3.6-7.9 um Photometry of L and T Dwarfs and the Prevalence of Vertical   Mixing in their Atmospheres
  We present new L' (3.75 um) photometry of six L and T dwarfs, and M' (4.70 um) photometry of ten L and T dwarfs, observed at Gemini Observatory, and new 3.55, 4.49, 5.73 and 7.87 um photometry of nine L and T dwarfs, obtained with the Spitzer Space Telescope. The sample includes unusually blue and red dwarfs from our near-infrared studies. The data are combined with published L', M' and Spitzer photometry of L and T dwarfs, and trends of colors with spectral type and other colors are examined. Model atmospheres by Marley and Saumon are used to generate synthetic colors for ranges of effective temperature, gravity, grain sedimentation efficiency, metallicity and vertical mixing efficiency. We explore how these parameters affect the mid-infrared colors of L and T dwarfs and find that the data are modelled satisfactorily only if substantial vertical mixing occurs in both L- and T-dwarf atmospheres. The location and range of the L and T dwarf sequences in IRAC color-color and color - magnitude diagrams is also only reproduced if this mixing occurs, with a range of efficiency described by K_zz ~ 10^2-10^6 cm^2/s. The colors of the unusually red dwarfs are best reproduced by non-equilibrium models with low sedimentation efficiency, i.e. thick cloud decks, and those of the unusually blue dwarfs by non-equilibrium models with high sedimentation efficiency, i.e. thin cloud decks. The K-L' and Spitzer [3.55]-[4.49] colors can be used as indicators of effective temperature for L and T dwarfs, but care must be taken to include gravity and metallicity effects for late-T dwarfs and vertical mixing for both late-L and T dwarfs. 
S. K. Leggett, D. Saumon, M. S. Marley, T. R. Geballe, D. A.   Golimowski, D. Stephens, X. Fan