Controllable spin-orbit coupling and its influence on the upper critical   field in the chemically doped quasi-one-dimensional Nb$_2$PdS$_5$   superconductor
  By systematic chemical substitution of Pt and Ni in the newly-discovered superconductor Nb$_2$PdS$_5$ ($T_c\sim$6 K), we study the evolution of its superconducting properties with doping, focussing on the behavior of the upper critical field $H_{c2}$. In contrast to the previous results of Se doping on S sites, superconductivity is found to be rather robust against the Pt and Ni dopants on the one-dimensional Pd chains. Most strikingly, the reduced $H_{c2}$, i.e., the ratio of $H_{c2}/T_c$, is seen to be significantly enhanced by the heavier Pt doping but suppressed in the Ni-doped counterparts, distinct from the nearly constant value in the Se doped samples. Our findings therefore suggest that the upper critical field of this system can be modified in a tunable fashion by chemical doping on the Pd chains with elements of varying mass numbers. The spin-orbit coupling on the Pd sites, by inference, should play an important role in the observed superconductivity and on the large upper critical field beyond the Pauli pair-breaking field. 
N. Zhou, Xiaofeng Xu, J. R. Wang, J. H. Yang, Y. K. Li, Y. Guo, W. Z.   Yang, C. Q. Niu, Bin Chen, Chao Cao, Jianhui Dai
cond-mat.supr-con cond-mat.str-el