Observation of surface layering in a nonmetallic liquid
  Oscillatory density profiles (layers) have previously been observed at the free surfaces of liquid metals, but not in other isotropic liquids. We have used x-ray reflectivity to study a molecular liquid, tetrakis(2-ethylhexoxy)silane. When cooled to T/Tc~0.25 (well above the freezing point for this liquid), density oscillations appear at the surface. Lateral order within the layers is liquid-like. Our results confirm theoretical predictions that a surface-layered state will appear even in dielectric liquids at sufficiently low temperatures, if not preempted by freezing. 
Haiding Mo, Guennadi Evmenenko, Sumit Kewalramani, Kyungil Kim, Steven   N. Ehrlich and Pulak Dutta