Boundary effects in the gradient theory of phase transitions
  We consider the van der Waals' free energy functional, with a scaling small parameter epsilon, in the plane domain given by the first quadrant, and inhomogeneous Dirichlet boundary conditions. The boundary data are chosen in such a way that the interface between the pure phases tends to be horizontal and is pinned at some point on the y-axis which approaches zero as epsilon converges to zero. We show that there exists a critical scaling for the pinning point, such that, as the small parameter epsilon tends to zero, the competing effects of repulsion from the boundary and penalization of gradients play a role in determining the optimal shape of the (properly rescaled) interface. This result is achieved by means of an asymptotic development of the free energy functional. As a consequence, such analysis is not restricted to minimizers but also encodes the asymptotic probability of fluctuations. 
L. Bertini, P. Butt\`a, A. Garroni
math-ph math.AP math.MP