Resonant X-Ray Diffraction Study of Strongly Spin-Orbit-Coupled Mott   Insulator CaIrO3
  We performed resonant x-ray diffraction experiments at the $L$ absorption edges for the post-perovskite-type compound CaIrO$_{3}$ with $(t_{2g})^5$ electronic configuration. By observing the magnetic signals, we could clearly see that the magnetic structure was a striped order with an antiferromagnetic moment along the c-axis and that the wavefunction of a $t_{2g}$ hole is strongly spin-orbit entangled, the $J_{\rm eff} =1/2$ state. The observed spin arrangement is consistent with theoretical work predicting a unique superexchange interaction in the $J_{\rm eff} =1/2$ state and points to the universal importance of the spin-orbit coupling in Ir oxides, irrespective of the local coordination and lattice topology. We also propose that the non-magnetic resonant scattering is a powerful tool for unraveling an orbital state even in a metallic iridate. 
Kenya Ohgushi, Jun-ichi Yamaura, Hiroyuki Ohsumi, Kunihisa Sugimoto,   Soshi Takeshita, Akihisa Tokuda, Hidenori Takagi, Mas...
cond-mat.str-el