23Na NMR study of sodium order in NaxCoO2 with 22K Neel temperature
  We report a systematic study of the $c$ lattice parameter in the Na$_{x}$CoO$_{2}$ phases versus Na content $x>0.5$, in which sodium always displays ordered arrangements. This allows us to single out the first phase which exhibits an AF magnetic order at a N\'eel temperature $T_{N}=$22 K which is found to occur for $x\approx 0.77(1)$. Pure samples of this phase have been studied both as aligned powders and single crystals. They exhibit identical $^{23}$Na NMR spectra in which three sets of Na sites could be fully resolved, and are found to display $T$ dependencies of their NMR shifts which scale with each other. This allows us to establish that the $T$ variation of the shifts is due to the paramagnetism of the Co sites with formal charge state larger than 3$^{+}$. The existence of a sodium site with axial charge symmetry and the intensity ratio between the sets of $^{23}$Na lines permits us to reveal that the 2D structure of the Na order corresponds to 10 Na sites on top of a 13 Co sites unit cell, that is with $x=10/13\approx 0.77$. This structure fits with that determined from local density calculations and involves triangles of 3 Na sites located on top of Co sites (so called Na1 sites). The associated ordering of the Na vacancies is quite distinct from that found for $x<0.75$. 
H.Alloul, I. R. Mukhamedshin, A. V. Dooglav, Ya. V. Dmitriev, V.-C.   Ciomaga, L. Pinsard-Gaudart, G. Collin
cond-mat.str-el cond-mat.supr-con