Solid-state electronic spin coherence time approaching one second
  Solid-state electronic spin systems such as nitrogen-vacancy (NV) color centers in diamond are promising for applications of quantum information, sensing, and metrology. However, a key challenge for such solid-state systems is to realize a spin coherence time that is much longer than the time for quantum spin manipulation protocols. Here we demonstrate an improvement of more than two orders of magnitude in the spin coherence time ($T_2$) of NV centers compared to previous measurements: $T_2 \approx 0.5$ s at 77 K, which enables $\sim 10^7$ coherent NV spin manipulations before decoherence. We employed dynamical decoupling pulse sequences to suppress NV spin decoherence due to magnetic noise, and found that $T_2$ is limited to approximately half of the longitudinal spin relaxation time ($T_1$) over a wide range of temperatures, which we attribute to phonon-induced decoherence. Our results apply to ensembles of NV spins and do not depend on the optimal choice of a specific NV, which could advance quantum sensing, enable squeezing and many-body entanglement in solid-state spin ensembles, and open a path to simulating a wide range of driven, interaction-dominated quantum many-body Hamiltonians. 
Nir Bar-Gill, Linh M. Pham, Andrejs Jarmola, Dmitry Budker and Ronald   L. Walsworth
quant-ph cond-mat.mes-hall