Why is Understanding Glassy Polymer Mechanics So Difficult?
  In this Perspective, I describe recent work on systems in which the traditional distinctions between (i) unentangled vs. well-entangled systems and (ii) melts vs. glasses seem least useful, and argue for the broader use in glassy polymer mechanics of two more dichotomies: systems which possess (iii) unary vs. binary and (iv) cooperative vs. nonccoperative relaxation dynamics. I discuss the applicability of (iii-iv) to understanding the functional form of glassy strain hardening. Results from molecular dynamics simulations show that the "dramatic" strain hardening observed in densely entangled systems is associated with a crossover from unary, noncooperative to binary, cooperative relaxation as strain increases; chains stretch between entanglement points, altering the character of local plasticity. Promising approaches for future research along these lines are discussed. 
Robert S. Hoy
cond-mat.soft cond-mat.mes-hall cond-mat.mtrl-sci