Stochastic and deterministic molecular dynamics derived from the   time-independent Schr\"odinger equation
  Ehrenfest, Born-Oppenheimer, Langevin and Smoluchowski dynamics are shown to be accurate approximations of time-independent Schr\"odinger observables for a molecular system avoiding caustics, in the limit of large ratio of nuclei and electron masses, without assuming that the nuclei are localized to vanishing domains. The derivation, based on a Hamiltonian system interpretation of the Schr\"odinger equation and stability of the corresponding Hamilton-Jacobi equation, bypasses the usual separation of nuclei and electron wave functions, includes crossing electron eigenvalues, and gives a different perspective on the Born-Oppenheimer approximation, Schr\"odinger Hamiltonian systems, stochastic electron equilibrium states and numerical simulation in molecular dynamics modeling. 
Anders Szepessy