Taylor Dispersion with Adsorption and Desorption
  We use a stochastic approach to show how Taylor dispersion is affected by kinetic processes of adsorption and desorption onto surfaces. A general theory is developed, from which we derive explicitly the dispersion coefficients of canonical examples like Poiseuille flows in planar and cylindrical geometries, both in constant and sinusoidal velocity fields. These results open the way for the measurement of adsorption and desorption rate constants using stationary flows and molecular sorting using the stochastic resonance of the adsorption and desorption processes with the oscillatory velocity field. 
Maximilien Levesque and Olivier B\'enichou and Rapha\"el Voituriez and   Benjamin Rotenberg
cond-mat.stat-mech physics.flu-dyn