Dynamics of Br Electrosorption on Single-Crystal Ag(100): A   Computational Study
  We present dynamic Monte Carlo simulations of a lattice-gas model for bromine electrodeposition on single-crystal silver (100). This system undergoes a continuous phase transition between a disordered phase at low electrode potentials and a commensurate c(2X2) phase at high potentials. The lattice-gas parameters are determined by fitting simulated equilibrium adsorption isotherms to chronocoulometric data, and free-energy barriers for adsorption/desorption and lateral diffusion are estimated from ab initio data in the literature. Cyclic voltammograms in the quasi-static limit are obtained by equilibrium Monte Carlo simulations, while for nonzero potential scan rates we use dynamic Monte Carlo simulation. The butterfly shapes of the simulated voltammograms are in good agreement with experiments. Simulated potential-step experiments give results for the time evolution of the Br coverage, as well as the c(2X2) order parameter and its correlation length. During phase ordering following a positive potential step, the system obeys dynamic scaling. The disordering following a negative potential step is well described by random desorption with diffusion. Both ordering and disordering processes are strongly influenced by the ratio of the time scales for desorption and diffusion. Our results should be testable by experiments, in particular cyclic voltammetry and surface X-ray scattering. 
S.J. Mitchell, G. Brown, P.A. Rikvold (Florida State U.)