Itinerant Nature of U 5f States in Uranium Mononitride UN Revealed by   Angle Resolved Photoelectron Spectroscopy
  The electronic structure of the antiferromagnet uranium nitride (UN) has been studied by angle resolved photoelectron spectroscopy using soft X-rays (hn=420-520 eV). Strongly dispersive bands with large contributions from the U 5f states were observed in ARPES spectra, and form Fermi surfaces. The band structure as well as the Fermi surfaces in the paramagnetic phase are well explained by the band-structure calculation treating all the U 5f electrons as being itinerant, suggesting that itinerant description of the U 5f states is appropriate for this compound. On the other hand, changes in the spectral function due to the antiferromagnetic transition were very small. The shapes of the Fermi surfaces in a paramagnetic phase are highly three-dimensional, and the nesting of Fermi surfaces is unlikely as the origin of the magnetic ordering. 
Shin-ichi Fujimori, Takuo Ohkochi, Tetsuo Okane, Yuji Saitoh, Atsushi   Fujimori, Hiroshi Yamagami, Yoshinori Haga, Etsuji Y...
cond-mat.str-el