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Mechanisms of Diffusional Nucleation of Nanocrystals and Their Self‐Assembly into Uniform Colloids

We survey our research on modeling the mechanisms of control of uniformity in the growth of nanosize and colloid size particles. The former are produced as nanocrystals by burst nucleation from solution and the latter are formed by self‐assembly (aggregation) of the nanocrystals. In the colloid particle synthesis, the two dynamical processes are coupled, both governed by diffusional transport of the respective building blocks (monomers). The interrelation of the two processes allows for the synthesis of narrow size distribution colloid dispersions, which are of importance in many applications. We first review a mathematical model of diffusive cluster growth by the capture of monomer “singlets.” We then analyze burst nucleation of nanoparticles in solution. Finally, we couple it to the secondary process of aggregation of nanoparticles to form colloids and discuss various aspects of the modeling of particle size distribution, as well as other features of the processes considered.