Discovery of excess O I absorption towards the z = 6.42 QSO SDSS   J1148+5251
  We present a search for O I in the spectra of nine 4.9 < z_qso < 6.4 QSOs taken with Keck/HIRES. We detect six systems with N(O I) > 10^13.7 cm^{-2} in the redshift intervals where O I 1302 falls redward of the Ly-alpha forest. Four of these lie towards SDSS J1148+5251 (z_qso = 6.42). This imbalance is unlikely to arise from variations in sensitivity among our data or from a statistical fluctuation. The excess O I occurs over a redshift interval that also contains transmission in Ly-alpha and Ly-beta. Therefore, if these O I systems represent pockets of neutral gas, then they must occur within or near regions of the IGM that are highly ionized. In contrast, no O I is detected towards SDSS J1030+0524 (z_qso = 6.30), whose spectrum shows complete absorption in Ly-alpha and Ly-beta over \Delta z ~ 0.2. Assuming no ionization corrections, we measure mean abundance ratios <[O/Si]> = -0.04 +/- 0.06, <[C/O]> = -0.31 +/- 0.09, and <[C/Si]> = -0.34 +/- 0.07 (2 sigma), which are consistent with enrichment dominated by Type II supernovae. The O/Si ratio limits the fraction of silicon in these systems contributed by metal-free very massive stars to < 30%, a result which is insensitive to ionization corrections. The ionic comoving mass densities along the z_qso > 6.2 sightlines, including only the detected systems, are \Omega(O I) = (7.0 +/- 0.6) * 10^{-8}, \Omega(Si II) = (9.6 +/- 0.9) * 10^{-9}, and \Omega(C II) = (1.5 +/- 0.2) * 10^{-8}. 
George D. Becker, Wallace L. W. Sargent (Caltech), Michael Rauch   (OCIW), Robert A. Simcoe (MIT)