Correlation between spin helicity and electric polarization vector in   quantum-spin chain magnet LiCu$_2$O$_2$
  Measurements of polarized neutron scattering were performed on a $S=1/2$ chain multiferroic LiCu$_2$O$_2$. In the ferroelectric ground state with the spontaneous polarization along the c-axis, the existence of transverse spiral spin component in the $bc$-plane was confirmed. When the direction of electric polarization is reversed, the vector spin chirality as defined by ${\bf C}_{ij} = {\bf S}_i \times {\bf S}_j$ ($i$ and $j$ being the neighboring spin sites) is observed to be reversed, indicating that the spin-current model or the inverse Dzyaloshinskii-Moriya mechanism is applicable even to this $e_{\mathrm{g}}$-electron quantum-spin system. Differential scattering intensity of polarized neutrons shows a large discrepancy from that expected for the classical-spin $bc$-cycloidal structure, implying the effect of large quantum fluctuation. 
S. Seki, Y. Yamasaki, M. Soda, M. Matsuura, K. Hirota, and Y. Tokura