Formation of H$_3^-$ by radiative association of H$_2$ and H$^-$ in the   interstellar medium
  We develop the theory of radiative association of an atom and a diatomic molecule within a close-coupling framework. We apply it to the formation of H$_3^-$ after the low energy collision (below 0.5 eV) of H$_2$ with H$^-$. Using recently obtained potential energy and permanent dipole moment surfaces of H$_3^-$, we calculate the lowest rovibrational levels of the H$_3^-$ electronic ground state, and the cross section for the formation of H$_3^-$ by radiative association between H$^-$ and ortho- and para-H$_2$. We discuss the possibility for the H$_3^-$ ion to be formed and observed in the cold and dense interstellar medium in an environment with a high ionization rate. Such an observation would be a probe for the presence of H$^-$ in the interstellar medium. 
M. Ayouz (LAC), Raphael Lopes (LAC), Maurice Raoult (LAC), Olivier   Dulieu (LAC), V. Kokoouline (LAC, UCF)
physics.atom-ph astro-ph.GA quant-ph