The role of HeH+ in cool helium rich white dwarfs
  HeH$^+$ is found to be the dominant positive ion over a wide range of temperatures and densities relevant to helium rich white dwarfs. The inclusion of HeH$^+$ in ionization equilibrium computations increases the abundance of free electrons by a significant factor. For temperatures below 8000 K, He$^-$ free-free absorption is increased by up to a factor of 5, by the inclusion of HeH$^+$. Illustrative model atmospheres and spectral energy distributions are computed, which show that HeH$^+$ has a strong effect upon the density and pressure structure of helium rich white dwarfs with teff < 8000 K. The inclusion of HeH$^+$ significantly reddens spectral energy distributions and broad band color indices for models with Teff < 5500 K. This has serious implications for existing model atmospheres, synthetic spectra and cooling curves for helium rich white dwarfs. 
G. J. Harris, A. E. Lynas-Gray, S. Miller and J. Tennyson