Quantum coherence and population trapping in three-photon processes
  The spectroscopic properties of a single, tightly trapped atom are studied, when the electronic levels are coupled by three laser fields in an $N$-shaped configuration of levels, whereby a $\Lambda$-type level system is weakly coupled to a metastable state. We show that depending on the laser frequencies the response can be tuned from coherent population trapping at two-photon resonance to novel behaviour at three photon resonance, where the metastable state can get almost unit occupation in a wide range of parameters. For certain parameter regimes the system switches spontaneously between dissipative and coherent dynamics over long time scales. 
Caroline Champenois (PIIM), Giovanna Morigi (GRUP D'OPTICA), Juergen   Eschner (ICFO)