Low Symmetry Phase in (001) BiFeO$_3$ Epitaxial Constrained Thin Films
  The lattice of (001)-oriented BiFeO$_3$ epitaxial thin film has been identified by synchrotron x-ray diffraction. By choosing proper scattering zones containing the fixed (001) reflection, we have shown that low-symmetry phases similar to a $M_A$ phase exist in the thin film at room temperature. These results demonstrate a change in phase stability from rhombohedral in bulk single crystals, to a modified monoclinic structure in epitaxial thin films. 
Guangyong Xu, H. Hiraka, G. Shirane, Jiefang Li, Junling Wang, and D.   Viehland