240  US 9,423,690 B2  239  The resins (P-1) to (P-4), (P-6) to (P-14), (P-16), (P-22),  (P-24) to (P-26), (P-28) to (P-38), (P-42) to (P-44), (P-47),  (P-51), (P-53), (P-57), (P-61) to (P-64), (P-66), (P-71) to  (P-73), (P-77), (P-78) to (P-91) were synthesized in the same  manner as in resin (P-5). The synthesized polymer structure  is described previously as specific examples.  In addition, the weight average molecular weight (Mw)  and the polydispersity (Mw/Mn) of each resin, which was  synthesized as described above and will be used in the  Examples being described later, are shown in the following  table.  As for the Comparative Examples, the following resin  C-1  was synthesized according to the above-described  method and used in the Examples as described below. The  polymer structure, the weight average molecular weight  (Mw) and the polydispersity (Mw/Mn) of resin C-1 are  shown below. Further, the composition ratio of each repeat› ing unit of the polymer structure is shown in the molar ratio.  [Hydrophobic Resin]  The hydrophobic resin was appropriately selected from  the above-examplified hydrophobic resins HR-1 to HR-34  and then used.  Hereinafter, the composition ratio (molar ratio)  of  the  hydrophobic resin, the weight average molecular weight  (Mw) and the polydispersity (Mw/Mn) will be described.  [Photo-Acid Generator]  The photo-acid generator was appropriately selected from  the above-examplified acid generators zl to z141, and then  used.  TABLE 3  Added  Composition Ratio  %  Weight average  poly- polymer  (From left)  molecular weight  dispersity  HR-1  90  10  8000  1.5  HR-24  50  50  20000  1.6  HR-28  80  30  5000  1.45  HR-29  10  90  12000  1.47  P-66  P-78  P-79  P-80  P-81  P-82  P-83  P-84  P-85  Weight average  mloecular weight  13000  14000  13500  15000  14500  16000  15000  20000  19000  Polydispersity  1.57  1.61  1.60  1.54  1.52  1.58  1.55  1.75  1.72  TABLE 2  TABLE 1  P-1  P-2  P-3  P-4  P-5  P-6  P-7  P-8  P-9  P-10  P-11  P-12  P-13  P-14  P-16  P-22  P-24  P-25  P-26  P-28  P-29  P-30  P-31  P-32  P-33  P-34  P-35  P-36  P-37  P-38  P-42  P-43  P-44  P-47  P-51  P-53  P-57  P-61  P-62  P-63  P-64  P-71  P-72  P-73  P-77  Weight average  mloecular weight  12500  12000  Polydispersity  1.55  1.51  11500  13000  12000  11000  12500  12000  11500  12000  18000  7000  16500  14500  20000  7500  12000  17500  15500  14000  17000  17500  19000  10000  10500  5000  18000  14000  28000  25000  11500  12000  9500  8000  16500  15000  13000  10000  11000  10500  13000  12000  13000  14000  15000  1.50  1.58  1.52  1.48  1.44  1.38  1.36  1.45  1.67  1.49  1.62  1.78  1.75  1.56  1.48  1.68  1.57  1.60  1.60  1.63  1.67  1.44  1.53  1.44  1.45  1.66  1.76  1.89  1.44  1.49  1.51  1.46  1.60  1.85  1.52  1.54  1.46  1.47  1.50  1.51  1.55  1.58  1.60  TABLE 2-continued  Weight average  mloecular weight  Polydispersity  P-86  22000  1.82  P-87  21000  1.80  P-88  15000  1.50  P-89  13000  1.44  P-90  14000  1.46  P-91  16000  1.58  •:t•  0  0~  •:t•  0  0  CN  0  0  Mw: 10000  Mw/Mn:1.60  ~OH  HO  OH  C-1 