Nanoscale domains in strained epitaxial BiFeO3 thin Films on LaSrAlO4   Substrate
  BiFeO3 thin films with various thicknesses were grown epitaxially on (001) LaSrAlO4 single crystal substrates using pulsed laser deposition. High resolution x-ray diffraction measurements revealed that a tetragonal-like phase with c-lattice constant ~4.65 {\AA} is stabilized by a large misfit strain. Besides, a rhombohedral-like phase with c-lattice constant ~3.99 {\AA} was also detected at film thickness of ~50 nm and above to relieve large misfit strains. In-plane piezoelectric force microscopy studies showed clear signals and self-assembled nanoscale stripe domain structure for the tetragonal-like regions. These findings suggest a complex picture of nanoscale domain patterns in BiFeO3 thin films subjected to large compressive strains. 
Zuhuang Chen, Lu You, Chuanwei Huang, Yajun Qi, Junling Wang,   Thirumany Sritharan and Lang Chen
cond-mat.mtrl-sci