Metallicity Effects on Mid-Infrared Colors and the 8 micron PAH Emission   in Galaxies
  We examine colors from 3.6 micron to 24 micron as a function of metallicity (O/H) for a sample of 34 galaxies. The galaxies range over 2 orders of magnitude in metallicity. They display an abrupt shift in the 8 micron to 24 micron color between metallicities 1/3 to 1/5 of the solar value. The mean 8 micron to 24 micron flux density ratio below and above 12 + log (O/H) = 8.2 is 0.08 +/- 0.04 and 0.70 +/- 0.53, respectively. We use mid-infrared colors and spectroscopy to demonstrate that the shift is primarily due to a decrease in the 8 micron flux density as opposed to an increase in the 24 micron flux density. This result is most simply interpreted as due to a weakening at low metallicity of the mid-infrared emission bands usually attributed to PAHs (polycyclic aromatic hydrocarbons) relative to the small-grain dust emission. However, existing empirical spectral energy distribution models cannot account for the observed short-wavelength (i.e., below 8 micron) colors of the low-metallicity galaxies merely by reducing the strength of the PAH features; some other emission source (e.g., hot dust) is required. 
C. W. Engelbracht, K. D. Gordon, G. H. Rieke, M. W. Werner, D. A.   Dale, and W. B. Latter