Multiphonon anharmonic decay of a quantum mode
  A nonperturbative theory of multiphonon anharmonic transitions between energy levels of a local mode is presented. It is shown that the rate of transitions rearranges near the critical level number $n_{cr}$: at smaller $n$ the process slows down, while at larger $n$ it accelerates in time, causing a jump-like loss of energy followed by the generation of phonon bursts. Depending on parameters, phonons are emitted in pairs, triplets etc. 
V.Hizhnyakov