{'fraction_non_alphanumeric': 0.03009259259259259, 'fraction_numerical': 0.008101851851851851, 'mean_word_length': 5.455223880597015, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 0, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
Synthesis of NH-Sulfoximines Using Recyclable Hypervalent Iodine (III) Reagents under Aqueous Micellar Conditions.

The synthesis of NH-sulfoximines from sulfides has been first developed under a mild, sustainable condition in an aqueous solution with surfactant TPGS-750-M as the catalyst at room temperature. In this newly developed process, a simple and convenient recyclable strategy to regenerate the indispensable hypervalent iodine(III) was utilized. The resulting 1,2,3-trifluoro-5-iodobezene could be recovered almost quantitively from the mixture by liquid-liquid extraction, and then oxidized to the corresponding iodine (III) species. This optimized protocol is compatible with a broad range of functional groups and could be easily performed on a gram scale. Thus, this novel method provides a new and green protocol for the synthesis of sulfoximines.