Nuclear spin-lattice relaxation from fractional wobbling in a cone
  We consider nuclear spin-lattice relaxation rate resulted from a fractional diffusion equation for anomalous rotational wobbling in a cone. The mechanism of relaxation is assumed to be due to dipole-dipole interaction of nuclear spins and is treated within the framework of the standard Bloemberger, Purcell, Pound - Solomon scheme. We consider the general case of arbitrary orientation of the cone axis relative the magnetic field. The BPP-Solomon scheme is shown to remain valid for systems with the distribution of the cone axes depending only on the tilt relative the magnetic field but otherwise being isotropic. We consider the case of random isotropic orientation of cone axes relative the magnetic field taking place in powders. Also we consider the case of their predominant orientation along or opposite the magnetic field and that of their predominant orientation transverse to the magnetic field which may be relevant for, e.g., liquid crystals. Besides we treat in details the model case of the cone axis directed along the magnetic field. The latter provides direct comparison of the limiting case of our formulas with the textbook formulas for ordinary isotropic rotational diffusion. We show that the present model enables one to obtain naturally the well known power law for Larmor frequency dependence of the spin-lattice relaxation rate. The latter is observed in some complex systems. From this law the dependence of the fractional diffusion coefficient on the fractional index is obtained to have a rather simple functional form. The dependence of the spin-lattice relaxation rate on the cone half-width for the case of ordinary rotational diffusion yields results similar to those predicted by the model-free approach. 
A.E. Sitnitsky
cond-mat.stat-mech cond-mat.soft