Fabrication and characterization of scanning tunneling microscopy   superconducting Nb tips having highly enhanced critical fields
  We report a simple method for the fabrication of Niobium superconducting (SC) tips for scanning tunnelling microscopy which allow atomic resolution. The tips, formed in-situ by the mechanical breaking of a niobium wire, reveal a clear SC gap of 1.5 meV and a critical temperature Tc=9.2+-0.3 K as deduced from Superconductor Insulator Normal metal (NIS) and Superconductor Insulator Superconductor (SIS) spectra. These match the values of bulk Nb samples. We systematically find an enhanced value of the critical magnetic field in which superconductivity in the tip is destroyed (around 1 T for some tips) up to five times larger than the critical field of bulk Nb (0.21 T). Such enhancement is attributed to a size effect at the tip apex 
A. Kohen, Y. Noat, T. Proslier, E. Lacaze, M. Aprili, W. Sacks and D.   Roditchev