H4O and other hydrogen-oxygen compounds at giant-planet core pressures
  Water and hydrogen at high pressure make up a substantial fraction of the interiors of giant planets. Using ab initio random structure search methods we investigate the ground-state crystal structures of water, hydrogen, and hydrogen-oxygen compounds. We find that, at pressures beyond 14 Mbar, excess hydrogen is incorporated into the ice phase to form a novel structure with H4O stoichiometry. We also predict two new ground state structures, P2_1/m and I4/mmm, for post-C2/m water ice. 
Shuai Zhang, Hugh Wilson, Kevin Driver, Burkhard Militzer
cond-mat.mtrl-sci astro-ph.EP