Charge order at the frontier between the molecular and solid states in   Ba3NaRu2O9
  We show that the valence electrons of Ba3NaRu2O9, which has a quasi-molecular structure, completely crystallize below 210 K. Using an extended Hubbard model, we show that the charge ordering instability results from long-range Coulomb interactions. However, orbital ordering, metal-metal bonding and formation of a partial spin gap enforce the magnitude of the charge separation. The striped charge order and frustrated hcp lattice of Ru2O9 dimers lead to competition with a quasi-degenerate charge-melted phase under photo-excitation at low temperature. Our results establish a broad class of simple metal oxides as models for emergent phenomena at the border between the molecular and solid states. 
Simon A. J. Kimber, Mark S. Senn, Simone Fratini, Hua Wu, Adrian H.   Hill, Pascal Manuel, J. Paul Attfield, Dimitri N. Argy...
cond-mat.str-el