Tentative Detection of Deuterated Methane toward the Low-Mass Protostar   IRAS 04368+2557 in L1527
  The millimeter-wave rotational transition line ($J_K = 1_0 - 0_0$) of deuterated methane CH$_3$D has tentatively been detected toward the low-mass Class 0 protostar IRAS 04368+2557 in L1527 with the Heinrich Hertz Submillimeter Telescope. This is the first detection of CH$_3$D in interstellar clouds, if confirmed. The column density and fractional abundance of CH$_3$D are determined to be $(9.1\pm3.4) \times 10^{15}$ cm$^{-2}$ and $(3.0\pm1.1) \times 10^{-7}$, respectively, where we assume the rotational temperature of 25 K. The column density and fractional abundance of the gaseous CH$_4$ are estimated to be $(1.3-4.6) \times 10^{17}$ cm$^{-2}$ and $(4.3-15.2) \times 10^{-6}$, respectively, by adopting the molecular D/H ratios of 2--7% reported for various molecules in L1527. The fractional abundance of CH$_4$ is higher than or comparable to that found in high-mass star-forming cores by infrared observations. It is sufficiently high for triggering the efficient production of various carbon-chain molecules in a lukewarm region near the protostar, which supports the picture of the warm carbon-chain chemistry. 
Nami Sakai, Yancy L. Shirley, Takeshi Sakai, Tomoya Hirota, Yoshimasa   Watanabe, and Satoshi Yamamoto
astro-ph.SR