A chain coalgebra model for the James map
  Let EK be the simplicial suspension of a pointed simplicial set K. We construct a chain model of the James map, $\alpha_{K} : CK \to \Omega CEK$. We compute the cobar diagonal on $\Omega CEK$, not assuming that $EK$ is 1-reduced, and show that $\alpha_{K}$ is comultiplicative. As a result, the natural isomorphism of chain algebras $TCK \cong \Omega CK$ preserves diagonals.   In an appendix, we show that the Milgram map, $\Omega (A \otimes B) \to \Omega A \otimes \Omega B$, where A and B are coaugmented coalgebras, forms part of a strong deformation retract of chain complexes. Therefore, it is a chain equivalence even when A and B are not 1-connected. 
Kathryn Hess, Paul-Eugene Parent, Jonathan Scott