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Solid-state effects on nonradiative decay of 4d94f1 states in barium halides.

The nonradiative decay of 4d 9 4f 1 states in barium halides was investigated by using resonant-photoemission spectroscopy. Constant-final-state spectra with the final state at N 4,5 -O 2,3 O 2,3 Auger electron peak and constant-initial-state (CIS) spectra with the initial state at Ba 5p levels were enhanced in the Ba 4d excitation-energy region, indicating Auger and direct recombination decay processes, respectively