Isospin breaking and the chiral condensate
  With two degenerate quarks, the chiral condensate exhibits a jump as the quark masses pass through zero. I discuss how this single transition splits into two Ising like transitions when the quarks are made non-degenerate. The order parameter is the expectation of the neutral pion field. The transitions represent long distance coherent phenomena occuring without the Dirac operator having vanishingly small eigenvalues. 
Michael Creutz