Spitzer observations of acetylene bands in carbon-rich AGB stars in the   Large Magellanic Cloud
  We investigate the molecular bands in carbon-rich AGB stars in the Large Magellanic Cloud (LMC), using the InfraRed Spectrograph (IRS) on board the Spitzer Space Telescope (SST) over the 5--38 micron range. All 26 low-resolution spectra show acetylene (C2H2) bands at 7 and 14 micron. The hydrogen cyanide (HCN) bands at these wavelengths are very weak or absent. This is consistent with low nitrogen abundances in the LMC. The observed 14 micron C2H2 band is reasonably reproduced by an excitation temperature of 500 K. There is no clear dilution of the 14 micron band by circumstellar dust emission. This 14 micron band originates from molecular gas in the circumstellar envelope in these high mass-loss rate stars, in agreement with previous findings for Galactic stars. The C2H2,column density, derived from the 13.7 micron band, shows a gas mass-loss rate in the range 3x10^-6 to 5x10^{-5} Msun yr-1. This is comparable with the total mass-loss rate of these stars estimated from the spectral energy distribution. Additionally, we compare the line strengths of the 13.7 micron C2H2 band of our LMC sample with those of a Galactic sample. Despite the low metallicity of the LMC, there is no clear difference in the C2H2 abundance among LMC and Galactic stars. This reflects the effect of the 3rd dredge-up bringing self-produced carbon to the surface, leading to high C/O ratios at low metallicity. 
M. Matsuura, P.R. Wood, G.C. Sloan, A.A. Zijlstra, J.Th. van Loon,   M.A.T. Groenewegen, J.A.D.L. Blommaert, M.-R.L. Cioni, ...