Barlowite as a canted antiferromagnet: theory and experiment
  We investigate the structural, electronic and magnetic properties of the newly synthesized mineral barlowite Cu4(OH)6FBr which contains Cu2+ ions in a perfect kagome arrangement. In contrast to the spin-liquid candidate herbertsmithite ZnCu3(OH)6Cl2, kagome layers in barlowite are perfectly aligned due to the different bonding environments adopted by F- and Br- compared to Cl-. We perform density functional theory calculations to obtain the Heisenberg Hamiltonian parameters of Cu4(OH)6FBr which has a Cu2+ site coupling the kagome layers. The 3D network of exchange couplings together with a substantial Dzyaloshinskii-Moriya coupling lead to canted antiferromagnetic ordering of this compound at TN=15 K as observed by magnetic susceptibility measurements on single crystals. 
Harald O. Jeschke, Francesc Salvat-Pujol, Elena Gati, Nguyen Hieu   Hoang, Bernd Wolf, Michael Lang, John A. Schlueter, and ...
cond-mat.str-el