Anomalous electronic Raman scattering in Na_xCoO_2 H_2O
  Raman scattering experiments on Na_{x}CoO_2 yH_2O single crystals show a broad electronic continuum with a pronounced peak around 100 cm-1 and a cutoff at approximately 560 cm-1over a wide range of doping levels. The electronic Raman spectra in superconducting and non-superconducting samples are similar at room temperature, but evolve in markedly different ways with decreasing temperature. For superconducting samples, the low-energy spectral weight is depleted upon cooling below T* sim 150K, indicating a opening of a pseudogap that is not present in non-superconducting materials. Weak additional phonon modes observed below T* suggest that the pseudogap is associated with charge ordering. 
P. Lemmens, K. Y. Choi, V. Gnezdilov, E. Ya. Sherman, D. P. Chen, C.   T. Lin, F.C. Chou, and B. Keimer