Violation of the zeroth law of thermodynamics for a non-ergodic   interaction
  The phenomenon described by our title should surprise no one. What may be surprising though is how easy it is to produce a quantum system with this feature; moreover, that system is one that is often used for the purpose of showing how systems equilibrate. The violation can be variously manifested. In our detailed example, bringing a detuned 2-level system into contact with a monochromatic reservoir does not cause it to relax to the reservoir temperature; rather, the system acquires the reservoir's level-occupation-ratio. 
B. Gaveau and L. S. Schulman
cond-mat.stat-mech quant-ph