Semiclassical time evolution of the density matrix and tunneling
  The time dependent density matrix of a system with potential barrier is studied using path integrals. The characterization of the initial state, which is assumed to be restricted to one side of the barrier, and the time evolution of the density matrix lead to a three-fold path integral which is evaluated in the semiclassical limit. The semiclassical trajectories are found to move in the complex coordinate plane and barrier penetration only arises due to fluctuations. Both the form of the semiclassical paths and the relevant fluctuations change significantly as a function of temperature. The semiclassical analysis leads to a detailed picture of barrier penetration in the real time domain and the changeover from thermal activation to quantum tunneling. Deep tunneling is associated with quasi-zero modes in the fluctuation spectrum about the semiclassical orbits in the long time limit. The connection between this real time description of tunneling and the standard imaginary time instanton approach is established. Specific results are given for a double well potential and an Eckart barrier. 
Joachim Ankerhold and Hermann Grabert