Successive transition from superconducting to antiferromagnetic phase in   (Ca_6(Al, Ti)_4O_y)Fe_2As_2 studied via ^{75}As and ^{27}Al NMR
  An unusual successive phase transition from superconducting (SC) to antiferromagnetic (AF) phases was discovered via ^{75}As and ^{27}Al nuclear magnetic resonance (NMR) in (Fe_2As_2)(Ca_6(Al, Ti)_4O_y) with four (Al, Ti)O layers intercalated between FeAs planes. Although the spatially-uniform AF ordering is clearly visible from ^{27}Al spectra, the ordered moments are very small and the low-frequency fluctuation is much suppressed, contrary to existing pnictides with localized magnetic elements. Furthermore, the temperature (T) dependence of the fluctuation at both nuclei is very similar throughout the entire temperature range. These facts suggest that some hybridization between Ti and Fe orbitals induces a uniform electronic state within FeAs and (Al, Ti)O layers accompanied by the SC and AF transitions. The iron-based pnictide with Ti-doped blocking layers is the first high-T_c compound having metallic blocking layers. 
T. Nakano, N. Fujiwara, S. Tsutsumi, H. Ogino, K. Kishio and J.   Shimoyama
cond-mat.supr-con