Carbonyl Vibrational Wave Packet Circulation in Mn$_2$(CO)$_{10}$ Driven   by Ultrashort Polarized Laser Pulses
  The excitation of the degenerate $E_1$ carbonyl stretching vibrations in dimanganese decacarbonyl is shown to trigger wave packet circulation in the subspace of these two modes. On the time scale of about 5 picoseconds intramolecular anharmonic couplings do not cause appreciable disturbance, even under conditions where the two $E_1$ modes are excited by up to about two vibrational quanta each. The compactness of the circulating wave packet is shown to depend strongly on the excitation conditions such as pulse duration and field strength. Numerical results for the solution of the seven-dimensional vibrational Schr\"odinger equation are obtained for a density functional theory based potential energy surface and using the multi-configuration time-dependent Hartree method. 
Mahmoud K. Abdel-Latif and Oliver K\"uhn
quant-ph physics.chem-ph