Al-Substitution Effects on Physical Properties of the Colossal   Magnetoresistance Compouns La0.67ca0.33mno3
  We present a detailed study of the polycrystalline perovskite manganites La0.67Ca0.33AlxMn1-xO3 (x = 0, 0.1, 0.15, 0.5) at low temperatures and high magnetic fields, including electrical resistance, magnetization, ac susceptibility. The static magnetic susceptibility was also measured up to 1000 K. All the samples show colossal magnetoresistance behavior and the Curie temperatures decrease with Al doping. The data suggest the presence of correlated magnetic clusters near by the ferromagnetic transition. This appears to be a consequence of the structural and magnetic disorder created by the random distribution of Al atoms. 
I. G. Deac, L. Giurgiu, A. Darabont, R. V. Tetean, M. Miron, E. Burzo