Post-Newtonian Theory for Precision Doppler Measurements of Binary Star   Orbits
  The determination of velocities of stars from precise Doppler measurements is described here using relativistic theory of astronomical reference frames so as to determine the Keplerian and post-Keplerian parameters of binary systems. We apply successive Lorentz transformations and the relativistic equation of light propagation to establish the exact treatment of Doppler effect in binary systems both in special and general relativity theories. As a result, the Doppler shift is a sum of (1) linear in $c^{-1}$ terms, which include the ordinary Doppler effect and its variation due to the secular radial acceleration of the binary with respect to observer; (2) terms proportional to $c^{-2}$, which include the contributions from the quadratic Doppler effect caused by the relative motion of binary star with respect to the Solar system, motion of the particle emitting light and diurnal rotational motion of observer, orbital motion of the star around the binary's barycenter, and orbital motion of the Earth; and (3) terms proportional to $c^{-2}$, which include the contributions from redshifts due to gravitational fields of the star, star's companion, Galaxy, Solar system, and the Earth. After parameterization of the binary's orbit we find that the presence of periodically changing terms in the Doppler schift enables us disentangling different terms and measuring, along with the well known Keplerian parameters of the binary, four additional post-Keplerian parameters, including the inclination angle of the binary's orbit, $i$. We briefly discuss feasibility of practical implementation of these theoretical results, which crucially depends on further progress in the technique of precision Doppler measurements. 
S.M. Kopeikin and L.M. Ozernoy