Electronic self-doping of Mo-states in A2FeMoO6 (A=Ca, Sr and Ba)   half-metallic ferromagnets - a Nuclear Magnetic Resonance study
  A systematic study of (A,A')2FeMoO6 (A,A'=Ca, Sr, Ba) ferromagnetic oxides with double perovskite structure has been performed using 95,97Mo and 57Fe NMR spectroscopy. These oxides are isoelectronic but have substantially different Curie temperatures. The NMR analysis provides clear evidence that the magnetic moment at Mo sites is not constant but varies sensitively with the ionic size of the alkaline ions. The 95,97Mo frequency, and thus the electronic charge at Mo ions, is found to be smaller in Ba and Ca than in Sr-based oxides. The charge release from Mo sites is accompanied by an uptake at Fe sites, and thus a self-doping Fe-Mo process is observed. This process is controlled by relevant structural parameters: the Fe-O-Mo bond length and bending. A clear relationship between the Curie temperature and the magnetic moment and thus electron density at Mo sites has been disclosed. The relevance of these findings for the understanding of ferromagnetic coupling in double perovskites is discussed. 
M. Wojcik, E. Jedryka, S. Nadolski, D. Rubi, C. Frontera, J.   Fontcuberta, B. Jurca, N. Dragoe and P. Berthet