Aluminum Abundances on the Red Giant Branch: Testing Helium Mixing as a   Second Parameter
  We present new data and discuss the relationship between the Al abundances on the red giant branches (RGBs) and the horizontal-branch (HB) morphologies of the second-parameter pair of globular clusters M3 and M13. Since Al is produced during RGB evolution inside the H-burning shell where He is synthesized, its overabundance in stellar atmospheres can indicate He mixing, which has been shown to be a viable second parameter in explaining HB morpohogies. 
R. M. Cavallo