Charge order and phonon renormalizations: Possible implications for   cobaltates
  Several experimental and theoretical studies in cobaltates suggest the proximity of the system to charge ordering (CO). We show, qualitatively, in the frame of a $t-V$ model coupled to phonons that optical phonon modes at the $K$ and $M$ points of the Brillouin zone, which involves only $O$-ions displacement around a $Co$-ion, are good candidates to display anomalies due to the CO proximity. If by increasing of $H_2O$ content the system is pushed closer to CO, the mentioned phonon modes should show softening and broadening. 
M. Bejas, A. Greco and A. Foussats