Is the silicate emission feature only influenced by grain size?
  The flattening of the 10mu silicate emission feature observed in the spectra of T Tauri and Herbig Ae/Be stars is usually interpreted as an indicator of grain growth. We show in this paper that a similar behaviour of the feature shape occurs when the porosity of composite grains varies. The fluffy aggregates, having inclusions of different sizes, were modeled by multi-layered spheres consisting of amorphous carbon, amorphous silicate and vacuum. It is also found that the inclusion of crystalline silicates in composite porous particles can lead to a shift of the known resonances and production of new ones. 
N.V. Voshchinnikov, Th.Henning