Neutral pion photoproduction off nucleons revisited
  We investigate threshold pion photoproduction in the framework of heavy baryon chiral perturbation theory. We give the expansion of the electric dipole amplitude $E_{0+}$ to three orders in $\mu$, the ratio of the pion to nucleon mass, and show that it is slowly converging. We argue that this observable is not a good testing ground for the chiral dynamics of QCD. In contrast, we exhibit new and fastly converging low--energy theorems in the P--waves which should be used to constrain the data analysis. We also discuss the importance of polarization observables to accurately pin down certain multipoles and give predictions for the reaction $\gamma n \to \pi^0 n$. 
V. Bernard, N. Kaiser, Ulf-G. Mei{\ss}ner