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Multiplet Structure in X-Ray p-Shell Photoelectron Spectra of Titanium and Vanadium Compounds

The exact calculation of multiplet structure arising from the interaction of d -electrons with a p -hole created in both the 2 p - and 3 p -shell X-ray photoemission spectroscopy and the high-resolution spectroscopy of the X-ray K α- and K β-emission of titanium and vanadium compounds is presented.