Coronal lines and the importance of deep core-valence correlation in   Ag-like ions
  We report on large-scale and critically evaluated {\em ab initio} MCDHF calculations of the wavelength of the "coronal", M1 transition $4f\ ^2\mathrm{F}_{5/2}^o-^2\mathrm{F}_{7/2}^o$ in Ag-like ions. The transition between these two fine structure levels, which makes up the ground term for $Z \ge 62$ in the isoelectronic sequence, has recently been observed in Yb$^{23+}$ and W$^{27+}$, where the latter could be of great importance for fusion plasma diagnostics. We present recommended values for all members of the sequence between $Z = 50$ and $94$, which are supported by excellent agreement with values from recent experiments. The importance of including core-valence correlation with the $n=3$ shell in the theoretical model is emphasized. The results show close to spectroscopic accuracy for these forbidden lines. 
Jon Grumer, Ruifeng Zhao, Tomas Brage, Wenxian Li, Sven Huldt, Roger   Hutton, Yaming Zou
physics.atom-ph