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Synthesis and Characterization of Phosphonic-Acrylic Organogels

Polymeric organogels based on vinyl phosphonic acid (VPA) and acrylic monomers such as 2-acrylamido 2-methyl propane sulfunic acid (AMPS) and acrylamide (AM) were prepared. The synthesized poly (AMPS-VPA) organgels can absorb ethanol (12.64–31.2 g/g) and methanol (17.65–32.32 g/g). Poly (AM-VPA) can absorb DMSO (4.05–8.94 g/g). TGA analysis showed that thermal stability of organogels was improved with enhancement of VPA content. This was attributed to presence of phosphorus in the polymer structure. Rheological behavior exhibited that gel strength was decreased with higher VPA content in copolymeric structures.