Unique Phase Transition on Spin-2 Triangular Lattice of Ag2MnO2
  Ag2MnO2 is studied as a possible candidate compound for an antiferromagnetic XY spin model on a triangular lattice. In spite of the large Curie-Weiss temperature of -430 K found in magnetic susceptibi-lity, Mn3+ spins with S = 2 do not undergo a conventional long-range order down to 2 K probably owing to the geometrical frustration and two dimensionality in the system. Instead, a unique phase transition is found at 80 K, where specific heat exhibits a clear sign of a second-order phase transition, while magnetic susceptibility changes smoothly without a distinct anomaly. We think that this transition is related to the chirality degree of freedom associated with a short-range order, which has been expected for the classical XY spin model on a triangular lattice. On further cooling, spin-glass-like behavior is observed below 22 K, possibly corresponding to a quasi-long-range order. 
Hiroyuki Yoshida, Sascha Ahlert, Martin Jansen, Yoshihiko Okamoto,   Jun-Ichi Yamaura, and Zenji Hiroi