An adaptive Metropolis-Hastings scheme: sampling and optimization
  We propose an adaptive Metropolis-Hastings algorithm in which sampled data are used to update the proposal distribution. We use the samples found by the algorithm at a particular step to form the information-theoretically optimal mean-field approximation to the target distribution, and update the proposal distribution to be that approximatio. We employ our algorithm to sample the energy distribution for several spin-glasses and we demonstrate the superiority of our algorithm to the conventional MH algorithm in sampling and in annealing optimization. 
David H. Wolpert, Chiu Fan Lee