Structural Signature of a Brittle-to-Ductile Transition in   Self-Assembled Networks
  We study the nonlinear rheology of a novel class of transient networks, made of surfactant micelles of tunable morphology reversibly linked by block copolymers. We couple rheology and time-resolved structural measurements, using synchrotron radiation, to characterize the highly nonlinear viscoelastic regime. We propose the fluctuations of the degree of alignment of the micelles under shear as a probe to identify a fracture process. We show a clear signature of a brittle-to-ductile transition in transient gels, as the morphology of the micelles varies, and provide a parallel between the fracture of solids and the fracture under shear of viscoelastic fluids. 
Laurence Ramos, Arnaud Laperrousaz, Philippe Dieudonne, Christian   Ligoure
cond-mat.soft