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Structure of D2 in zeolite.

We have measured the structure of D[sub 2] adsorbed in zeolite 13[ital X] at temperatures in the range 5.5 to 80 K at a variety of fillings. We find that the D[sub 2] molecules adsorb into well-defined adsorbtion sites in the zeolite structure. Two distinct adsorbtion sites, with binding energies on the order of 40 and 80 K, have been identified. No evidence for bulklike liquid or solid behavior of the D[sub 2] adsorbed in the pores has been observed. Once the adsorbtion sites are saturated D[sub 2] is no longer adsorbed into the pores and forms a bulk phase on the surface of the zeolite.