Breakdown of time-temperature superposition in a bead-spring polymer   melt near the glass transition temperature
  The breakdown of the time-temperature superposition (TTS) near its glass transition temperature (Tg) in simple bead-spring polymer melts with and without the chain angle potential was numerically investigated. The stress relaxation modulus at different temperatures G(t,T) was calculated by the Green-Kubo relation. The TTS of G(t,T) of bead-spring polymer melts worked well at temperatures sufficiently higher than its Tg. However, when the system temperature is approaching the glass transition regime, the breakdown of TTS is observed. At temperatures near the Tg, the temperature dependence of the shift factor aTB, which is defined at the time scale between the bond relaxation and the chain relaxation regimes of a G(t)-function, is significantly stronger than ones aTA defined by the time scale of the chain relaxation modes. In direct relation to the breakdown of TTS of G(t,T), the decoupling of Stokes-Einstein law of diffusion-viscosity relation also appears in the glass transition regime. The analysis of the van Hove function Gs(r,t) and non-gaussian parameter, a2(t), of the bead motions strongly suggest that the TTS breakdown is concerned with the dynamic heterogeneity. The effect of the chain stiffness on the temperature dependence of the shift factors was also investigated in this study. The stiffer chains melt has a stronger temperature dependence of the shift factors than the ones of the flexible chains melt. However, regardless of the chain stiffness, the stress relaxation modulus functions of the bead-spring polymer melts will begin to breakdown the TTS at a similar Tg-normalized temperature around T/Tg ~ 1.2. 
Tamio Yamazaki
cond-mat.soft