Interplay between Plasmon Luminescence and Vibrationally Resolved   Molecular Luminescence Induced by Scanning Tunneling Microscopy
  Effects of coupling between a molecular exciton and a surface plasmon (exciton-plasmon coupling) on the luminescence properties of the molecule and the surface plasmons are investigated using the nonequilibrium Green's function method. Molecular absorption and enhancement by molecular electronic and vibrational modes (molecular modes) lead to dip and peak structures in the luminescence spectra of the surface plasmons. These structures will correspond to the peak and dip structures observed in a recent experiment. We found that in addition to the molecular dynamics, the re-absorption by the surface plasmons plays important roles in determining the luminescence spectral profiles. 
Kuniyuki Miwa, Mamoru Sakaue, Hideaki Kasai
cond-mat.mtrl-sci physics.chem-ph