Superspin Glass Mediated Giant Spontaneous Exchange Bias in a   Nanocomposite of BiFeO$_3$-Bi$_2$Fe$_4$O$_9$
  We observe an enormous $\textit{spontaneous}$ exchange bias ($\sim$300-600 Oe) - measured in an unmagnetized state following zero-field cooling - in a nanocomposite of BiFeO$_3$ ($\sim$94%)-Bi$_2$Fe$_4$O$_9$ ($\sim$6%) over a temperature range 5-300 K. Depending on the path followed in tracing the hysteresis loop - positive (p) or negative (n) - as well as the maximum field applied, the exchange bias ($H_E$) varies significantly with $\mid-H_{Ep}\mid$ $>$ $\mid H_{En}\mid$. The temperature dependence of $H_E$ is nonmonotonic. It increases, initially, till $\sim$150 K and then decreases as the blocking temperature $T_B$ is approched. All these rich features appear to be originating from the spontaneous symmetry breaking and consequent onset of unidirectional anisotropy driven by "superinteraction bias coupling" between ferromagnetic core of Bi$_2$Fe$_4$O$_9$ (of average size $\sim$19 nm) and canted antiferromagnetic structure of BiFeO$_3$ (of average size $\sim$112 nm) via superspin glass moments at the shell. 
Tuhin Maity, Sudipta Goswami, Dipten Bhattacharya, Saibal Roy
cond-mat.mtrl-sci