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Influence of the Surface Chemistry and Dynamics on an Elasticity-Dependent Macroscopic Supramolecular Assembly

Macroscopic supramolecular assembly (MSA) investigates multivalent supramolecular interactions between large surfaces (exceeding a size of 10 μm) modified with numerous interactive motifs. Because MSA is the first step to initiate noncovalent interactions at the interface, study of MSA mechanism is significant for various interfacial phenomena such as underwater adhesion, cell-material interaction, self-healing etc. Until now, most researches about MSA mainly report some assembly phenomena by applying molecular interactions into macroscopic assembly, insight into the underlying assembly mechanism is still lacking, e. g. fundamental questions such as what kind of building blocks or surface chemistry is requisite to realize MSA remains to be answered. Especially, multiple variables including surface chemistry, substrate effects, interaction dynamics etc. are significant factors to influence MSA behaviors. Previously we have revealed a rule that the MSA probability declines with increasing substrate rigidity...