Light-assisted ion-neutral reactive processes in the cold regime:   radiative molecule formation vs. charge exchange
  We present a combined experimental and theoretical study of cold reactive collisions between laser-cooled Ca+ ions and Rb atoms in an ion-atom hybrid trap. We observe rich chemical dynamics which are interpreted in terms of non-adiabatic and radiative charge exchange as well as radiative molecule formation using high-level electronic structure calculations. We study the role of light-assisted processes and show that the efficiency of the dominant chemical pathways is considerably enhanced in excited reaction channels. Our results illustrate the importance of radiative and non-radiative processes for the cold chemistry occurring in ion-atom hybrid traps. 
Felix H.J. Hall, Mireille Aymar, Nadia Bouloufa-Maafa, Olivier Dulieu,   and Stefan Willitsch
physics.atom-ph physics.chem-ph