Effect of suppression of local distortion on magnetic, electrical and   thermal transport properties of Cr substituted bi-layer manganite   LaSr$_{2}$Mn$_{2}$O$_{7}$
  We have investigated magnetic, electrical and thermal transport properties (Seebeck effect and thermal conductivity) of LaSr$_{2}$Mn$_{2-y}$Cr$_{y}$O$_{7}$ polycrystalline samples ($y$=0.1, 0.2, 0.4 and 0.6). The Cr$^{3+}$ substitution for Mn$^{3+}$ sites causes a removal of $d_{x^2-y^2}$ orbital of $e_g$-electron resulting in a volume shrinkage of lattice. Magnetic measurements reveal the appearance of a glassy behavior for Cr-doped samples, accompanied by both a collapse of the A-type antiferromagnetic structure and the growth of ferromagnetic clusters. Cr-doping effect on electrical transport strongly enhances an insulating behavior over a wide range of temperature, while it suppresses a local minimum of thermoelectric power at lower temperatures. The phonon thermal conduction gradually rises with increasing Cr content, which is contradictory to a typical impurity effect on thermal conductivity. We attribute this to a suppression of local lattice distortion through the introduction of Jahn-Teller inactive ions of Cr$^{3+}$. 
M.Matsukawa, M.Chiba, E.Kikuchi, R.Suryanarayanan, et al