Suppression of Antiferroelectric State in NaNbO3 at High Pressure from   In Situ Neutron Diffraction
  We report direct experimental evidence of antiferroelectric to paraelectric phase transition under pressure in NaNbO3 using neutron diffraction at room temperature. The paraelectric phase is found to stabilize above 8 GPa and its crystal structure has been determined in orthorhombic symmetry with space group Pbnm. The variation of the structural parameters of the both orthorhombic phases as a function of pressure was determined. We have not found evidence for structural phase transition around 2 GPa as previously suggested in the literature based on Raman scattering experiments, however, significant change in Nb-O-Nb bond angles are found around this pressure. The response of the lattice parameters to pressure is strongly anisotropic with a largest contraction along <100>. The structural phase transition around ~ 8 GPa is followed by an anomalous increase in the orthorhombic strain and tilt angle associated with the R point (q= 1/2 1/2 1/2). Ab-initio calculation of the enthalpy in the various phases of NaNbO3 is able to predict the phase transition pressure well. 
S. K. Mishra, M. K. Gupta, R. Mittal, S. L. Chaplot and Thomas Hansen
cond-mat.mtrl-sci