Stimulating the production of deeply bound RbCs molecules with laser   pulses: the role of spin-orbit coupling in forming ultracold molecules
  We investigate the possibility of forming deeply bound ultracold RbCs molecules by a two-color photoassociation experiment. We compare the results with those for Rb_2 in order to understand the characteristic differences between heteronuclear and homonuclear molecules. The major differences arise from the different long-range potential for excited states. Ultracold 85Rb and 133Cs atoms colliding on the X^1Sigma+ potential curve are initially photoassociated to form excited RbCs molecules in the region below the Rb(5S) + Cs(6P_1/2) asymptote. We explore the nature of the Omega=0^+ levels in this region, which have mixed A^1Sigma^+ and b^3Pi character. We then study the quantum dynamics of RbCs by a time-dependent wavepacket (TDWP) approach. A wavepacket is formed by exciting a few vibronic levels and is allowed to propagate on the coupled electronic potential energy curves. For a detuning of 7.5 cm-1, the wavepacket for RbCs reaches the short-range region in about 13 ps, which is significantly faster than for the homonuclear Rb_2 system; this is mostly because of the absence of an R^-3 long-range tail in the excited-state potential curves for heteronuclear systems. We give a simple semiclassical formula that relates the time taken to the long-range potential parameters. For RbCs, in contrast to Rb_2, the excited-state wavepacket shows a substantial peak in singlet density near the inner turning point, and this produces a significant probability of deexcitation to form ground-state molecules bound by up to 1500 cm-1. Our analysis of the role of spin-orbit coupling concerns the character of the mixed states in general and is important for both photoassociation and stimulated Raman deexcitation. 
Subhas Ghosal, Richard J. Doyle, Christiane P. Koch and Jeremy M.   Hutson