Alignment of D-state Rydberg molecules
  We report on the formation of ultralong-range Rydberg D-state molecules via photoassociation in an ultracold cloud of rubidium atoms. By applying a magnetic offset field on the order of 10 G and high resolution spectroscopy, we are able to resolve individual rovibrational molecular states. A full theory, using the Born-Oppenheimer approximation including s- and p-wave scattering, reproduces the measured binding energies. The calculated molecular wavefunctions show that in the experiment we can selectively excite stationary molecular states with an extraordinary degree of alignment or anti-alignment with respect to the magnetic field axis. 
Alexander T. Krupp, Anita Gaj, Jonathan B. Balewski, Philipp   Ilzh\"ofer, Sebastian Hofferberth, Robert L\"ow, Tilman Pfau,...
physics.atom-ph cond-mat.quant-gas quant-ph