Optical Properties of the Spin-Ladder Compound Sr_{14}Cu_{24}O_{41}
  We report the measurements of the pseudodielectric function, far-infrared reflectivity and Raman scattering spectra in Sr_{14}Cu_{24}O_{41} single crystal. We study the lattice and the spin dynamics of the Cu$_2$O$_3$ spin ladders and CuO$_2$ chains of this compound. The ellipsometric and the optical reflectivity measurements yield the gap values of 1.4 eV, 1.86 eV, 2.34 eV (2.5 eV) for the ladders (chains) along the {\bf c}-axis and 2.4 eV along the {\bf a}-axis. The electronic structure of the Cu$_2$O$_3$ ladders is analyzed using tight-binding approach for the correlated electron systems. The correlation gap value of 1.4 eV is calculated with the transfer energy (hopping) parameters $t=t_{0}$=0.26 eV, along and perpendicular to legs, $t_{xy}$=0.026 eV (interladder hopping) and U=2.1 eV, as a Coulomb repulsion. The optical parameters of the infrared active phonons and plasmons are obtained by oscillator fitting procedure of the reflectivity spectra. Raman scattering spectra are measured at different temperatures using different laser line energies. The two-magnon peak is observed at about 2880 cm$^{-1}$. At temperatures below 150 K the new infrared and Raman modes appear due to the charge ordering. 
Z. V. Popovi\'c, M. J. Konstantinovi\'c, V. A. Ivanov, O. P. Khuong,   R. Gaji\'c, A. Vietkin and V. V. Moshchalkov