Strongly enhanced magnetic moments in ferromagnetic   FeMnP$_{0.50}$Si$_{0.50}$
  The compound FeMnP$_{0.50}$Si$_{0.50}$ has been studied by magnetic measurements, M\"ossbauer spectroscopy and electronic structure and total energy calculations. An unexpected high magnetic hyperfine field for Fe atoms located at the tetrahedral Me(1) site in the Fe$_2$P structure is found. The saturation moment derived from magnetic measurements corresponds to 4.4 $\mu_B$/f.u. at low temperatures, a value substantially higher than previously reported, but in accord with the results from our electron structure calculations. This high saturation moment, a first order nature of the ferromagnetic transition and a tunable transition temperature make the Fe$_{2-x}$Mn$_{x}$P$_{1-y}$Si$y$ system promising for magnetocaloric applications. 
Matthias Hudl, Lennart H\"aggstr\"om, Erna-Krisztina Delczeg-Czirjak,   Viktor H\"oglin, Martin Sahlberg, Levente Vitos, Oll...
cond-mat.mtrl-sci