Electronically excited cold ion crystals
  The laser excitation of an ion crystal to high lying and long-lived electronic states is a genuine many-body process even if in fact only a single ion is excited. This is a direct manifestation of the strong coupling between internal and external dynamics and becomes most apparent in the vicinity of a structural phase transition. Here we show that utilizing highly excited states offers a new approach to the coherent manipulation of ion crystals. This permits the study of phenomena which rely on a strong coupling between electronic and vibrational dynamics and opens up a route towards the quantum simulation of molecular processes in a Paul trap. 
Weibin Li and Igor Lesanovsky
physics.atom-ph quant-ph