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Application of Pitzer equations for quaternary systems: sodium chloride-sodium nitrate-sodium acetate-water and potassium chloride-potassium nitrate-potassium acetate-water at 25.degree.C

Electromotive force measurements were carried out on the NaCl-NaNO 3 -NaOAc-H 2 O and KCl-KNO 3 - KOAc-H 2 0 systems at constant total ionic stress of 0.5, 1.0, 2.0, and 3.0 mol/kg and at 25 o C using a cell consisting of a sodium ion-selective electrode or potassium ion-selective electrode and an Ag/AgCl electrode. The results were analyzed in terms of the Harned equation and by the Pitzer formalism