Quantum chaos in multicharged ions and statistical approach to the   calculation of electron-ion resonant radiative recombination
  We show that the spectrum and eigenstates of open-shell multicharged atomic ions near the ionization threshold are chaotic, as a result of extremely high level densities of multiply excited electron states ($10^3 eV^{-1}$ in Au^{24+}) and strong configuration mixing. This complexity enables one to use statistical methods to analyse the system. We examine the dependence of the orbital occupation numbers and single-particle energies on the excitation energy of the system, and show that the occupation numbers are described by the Fermi-Dirac distribution, and temperature and chemical potential can be introduced. The Fermi-Dirac temperature is close to the temperature defined through the canonical distribution. Using a statistical approach we estimate the contribution of multielectron resonant states to the radiative capture of low-energy electrons by Au^{25+} and demonstrate that this mechanism fully accounts for the 10^2 times enhancement of the recombination over the direct radiative recombination, in agreement with recent experimental observations. 
G. F. Gribakin, A. A. Gribakina, and V. V. Flambaum (School of   Physics, The University of New South Wales, Sydney, Australia)