Spin-dependent polaron formation dynamics in   Eu$_{0.75}$Y$_{0.25}$MnO$_3$ probed by femtosecond pump-probe spectroscopy
  We present a femtosecond optical pump-probe study of the multiferroic manganite Eu$_{0.75}$Y$_{0.25}$MnO$_3$. The optical response of the material at pump energies of 1.55 and 3.1 eV is dominated by the $d$-$d$ and $p$-$d$ transitions of the Mn$^{3+}$ ions. The relaxation of photoexcited electrons includes the relaxation of the Jahn-Teller distortion and polaron trapping at Mn$^{2+}$ and Mn$^{4+}$ sites. Ultrafast switching of superexchange interactions due to modulated $e_g$ orbital occupancy creates a localized spin excitation, which then decays on a time scale of tens of picoseconds at low temperatures. The localized spin state decay appears as a tremendous increase in the amplitude of the photoinduced reflectance, due to the strong coupling of optical transitions to the spin-spin correlations in the crystalline $a$-$b$ plane. 
Diyar Talbayev, Jinho Lee, Stuart A. Trugman, Chenglin Zhang,   Sang-Wook Cheong, Richard D. Averitt, Antoinette J. Taylor, ...
cond-mat.str-el