Numerical approximation of a reaction-diffusion system with fast   reversible reaction
  We consider the finite volume approximation of a reaction-diffusion system with fast reversible reaction. We deduce from a priori estimates that the approximate solution converges to the weak solution of the reaction-diffusion problem and satisfies estimates which do not depend on the chemical kinetics factor. It follows that the solution converges to the solution of a nonlinear diffusion problem, as the size of the volume elements and the time steps converge to zero while the kinetic rate tends to infinity. 
R. Eymard, D. Hilhorst and M. Olech