Kinky Behavior in Josephson Junctions
  We analyze nonperturbatively the behavior of a Josephson junction in which two BCS superconductors are coupled through an Anderson impurity. We recover earlier perturbative results which found that a $\delta=\pi$ phase difference is preferred when the impurity is singly occupied and the on-site Coulomb interaction is large. We find a novel intermediate phase in which one of $\delta=0$ and $\delta=\pi$ is stable while the other is metastable, with the energy $E(\delta)$ having a kink somewhere in between. As a consequence of the kink, the $I-V$ characteristics of the junction are modified at low voltages. 
A. V. Rozhkov and Daniel P. Arovas