Molecular beam epitaxial growth of MoSe2 on graphite, CaF2 and graphene
  We report the structural and optical properties of molecular beam epitaxy (MBE) grown 2-dimensional (2D) material molybdenum diselenide (MoSe2) on graphite, CaF2 and epitaxial graphene. Extensive characterizations reveal that 2H- MoSe2 grows by van-der-Waals epitaxy on all 3 substrates with a preferred crystallographic orientation and a Mo:Se ratio of 1:2. Photoluminescence at room temperature (~1.56 eV) is observed in monolayer MoSe2 on both CaF2 and epitaxial graphene. The band edge absorption is very sharp, <60 meV over 3 decades. Overcoming the observed small grains by promoting mobility of Mo atoms would make MBE a powerful technique to achieve high quality 2D materials and heterostructures. 
Suresh Vishwanath, Xinyu Liu, Sergei Rouvimov, Patrick C. Mende,   Angelica Azcatl, Stephen McDonnell, Robert M. Wallace, Ra...
cond-mat.mtrl-sci