(IO)  Patent No.:  US 8,663,607 B2  (45)  Date of Patent:  Mar. 4, 2014  c12)  United States Patent  Monzyk et al.  ( 54)  FERRATE(VI)-CONTAINING  COMPOSITIONS AND METHODS OF USING  FERRATE(VI)  (75)  Inventors:  Bruce  F.  Monzyk,  Delaware, OH (US);  Michael J. Murphy,  Dublin, OH (US);  Chad Cucksey,  Worthington, OH (US);  F.  Michael von Fahnestock,  Columbus,  OH (US);  Andrew J. Savage,  Dublin,  OH (US);  David N. Clark,  Los Lunas,  NM(US)  (73)  Assignee:  Battelle Memorial Institute,  Columbus,  OH (US)  ( *)  Notice:  Subject to any disclaimer, the term of this  patent is extended or adjusted under 35  U.S.C. 154(b) by 625 days.  (21)  Appl. No.:  12/529,540  (22)  PCT Filed:  Mar. 10, 2008  (86)  PCT No.:  PCT /US2008/056446  § 371 (c)(l),  (2), ( 4) Date:  Mar. 5, 2010  (87)  PCT Pub. No.:  WO2008/112657  (60)  Provisional application No. 60/893,929, filed on Mar.  9, 2007, provisional application No. 60/946,134, filed  on Jun.  25,  2007,  provisional application No.  60/946,940, filed on Jun. 28, 2007.  (51)  Int. Cl.  (52)  U.S. Cl.  USPC ...............  424/52;  424/49; 424/646; 510/109;  510/191; 510/276  ( 58)  Field of Classification Search  None  See application file for complete search history.  FOREIGN PATENT DOCUMENTS  OTHER PUBLICATIONS  (57)  ABSTRACT  6 Claims, 1 Drawing Sheet  (65)  Prior Publication Data  Related U.S. Application Data  (56)  References Cited  U.S. PATENT DOCUMENTS  3,372,125  A  3/1968 Hill  3,704,227  A  * 11/1972 Hill ............................... 510/117  A61K 8121  A61K 8/30  A61Q 11100  A61K 8/00  A61K 8/18  A01N59/16  A61K 33/26  C11D3/20  CllD 17100  C11D3/37  (2006.01)  (2006.01)  (2006.01)  (2006.01)  (2006.01)  (2006.01)  (2006.01)  (2006.01)  (2006.01)  (2006.01)  3,904,421 A  4,156,613 A  4,225,352  A  4,243,494 A  4,256,551  A  4,606,843  A  4,705,726  A  5,284,642  A  5,416,150 A  5,607,504  A  6,080,288  A  6,267,896 Bl  6,471,788 Bl  6,566,574 Bl  6,576,346 Bl  6,723,890 B2  6,837,984 B2  6,899,769 B2  6,899,956 B2  7,045,024 B2  7,045,051 B2  7,291,217 B2  7,347,893 B2  7,387,671 B2  7,387,672 B2  7,410,536 B2  7,422,793 B2  2002/0098989 Al  2003/0042134 Al  2003/0055245 Al  2003/0124065 Al*  2003/0146169 Al  2003/0159942 Al  2004/0104377 Al  2004/0216637 Al  9/1975 Shimizu et al.  5/1979 Hund  9/1980 Makino et al.  1/1981  Riggs, Jr. et al.  3/1981 Cliff et al.  8/1986 Kaczur  11/1987 Shindou et al.  2/ 1994 Evrard et al.  5/1995 Boeck  3/ 1997 Schmid et al.  6/2000 Schwartz et al.  7/2001  Patterson et al.  10/2002 Minevski et al.  5/2003 Tadros et al.  6/2003 Ravenscroft et al.  4/2004 Tucker et al.  1/2005 Wang et al.  5/2005 Ravenscroft et al.  5/2005 Block et al.  5/2006 Minevski et al.  5/2006 Minevski et al.  11/2007 Phelps et al.  3/2008 Low  6/2008 Meisen et al.  6/2008 Friedrich  8/2008 Friedrich et al.  9/2008 Phelps et al.  7/2002 Heimann et al.  3/2003 Tremblay et al.  3/2003 Tseng et al.  7/2003 Majeti et al. .................... 424/49  8/2003 Ciampi et al.  8/2003 Minevski et al.  6/2004 Phelps et al.  11/2004 Buchheit et al.  PCT Pub. Date:  Sep. 18, 2008  US 2011/0268672 Al  Nov. 3, 2011  Compositions containing ferrate(VI) are disclosed. Also,  methods are disclosed that utilize ferrate(VI).  Primary Examiner  - James D Anderson  Assistant Examiner  - William Lee  (74)  Attorney, Agent, or Firm  - Yimei C.  Hammond;  Kremblas & Foster  (Continued)  Bouzek, K., Rousar,  I.: "The StudyofElectrochemical Preparation of  Ferrate(VI) Using Alternating Current Superimposed on the Direct  Current Frequency Dependence of Current Yields". Electrochimica  Acta, vol. 38, No. 13, 1993, pp. 1717-1720.  Bouzek, K., Lipovska, M., Schmidt, M., Rousar,  I., Wragg, A.A.:  "Electrochemical Production ofFerrate(VI) Using Sinusoidal Alter› nating Current Superimposed on Direct Current: Grey and White  Cast Iron Electrodes". Electrochimica Acta, vol. 44 (1998) pp. 547- 557.  Svanks, "Oxidation of Ammonia in Water by Ferrates (VI) and (IV)",  Project Completion Report No. 444, Jun. 1976.*  Audette, R.J., Quail, J.W.: "Potassium, Rubidium, Cesium, and  Barium Ferrates(VI). Preparations, Infrared Spectra, and Magnetic  Susceptibilities". Inorganic Chemistry, [Online], vol. 11, No. 8, Aug.  1972, XP002569971 DOI: 10.1021/ic50114a034 [retrieved on Feb.  23,2010].  (Continued)  CN  DE  1524595  553004  9/2004  5/1943  (Continued)  US008663607B2 