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Lateral Resolution and Signal to Noise Ratio in Electrostatic Force Detection Based on Scanning Probe Microscopy

The lateral resolution (LR) and signal-to-noise ratio (SNR) are the essential factors in the applications of scanning probe microscopy in quantitative measurement of surface charge distribution, potential profile, and dielectric properties. We use a model system to comprise Au nanoparticles (NPs) embedded in a polystyrene (PS) matrix to study the effects of various experimental parameters, such as modulation bias voltage, tip-sample distance, and actual tip shape, on the electrostatic interactions between the tips and samples. The results show that LR and SNR decrease when the tip-sample distance increases, while SNR increases with tip modulation voltage. LR is less sensitive to tip modulation voltage, but shows complex dependence on the sample geometric structure. In combination with a numerical simulation based on the integral capacitance model, the electrostatic force interaction between tip and sample was quantitatively analyzed.