Temperature Dependence of the Chemical Potential in NaxCoO2:   Implications for the Large Thermoelectric Power
  We have performed a temperature-dependent photoemission study of a NaxCoO2 (x~0.8) epitaxial thin film prepared by the reactive solid-phase epitaxy method. The chemical potential shift as a function of temperature was derived from the Co 3d peak shift, and revealed a crossover from the degenerate Fermion state at low temperatures to the correlated hopping state of Co3+/Co4+ mixed-valence at high temperatures. This suggests that the large thermoelectric power at high temperatures should be considered in the correlated hopping picture. 
Y. Ishida, H. Ohta, A. Fujimori, H. Hosono