Observation of Topological Crystalline Insulator phase in the lead tin   chalcogenide Pb1-xSnxTe material class
  We perform systematic angle-resolved photoemission spectroscopic measurements on the lead tin telluride Pb1-xSnxTe pseudobinary alloy system. We show that the (001) crystalline surface, which is a crystalline surface symmetric about the (110) mirror planes of the Pb1-xSnxTe crystal, pos- sesses four metallic surface states within its surface Brillouin zone. Our systematic Fermi surface and band topology measurements show that the observed Dirac-like surface states lie on the symmetric momentum-space cuts. We further show that upon going to higher electron binding energies, the surface states' isoenergetic countours in close vicinity of each X point are observed to hybridize with each other, leading to a Fermi surface fractionalization and the Lifshitz transition. In addition, systematic incident photon energy dependent measurements are performed, which enable us to un- ambiguously identify the surface states from the bulk bands. These systematic measurements of the surface and bulk electronic structure on Pb1-xSnxTe, supported by our first principles calculation results, for the first time, show that the Pb1-xSnxTe system belongs to the topological crystalline insulator phase due to the four band inversions at the L points in its Brillouin zone, which has been recently theoretically predicted. 
Su-Yang Xu, Chang Liu, N. Alidoust, D. Qian, M. Neupane, J. D.   Denlinger, Y. J. Wang, L. A. Wray, R. J. Cava, H. Lin, A. M...
cond-mat.mes-hall cond-mat.mtrl-sci