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A Study of the Proton Transfer of Chloro substituted Benzoic Acids in Water DMF Mixtures Compared With the Same Process in the Gaseous Phase

A study on the proton transfer process from chloro substituted benzoic acids to benzoic acid in H 2O DMF mixtures compared with the same process in the gaseous phase is presented. A thermodynamic cycle was used to calculate changes of some thermodynamic properties for a proton transfer process in a solvent X which refers to a gaseous initial thermodynamic state, i.e. δΔ P i g→X . Values of this term have been assumed as a measure of “environmental” interactions of the proton transfer process among molecules, anions and solvent.