Symmetry of Magnetic Quantum Tunneling in the Single-Molecule Magnet   Mn12-Acetate
  The symmetry of magnetic quantum tunneling (MQT) in the single molecule magnet Mn12-acetate has been determined by sensitive low-temperature magnetic measurements in the pure quantum tunneling regime and high frequency EPR spectroscopy in the presence of large transverse magnetic fields. The combined data set definitely establishes the transverse anisotropy terms responsible for the low temperature quantum dynamics. MQT is due to a disorder induced locally varying quadratic transverse anisotropy associated with rhombic distortions in the molecular environment (2nd order in the spin-operators). This is superimposed on a 4th order transverse magnetic anisotropy consistent with the global (average) S4 molecule site symmetry. The hard axes associated with these forms of the transverse anisotropy are not collinear, leading to a complex interplay between local and global symmetries, the consequences of which are analyzed in detail. 
E. del Barco, A. D. Kent, S. Hill, J. M. North, N. S. Dalal, E. M.   Rumberger, D. N. Hendrickson, N. Chakov and G. Christou