Metals and dust in high redshift AGNs
  We summarize some recent results on the metallicity and dust properties of Active Galactic Nuclei (AGN) at high redshift (1<z<6.4). By using the spectra of more than 5000 QSOs from the SDSS we find no evidence for any metallicity evolution in the redshift range 2<z<4.5, while there is a significant luminosity-metallicity dependence. These results are confirmed by the spectra of a smaller sample of narrow line AGNs at high-z (QSO2s and radio galaxies). The lack of metallicity evolution is interpreted both as a consequence of the cosmic downsizing and as a selection effect resulting from the joint QSO-galaxy evolution. The luminosity-metallicity relation is interpreted as a consequence of the mass-metallicity relation in the host galaxies of QSOs, but a relationship with the accretion rate is also possible. The lack of metallicity evolution is observed even in the spectra of the most distant QSOs known (z~6). This result is particularly surprising for elements such as Fe, C and Si, which are subject to a delayed enrichment, and requires that the hosts of these QSOs formed in short bursts and at very high redshift (z>10). The properties of dust in high-z QSOs are discussed within the context of the dust production mechanisms in the early universe. The dust extinction curve is observed to evolve beyond z>4, and by z~6 it is well described by the properties expected for dust produced by SNe, suggesting that the latter is the main mechanism of dust production in the early universe. We also show that the huge dust masses observed in distant QSOs can be accounted for by SN dust within the observational constraints currently available. Finally, we show that QSO winds, which have been proposed as an alternative mechanism of dust production, may also contribute significantly to the total dust budget at high redshift. 
R. Maiolino, T. Nagao, A. Marconi, R. Schneider, S. Bianchi, M.   Pedani, A. Pipino, F. Matteucci, P. Cox, P. Caselli