The physical conditions in IRDC clumps from Herschel HIFI observations   of H2O
  Context. The earliest phases of high-mass star formation are poorly understood.   Aims. Our goal is to determine the physical conditions and kinematic structure of massive star-forming cloud clumps.   Methods. We analyze H$_2$O 557 GHz line profiles observed with HIFI toward four positions in two infrared-dark cloud clumps . By comparison with ground-based C$^{17}$O, N$_2$H$^+$, CH$_3$OH and NH$_3$ line observations, we constrain the volume density and kinetic temperature of the gas and estimate the column density and abundance of H$_2$O and N$_2$H$^+$.   Results. The observed water lines are complex with emission and absorption components. The absorption is red shifted and consistent with a cold envelope, while the emission is interpreted as resulting from protostellar outflows. The gas density in the clumps is $\sim$ 10$^7$ cm$^{-3}$. The o-H2O outflow column density is 0.3 to 3.0 10$^{14}$ cm$^{-2}$, the o-H2O absorption column density is between 1.5 10$^{14}$ and 2.6 10$^{15}$ cm$^-2$ with cold o-H2O abundances between 1.5 10$^{-9}$ and 3.1 10$^{-8}$.   Conclusions. All clumps have high gas densities ($\sim$ 10$^7$ cm$^{-3}$) and display infalling gas. Three of the four clumps have outflows. The clumps form an evolutionary sequence as probed by H$_2$O N$_2$H$^+$, NH$_3$ and CH$_3$OH. We find that G28-MM is the most evolved, followed by G11-MM then G28-NH3. The least evolved clump is G11-NH3 which shows no sign-posts of star-formation. G11-NH3 is a high-mass pre-stellar core. 
Russell F. Shipman, Floris F.S van der Tak, Friedrich Wyrowski,   Fabrice Herpin and Wilfred Frieswijk
astro-ph.SR