Hyperfine splitting of [Al VI]3.66um and the Al isotopic ratio in   NGC6302
  The core of planetary nebula NGC 6302 is filled with high-excitation photoionised gas at low expansion velocities. It represents a unique astrophysical situation in which to search for hyperfine structure (HFS) in coronal emission lines from highly ionised species. HFS is otherwise blended by thermal or velocity broadening. Spectra containing [AlVI]~3.66um 3P2-3P1, obtained with Phoenix on Gemini-South at resolving powers of up to 75000, resolve the line into five hyperfine components separated by 20 to 60km/s due to the coupling of the I=5/2 nuclear spin of 27Al with the total electronic angular momentum J. 26Al has a different nuclear spin of I=5, and a different HFS, which allows us to place a 3sigma upper limit on the 26Al/27Al abundance ratio of 1/33. We measure the HFS magnetic-dipole coupling constants for [AlVI], and provide the first estimates of the electric-quadrupole HFS coupling constants obtained through astronomical observations of an atomic transition. 
S. Casassus (1), P.J. Storey (2), M.J. Barlow (2), P.F. Roche (3) ((1)   U. de Chile, (2) UCL, (3) Oxford)