Plasma Kinetics in the Ethanol/Water/Air Mixture in "Tornado" Type   Electrical Discharge
  This paper presents the results of a theoretical and experimental study of plasma-assisted reforming of ethanol into molecular hydrogen in a new modification of the "tornado" type electrical discharge. Numerical modeling clarifies the nature of the non-thermal conversion and explains the kinetic mechanism of nonequilibrium plasma-chemical transformations in the gas-liquid system and the evolution of hydrogen during the reforming as a function of discharge parameters and ethanol-to-water ratio in the mixture. We also propose a scheme of chemical reactions for plasma kinetics description. It is shown that some characteristics of the investigated reactor are at least not inferior to characteristics of other plasma chemical reactors. 
D. Levko, A. Shchedrin, V. Chernyak, S. Olszewski, O. Nedybaliuk
physics.plasm-ph physics.chem-ph