Resolving the chemistry in the disk of TW Hydrae I. Deuterated species
  We present Submillimeter Array (SMA) observations of several deuterated species in the disk around the classical T Tauri star TW Hydrae at arcsecond scales, including detections of the DCN J=3-2 and DCO+ J=3-2 lines, and upper limits to the HDO 3(1,2)-2(2,1), ortho-H2D+ 1(1,0)-1(1,1) and para-D2H+ 1(1,0)-1(0,1) transitions. We also present observations of the HCN J=3-2, HCO+ J=3-2 and H13CO+ J=4-3 lines for comparison with their deuterated isotopologues. We constrain the radial and vertical distributions of various species in the disk by fitting the data using a model where the molecular emission from an irradiated accretion disk is sampled with a 2D Monte Carlo radiative transfer code. We find that the distribution of DCO+ differs markedly from that of HCO+. The D/H ratios inferred change by at least one order of magnitude (0.01 to 0.1) for radii <30 AU to >70 AU and there is a rapid falloff of the abundance of DCO+ at radii larger than 90 AU. Using a simple analytical chemical model, we constrain the degree of ionization, x(e-)=n(e-)/n(H2), to be ~10^-7 in the disk layer(s) where these molecules are present. Provided the distribution of DCN follows that of HCN, the ratio of DCN to HCN is determined to be 1.7\pm0.5 \times 10^-2; however, this ratio is very sensitive to the poorly constrained vertical distribution of HCN. The resolved radial distribution of DCO+ indicates that {\it in situ} deuterium fractionation remains active within the TW Hydrae disk and must be considered in the molecular evolution of circumstellar accretion disks. 
C. Qi, D.J. Wilner, Y. Aikawa, G.A. Blake, and M.R. Hogerheijde