Role of cross-links in bundle formation, phase separation and gelation   of long filaments
  We predict the thermodynamic and structural behavior of solutions of long cross-linked filaments. We find that at the mean field level, the entropy of self-assembled junctions induces an effective attraction between the filaments that can result in a phase separation into a connected network, in equilibrium with a dilute phase. A connected network can also be formed in a non-thermodynamic transition upon increase of the chain, or cross link density, or with decreasing temperature. For rigid rods, at low temperatures, we predict a transition from an isotropic network, to anisotropic bundles of rods tightly bound by cross links, that is triggered by the interplay between the configurational entropy of the cross-link distribution among the rods, and the rotational and translational entropy of the rods. 
A. Zilman and S. Safran