Small values of the Lusternik-Schnirelmann category for manifolds
  We prove that manifolds of Lusternik-Schnirelmann category 2 necessarily have free fundamental group. We thus settle a 1992 conjecture of Gomez-Larranaga and Gonzalez-Acuna, by generalizing their result in dimension 3, to all higher dimensions. We also obtain some general results on the relations between the fundamental group of a closed manifold M, the dimension of M, and the Lusternik-Schnirelmann category of M, and relate the latter to the systolic category of M. 
Alexander N. Dranishnikov, Mikhail G. Katz, and Yuli B. Rudyak