Defect Induced Photoluminescence from Dark Excitonic States in   Individual Single-Walled Carbon Nanotubes
  We show that new low-energy photoluminescence (PL) bands can be created in semiconducting single-walled carbon nanotubes by intense pulsed excitation. The new bands are attributed to PL from different nominally dark excitons that are "brightened" due to defect-induced mixing of states with different parity and/or spin. Time-resolved PL studies on single nanotubes reveal a significant reduction of the bright exciton lifetime upon brightening of the dark excitons. The lowest energy dark state has longer lifetimes and is not in thermal equilibrium with the bright state. 
Hayk Harutyunyan, Tobias Gokus, Alexander A. Green, Mark C. Hersam,   Maria Allegrini, Achim Hartschuh