Strong spin triplet contribution of the first removal state in the   insulating regime of Bi2Sr2Ca1-xYxCu2O8+delta
  The experimental dispersion of the first removal state in the insulating regime of Bi2Sr2Ca1-xYxCu2O8+delta is found to differ significantly from that of other parent materials: oxyclorides and La2CuO4 . For Y-contents of 0.92 > x > 0.55 due to nonstoichiometric effects in the Bi-O layers, the hole concentration in the CuO2 -layers is almost constant and on the contrary the crystal lattice parameters a,b,c change very strongly. This (a,b) parameter increase and c parameter decrease results in an unconventional three peak structure at (0,0);(pi/2, pi/2);(pi,pi) for x=0.92. We can describe the experimental data only beyond the framework of the 3-band pd-model involving the representations of a new triplet counterpart for the Zhang-Rice singlet state. 
C.Janowitz, U. Seidel, R.-ST. Unger, A. Krapf, R.Manzke,   V.A.Gavrichkov, S.G.Ovchinnikov