Dissociative electron attachment and vibrational excitation of   $\mathbf{CF_3Cl}$: Effect of two vibrational modes revisited
  We present a study of dissociative electron attachment and vibrational excitation processes in electron collisions with the CF$_3$Cl molecule. The calculations are based on the two-dimensional nuclear dynamics including the C-Cl symmetric stretch coordinate and the CF$_3$ symmetric deformation (umbrella) coordinate. The complex potential energy surfaces are calculated using the ab initio R-matrix method. The results for dissociative attachment and vibrational excitation of the umbrella mode agree quite well with experiment while the cross section for excitation of the C-Cl symmetric stretch vibrations is about a factor of three low as compared to experimental data. 
Michal Tarana and Karel Houfek and Ji\v{r}\'i Hor\'a\v{c}ek and Ilya   I. Fabrikant
physics.chem-ph