The 10 micron amorphous silicate feature of fractal aggregates and   compact particles with complex shapes
  We model the 10 micron absorption spectra of nonspherical particles composed of amorphous silicate. We consider two classes of particles, compact ones and fractal aggregates composed of homogeneous spheres. For the compact particles we consider Gaussian random spheres with various degrees of non-sphericity. For the fractal aggregates we compute the absorption spectra for various fractal dimensions. The 10 micron spectra are computed for ensembles of these particles in random orientation using the well-known Discrete Dipole Approximation. We compare our results to spectra obtained when using volume equivalent homogeneous spheres and to those computed using a porous sphere approximation. We conclude that, in general, nonspherical particles show a spectral signature that is similar to that of homogeneous spheres with a smaller material volume. This effect is overestimated when approximating the particles by porous spheres with the same volume filling fraction. For aggregates with fractal dimensions typically predicted for cosmic dust, we show that the spectral signature characteristic of very small homogeneous spheres (with a volume equivalent radius r_V<0.5 micron) can be detected even in very large particles. We conclude that particle sizes are underestimated when using homogeneous spheres to model the emission spectra of astronomical sources. In contrast, the particle sizes are severely overestimated when using equivalent porous spheres to fit observations of 10 micron silicate emission. 
M. Min, C. Dominik, J.W. Hovenier, A. de Koter and L.B.F.M. Waters