Gap like structure in a nonsuperconducting layered oxycarbonate   Bi$_{2+x}$Sr$_{4-x}$Cu$_2$CO$_3$O$_{8+\delta}$ single crystal
  The magnetic field and temperature dependence of the in-plane tunneling conductance $dI/dV(V)$ in high-quality nonsuperconducting (down to 10 mK) layered oxycarbonate Bi$_{2+x}$Sr$_{4-x}$Cu$_2$CO$_3$O$_{8+\delta}$ single crystals has been investigated using break junctions. Combining measurements of the in-plane magnetoresistivity $\rho_{ab}(T,H)$ and the magnetotunneling, we present evidence for the existence of a small "pseudogap" in a nonsuperconducting cuprate, without local incoherent pairs or any correlation phenomena associated with superconductivity. We are unable to distinguish if such a "pseudogap" is totally unrelated to superconductivity or if its existence is a necessary condition for the subsequent occurrence of superconductivity with increasing carrier density in the sample. 
S.I. Vedeneev, B.A. Piot and D.K. Maude
cond-mat.supr-con