The first detection of the 232 GHz vibrationally excited H2O maser in   Orion KL with ALMA
  We investigated the ALMA science verification data of Orion KL and found a spectral signature of the vibrationally excited H2O maser line at 232.68670 GHz (nu2=1, 5,5,0-6,4,3). This line has been detected in circumstellar envelopes of late-type stars so far but not in young stellar objects including Orion KL. Thus, this is the first detection of the 232 GHz vibrationally excited H2O maser in star-forming regions. The distribution of the 232 GHz maser is concentrated at the position of the radio Source I, which is remarkably different from other molecular lines. The spectrum shows a double-peak structure at the peak velocities of -2.1 and 13.3 km s-1. It appears to be consistent with the 22 GHz H2O masers and 43 GHz SiO masers observed around Source I. Thus, the 232 GHz H2O maser around Source I would be excited by the internal heating by an embedded protostar, being associated with either the root of the outflows/jets or the circumstellar disk around Source I, as traced by the 22 GHz H2O masers or 43 GHz SiO masers, respectively. 
Tomoya Hirota, Mi Kyoung Kim, and Mareki Honma
astro-ph.SR astro-ph.GA