Magnetic phases evolution in the LaMn1-xFexO3+y system
  We have investigated the crystal structure and magnetic properties for polycrystalline samples of LaMn1-xFexO3+y, in the whole range x=0.0 to x=1.0, prepared by solid state reaction in air. All samples show the ORT-2 orthorhombic structure that suppresses the Jahn-Teller distortion, thus favoring a ferromagnetic (FM) superexchange (SE) interaction between Mn^{3+}-O-Mn^{3+}. For x=0.0 the oxygen excess (y ~ 0.09) produces vacancies in the La and Mn sites and generates a fraction around 18% of Mn^{4+} ions and 82% of the usual Mn^{3+} ions, with possible double exchange interaction between them. The Fe doping in this system is known to produce only stable Fe^{3+} ions. We find an evolution from a fairly strong FM phase with a Curie temperature T_{C} ~ 160 K, for x=0.0, to an antiferromagnetic (AFM) phase with T_{N} = 790 K, for x=1.0, accompanied by clear signatures of a cluster-glass behavior. For intermediate Fe contents a mixed-phase state occurs, with a gradual decrease (increase) of the FM (AFM) phase, accompanied by a systematic transition broadening for 0.2 < x < 0.7. A model based on the expected exchange interaction among the various magnetic-ion types, accounts very well for the saturation-magnetization dependence on Fe doping. 
O. F. de Lima (1), J. A. H. Coaquira (2), R. L. de Almeida (3), L. B.   de Carvalho (3) and S. K. Malik (3) ((1)Instituto de...