Polarization Dependent Optical Control of Atomic Arrangement in   Multilayer Ge-Sb-Te Phase Change Materials
  We report the optical perturbation of atomic arrangement in the layered GeTe/Sb_{2}Te_{3} phase change memory material. To observe the structural change, the coherent A_{1} mode of GeTe_{4} local structure is investigated at various polarization angles of femtosecond pump pulses with the fluence at < 78 \mu J/cm^{2}. p-polarization found to be more effective in inducing the A_{1} frequency shift that can be either reversible or irreversible, depending on the pump fluence. The predominant origin of this shift is attributed to rearrangement of Ge atoms driven by anisotropic dissociation of the Ge-Te bonds along the [111] axis after the p-polarized pulse irradiation. 
Kotaro Makino, Junji Tominaga, Alexander V. Kolobov, Paul Fons, and   Muneaki Hase
cond-mat.mtrl-sci