Room temperature coherent spin alignment of silicon vacancies in 4H- and   6H-SiC
  We report the realization of the optically induced inverse population of the ground-state spin sublevels of the silicon vacancies ($V_{\mathrm{Si}}$) in silicon carbide (SiC) at room temperature. The data show that the probed silicon vacancy spin ensemble can be prepared in a coherent superposition of the spin states. Rabi nutations persist for more than 80 $\mu$s. Two opposite schemes of the optical alignment of the populations between the ground-state spin sublevels of the silicon vacancy upon illumination with unpolarized light are realized in 4H- and 6H-SiC at room temperature. These altogether make the silicon vacancy in SiC a very favorable defect for spintronics, quantum information processing, and magnetometry. 
Victor A. Soltamov, Alexandra A. Soltamova, Ivan I. Proskuryakov,   Pavel G. Baranov
cond-mat.mtrl-sci