. The study offers fundamental insights into the deformation mechanism of BCC metals. Body-centered cubic metals including steels and refractory metals suffer from an abrupt ductile-to-brittle transition (DBT) at a critical temperature, hampering their performance and applications. Temperature-dependent dislocation mobility and dislocation nucleation have been proposed as the potential factors responsible for the DBT. However, the origin of this sudden switch from toughness to brittleness still remains a mystery. Here, we discover that the ratio of screw dislocation velocity to edge dislocation velocity is a controlling factor responsible for the DBT. A physical model was conceived to correlate the efficiency of Frank–Read dislocation source with the relative mobility of screw versus edge dislocations. A sufficiently high relative mobility is a prerequisite for the coordinated movement of screw and edge segments to sustain dislocation multiplication. Nanoindentation experiments found that DBT in chromium requires a critical mobility ratio of 0.7, above which the dislocation sources transition from disposable to regeneratable ones. The proposed model is also supported by the experimental results of iron, tungsten, and aluminum.