$\alpha$-RuCl3: a Spin-Orbit Assisted Mott Insulator on a Honeycomb   Lattice
  We examine the role of spin-orbit coupling in the electronic structure of $\alpha$-RuCl3, in which Ru ions in 4d5 configuration form a honeycomb lattice. The measured optical spectra exhibit a clear optical gap and excitations within the t2g orbitals. The spectra can be described very well with first-principles electronic structure calculations obtained by taking into account both spin orbit coupling and electron correlations. Furthermore, our X-ray absorption spectroscopy measurements at the Ru L-edges exhibit distinct spectral features associated with the presence of substantial spin- orbit coupling, as well as an anomalously large branching ratio. We propose that $\alpha$-RuCl3 is a spin-orbit assisted Mott insulator, and the bond-dependent Kitaev interaction may be relevant for this compound. 
K. W. Plumb, J. P. Clancy, L. Sandilands, V. Vijay Shankar, Y.F. Hu,   K. S. Burch, Hae-Young Kee, and Young-June Kim
cond-mat.str-el