Detection of the Li I 6104 Angstroem transition in the Population II   star HD 140283
  Lithium is one of the few primordially produced elements. The value of the primordial Li is taken to be that observed in metal--poor dwarfs, where it is not contaminated by stellar Li sources which act on longer time scales. The atmospheric abundance is currently derived from the LiI 6707 Angstroem resonance transition and the validity of the models employed has been questioned (Kurucz 1995). In this letter we report the first detection of the Li I 6104 Angstroem 2^2P - 3^2D subordinate transition in the prototype population II star HD 140283. The same Li abundance of (Li/H) =1.4x10^{-10} is found consistent with both the resonance and subordinate lines. The two lines form at different depths in the atmosphere implying that the 1-D homogeneous atmospheric models used in the abundance determination are essentially correct. When coupled with the standard big bang yields, the Li in the halo dwarfs provides two solutions for the baryon-to-photon ratio \eta_{10}= n_{b}/n_{\gamma} x 10^{10}and for the present baryon density \Omega_b h_{70}^2=0.0748\eta_{10}: a) a first solution at \eta_{10} about 1.8, consistent with the \eta_{10} implied by the high deuterium values D/H\approx 2 x 10^{-4}observed in some quasar absorption systems (Webb et al 1997) and b) a second solution at \eta_{10} about 4 which is consistent, within the errors, with the low deuterium D/H =3.4x10^{-5} measured in other quasar absorption systems (Burles & Tytler 1998). 
Piercarlo Bonifacio and Paolo Molaro