Systematic trend of water vapour absorption in red giant atmospheres   revealed by high resolution TEXES 12 micron spectra
  The structures of the outer atmospheres of red giants are very complex. The notion of large optically thick molecular spheres around the stars (MOLspheres) has been invoked in order to explain e.g. spectro-interferometric observations. However, high-resolution spectra in the mid-IR do not easily fit into this picture. They rule out any large sphere of water vapour in LTE surrounding red giants. Our aim here is to investigate high-resolution, mid-infrared spectra for a range of red giants, from early-K to mid M. We have recorded 12 microns spectra of 10 well-studied bright red giants, with TEXES on the IRTF. We find that all giants in our study cooler than 4300 K, spanning a range of effective temperatures, show water absorption lines stronger than expected. The strengths of the lines vary smoothly with spectral type. We identify several spectral features in the wavelength region that undoubtedly are formed in the photosphere. From a study of water-line ratios of the stars, we find that the excitation temperatures, in the line-forming regions, are several hundred Kelvin lower than expected from a classical photospheric model. This could either be due to an actually lower temperature structure in the outer regions of the photospheres caused by, for example, extra cooling, or due to non-LTE level populations, affecting the source function and line opacities. We have demonstrated that these diagnostically interesting water lines are a general feature of red giants across spectral types, and we argue for a general explanation of their formation rather than explanations requiring specific properties. Since the water lines are neither weak (filled in by emission) nor appear in emission, as predicted by LTE MOLsphere models in their simplest forms, the evidence for the existence of such large optically-thick, molecular spheres enshrouding the stars is weakened. (abbreviated) 
N. Ryde, J. Lambert, M. Farzone, M. J. Richter, E. Josselin, G.M.   Harper, K. Eriksson, T. K. Greathouse
astro-ph.SR