The antiferromagnetic insulator Ca3FeRhO6: characterization and   electronic structure calculations
  We investigate the antiferromagnetic insulating nature of Ca3FeRhO6 both experimentally and theoretically. Susceptibility measurements reveal a Neel temperature T_N = 20 K, and a magnetic moment of 5.3 muB/f. u., while Moessbauer spectroscopy strongly suggests that the Fe ions, located in trigonal prismatic sites, are in a 3+ high spin state. Transport measurements display a simple Arrhenius law, with an activation energy of 0.2 eV. The experimental results are interpreted with LSDA band structure calculations, which confirm the Fe 3+ state, the high-spin/low-spin scenario, the antiferromagnetic ordering, and the value for the activation energy. 
V. Eyert, U. Schwingenschloegl, R. Fresard, A. Maignan, C. Martin, N.   Nguyen, C. Hackenberger, and T. Kopp