Evolution of two-step structural phase transition in Fe1+dTe detected by   low-temperature x-ray diffraction
  The low-temperature crystal structure of Fe1.13Te, which exhibits an anomalous two-step magnetic transition, was clarified by the systematic x-ray diffraction measurements. It was found that two-step structural phase transition, tetragonal-orthorhombic-monoclinic, occurred correspondingly to the two-step magnetic transition. The detailed analysis of the profile at 5 K indicated the coexistence of the minor orthorhombic area inside the major monoclinic lattice, which could explain the lower-shift (suppression) of the antiferromagnetic transition temperature in Fe1.13Te and suggest a possibility of superconductivity at the domain boundary. 
Yoshikazu Mizuguchi, Kentaro Hamada, Kazuki Goto, Hiroshi Takatsu,   Hiroaki Kadowaki, Osuke Miura
cond-mat.supr-con