A topological crystalline insulator (TCI) phase via topological phase   transition and crystalline mirror symmetry
  A Z2 topological insulator protected by time-reversal symmetry is realized via spin-orbit interaction driven band inversion. For example, the topological phase in the Bi-Sb system is due to an odd number of band inversions. A related spin-orbit system, the (Pb/Sn)Te class, has been known to contain an even number of inversions based on band theory. Here we experimentally investigate the possibility of a mirror symmetry protected topological crystalline insulator phase in the (Pb/Sn)Te class of materials which has been theoretically predicted to exist in its non-alloyed version. Our experimental results show that at a finite-Pb composition above the topological inversion phase transition, the surface exhibits even number of spin-polarized Dirac cone states (as opposed to odd as observed in Bi-Sb alloy or Bi2Se3) revealing mirror protected topological order distinct from that observed in Bi-Sb or Bi2Se3. Our observation of the spin-polarized Dirac surface states in the inverted (Pb/Sn)Te and their absence in the non-inverted compounds related via a topological phase transition (spin-orbit induced band inversion type) provide the experimental groundwork for opening the research on novel topological order in future quantum devices. 
Su-Yang Xu, Chang Liu, Nasser Alidoust, M Neupane, D. Qian, I.   Belopolski, J. D. Denlinger, Y. J. Wang, H. Lin, L. A. Wray...
cond-mat.mes-hall