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Understanding titanium carbide nanoparticle formation by an underwater electrical explosion process through experimental and modeling studies

A new approach has been presented herein to prepare nano titanium carbide based on the underwater electrical explosion approach. Scanning electron microscopy and x-ray photoelectron spectroscopy were used to investigate the morphology and composition of the electrical explosion products. A numerical model was established to investigate the nanoparticle formation process. The results show that the average diameter of the formed nanoparticles was ∼60 nm and approximately conformed to a lognormal distribution. Compared with the nanoparticles prepared by electrical explosion in gas, the nanoparticles prepared by the underwater electrical explosion had a smaller size distribution range and better sphericity. During the formation process of nanoparticles, the distribution of nanoparticles formed in a narrow temperature range near the specific temperature directly determined the characteristics of the final electrical explosion products. The specific temperature was ∼3400 K, which was also the specific temperature of the saturation ratio, the nucleation rate, the average diameter of the formed nuclei, the number of monomers, and the number of the formed nanoparticles. The diameters of nanoparticles obtained in the experiment were mainly concentrated between 50 and 70 nm, and the calculated diameters of the nanoparticles were mainly concentrated between 55 and 65 nm; therefore, the data obtained through the model were consistent with the experimental ones. These provide a way to synthesize the nano titanium carbide and a method to estimate their size and distribution, and it is hoped for understanding the evolution of the titanium wire underwater electrical explosion and the formation of nanoparticles.A new approach has been presented herein to prepare nano titanium carbide based on the underwater electrical explosion approach. Scanning electron microscopy and x-ray photoelectron spectroscopy were used to investigate the morphology and composition of the electrical explosion products. A numerical model was established to investigate the nanoparticle formation process. The results show that the average diameter of the formed nanoparticles was ∼60 nm and approximately conformed to a lognormal distribution. Compared with the nanoparticles prepared by electrical explosion in gas, the nanoparticles prepared by the underwater electrical explosion had a smaller size distribution range and better sphericity. During the formation process of nanoparticles, the distribution of nanoparticles formed in a narrow temperature range near the specific temperature directly determined the characteristics of the final electrical explosion products. The specific temperature was ∼3400 K, which was also the specific temperatu...