Apparent Fracture in Polymeric Fluids under Step Shear
  Recent step strain experiments in well-entangled polymeric liquids demonstrated a bulk fracture-like phenomenon. We have studied this instability using a modern version of the Doi-Edwards theory for entangled polymers, and we find close quantitative agreement with the experiments. The phenomenon occurs because the viscoelastic liquid is sheared into a rubbery state that possesses an elastic constitutive instability (Marrucci and Grizzuti, 1983). The fracture is a transient manifestation of this instability, which relies on the amplification of spatially inhomogeneous fluctuations. This mechanism differs from fracture in glassy materials and dense suspensions. 
Okpeafoh S. Agimelen and Peter D. Olmsted
physics.flu-dyn cond-mat.soft