Spin singlet pairing in the superconducting state of NaxCoO2\cdot1.3H2O:   evidence from a ^{59}Co Knight shift in a single crystal
  We report a ^{59}Co Knight shift measurement in a single crystal of the cobalt oxide superconductor Na_{x}CoO_2\cdot1.3H_2O (T_c=4.25 K). We find that the shift due to the spin susceptibility, K^s, is substantially large and anisotropic, with the spin shift along the a-axis K^s_a being two times that along the c-axis K^s_c. The shift decreases with decreasing temperature (T) down to T\sim100 K, then becomes a constant until superconductivity sets in. Both K^s_a and K^s_c decrease below T_c. Our results indicate unambiguously that the electron pairing in the superconducting state is in the spin singlet form. 
Guo-qing Zheng, Kazuaki Matano, D.P. Chen, C.T. Lin