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Microscale electrohydrodynamic printing of in situ reactive features for patterned ZnO nanorods

Patterning of zinc oxide (ZnO) nanorods has attracted considerable interests to enhance the performance of ZnO-based functional devices. Most of the existing techniques for patterned ZnO nanorods are based on conventional microfabrication methods that commonly require cleanroom environment, high-cost equipment and complicated processes. In this study, electrohydrodynamic (EHD) printing strategy was accommodated to fabricate microscale ZnO nanorods patterns based on in situ reactive inks. Smaller working voltage and larger nozzle-to-collector distance facilitated the formation of thinner PEO-Zn(NO3)2 filaments, which were decomposed into ZnO nanoparticles to serve as the seeding template for the hydrothermal growth of ZnO nanorods. The resultant ZnO nanorods can be flexibly tuned by the EHD printed patterns. The effect of growth time on the size and morphology of ZnO nanorods was investigated. Compared with the spin-coating method, the photoelectrochemical property of patterned ZnO nanorods was well controlled and showed enhanced photoelectrochemical stability. The presented method provides a flexible and rapid way to customize patterned ZnO nanorods that can be potentially used in the fields of optical detectors, biosensors or solar-driven devices.