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Electrooxidation of 5,6-dihydroxytryptamine in aqueous and micellar media

Electrochemical oxidation of neurotoxin 5,6-dihydroxytryptamine has been studied in aqueous and micellar media. In both the media oxidation occurs in two well-defined, pH dependent peaks involving 4e, 4H + in peak I a and2e, 2H + in peak II a respectively. The spectral studies and products identification corresponding to peak II a have been carried out in aqueous and micellar media at pH 2.8. The Ep and ip of the oxidation peaks have been found to be dependent on the nature and concentration of surfactants and the observed changes have been explained.