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Hydrous SiO2 in subducted oceanic crust and water transport to the core-mantle boundary


 Subduction of oceanic lithosphere transports surface water into the mantle where it can have remarkable effects, but how much can be cycled down into the deep mantle, and potentially to the core, remains ambiguous. Recent studies show that dense SiO2 in the form of stishovite, a major phase in subducted oceanic crust at depths greater than ~300 km, has the potential to host and carry water into the lower mantle. We investigate the hydration of stishovite and its higher-pressure polymorphs, CaCl2-type SiO2 and seifertite, in experiments at pressures of 44–152 GPa and temperatures of ~1380–3300 K. We quantify the water storage capacity of these dense SiO2 phases at high pressure and find that water stabilizes CaCl2-type SiO2 to pressures beyond the base of the mantle. We parametrize the P-T dependence of water capacity and model H2O storage in SiO2 along a lower mantle geotherm. Dehydration of slab mantle in cooler slabs in the transition zone can release fluids that hydrate stishovite in oceanic crust. Hydrous SiO2 phases are stable along a geotherm and progressively dehydrate with depth, potentially causing partial melting or silica enrichment in the lower mantle. Oceanic crust can transport ~0.2 wt% water to the core-mantle boundary region where, upon heating, it can initiate partial melting and react with the core to produce iron hydrides, providing plausible explanations for ultra-low velocity regions at the base of the mantle.