On the Ionisation Fraction in Protoplanetary Disks II: The Effect of   Turbulent Mixing on Gas--phase Chemistry
  We calculate the ionisation fraction in protostellar disk models using two different gas-phase chemical networks, and examine the effect of turbulent mixing by modelling the diffusion of chemical species vertically through the disk. The aim is to determine in which regions of the disk gas can couple to a magnetic field and sustain MHD turbulence. We find that the effect of diffusion depends crucially on the elemental abundance of heavy metals (magnesium) included in the chemical model. In the absence of heavy metals, diffusion has essentially no effect on the ionisation structure of the disks, as the recombination time scale is much shorter than the turbulent diffusion time scale. When metals are included with an elemental abundance above a threshold value, the diffusion can dramatically reduce the size of the magnetically decoupled region, or even remove it altogther. For a complex chemistry the elemental abundance of magnesium required to remove the dead zone is 10(-10) - 10(-8). We also find that diffusion can modify the reaction pathways, giving rise to dominant species when diffusion is switched on that are minor species when diffusion is absent. This suggests that there may be chemical signatures of diffusive mixing that could be used to indirectly detect turbulent activity in protoplanetary disks. We find examples of models in which the dead zone in the outer disk region is rendered deeper when diffusion is switched on. Overall these results suggest that global MHD turbulence in protoplanetary disks may be self-sustaining under favourable circumstances, as turbulent mixing can help maintain the ionisation fraction above that necessary to ensure good coupling between the gas and magnetic field. 
Martin Ilgner and Richard P. Nelson