Magnetoelectric polarizability and axion electrodynamics in crystalline   insulators
  The orbital motion of electrons in a three-dimensional solid can generate a pseudoscalar magnetoelectric coupling $\theta$, a fact we derive for the single-particle case using a recent theory of polarization in weakly inhomogeneous materials. This polarizability $\theta$ is the same parameter that appears in the "axion electrodynamics" Lagrangian $\Delta{\cal L}_{EM} = (\theta e^2 / 2 \pi h) {\bf E} \cdot {\bf B}$, which is known to describe the unusual magnetoelectric properties of the three-dimensional topological insulator ($\theta=\pi$). We compute $\theta$ for a simple model that accesses the topological insulator and discuss its connection to the surface Hall conductivity. The orbital magnetoelectric polarizability can be generalized to the many-particle wavefunction and defines the 3D topological insulator, like the IQHE, in terms of a topological ground-state response function. 
Andrew M. Essin, Joel E. Moore, David Vanderbilt