Awaking of ferromagnetism in GaMnN through control of Mn valence
  Room temperature ferromagnetism of GaMnN thin films is awaked by a mild hydrogenation treatment of samples synthesized by molecular beam epitaxy. Local environment of Mn atoms is monitored by Mn-L2,3 near edge x-ray absorption fine structure (NEXAFS) technique. Doped Mn ions are present at substitutional sites of Ga both before and after the hydrogenation. No secondary phase can be detected. Major valency of Mn changes from +3 to +2 by the hydrogenation. The present result supports the model that the ferromagnetism occurs when Mn2+ and Mn3+ are coexistent and holes in the mid- gap Mn band mediate the magnetic coupling. 
Saki Sonoda, Isao Tanaka, Fumiyasu Oba, Hidekazu Ikeno, Hiroyuki   Hayashi, Tomoyuki Yamamoto, Yoshihiko Yuba, Ken'ichi Yosh...