Multipeak Negative Differential Resistance from Interplay between   Nonlinear Stark Effect and Double-Branch Current Flow
  Multipeak negative differential resistance (NDR) molecular devices are designed from first principles. The effect of NDR is associated with the non-linear Stark shifts and the electron localization within the conductive region and contacts. Deep I(V)-curve well is formed when the aromatic molecule, containing intramolecular hydrogen bond, is connected to each lead by the double-branch contacts. This effect occurs at the same voltage where a single-junction case exhibits only a flat step in the current characteristics. The multipeak oscillations arise from the mutual effect of the Stark shifts located at the electron-rich contacts and parts of the molecule - this opens the route for further tailoring the desired properties. 
Mikolaj Sadek, Malgorzata Wierzbowska, Michal F. Rode and Andrzej L.   Sobolewski
cond-mat.mes-hall