Effect of oxygen content on the transport properties and   magnetoresistance in [Ca$_{2}$CoO$_{3-\delta}$]$_{0.62}$[CoO$_{2}$] single   crystals
  Transport property is investigated in [Ca$_{2}$CoO$_{3-\delta}$]$_{0.62}$[CoO$_{2}$] single crystals obtained by varying annealing conditions. The $\rho_{ab}(T)$ exhibits a resistivity minimum, and the temperature corresponding to this minimum increases with the loss of oxygen content, indicative of the enhancement of spin density wave (SDW). Large negative magnetoresistance (MR) was observed in all single crystals [Ca$_{2}$CoO$_{3-\delta}$]$_{0.62}$[CoO$_{2}$], while a magnetic-field-driven insulator-to-metal (IM) transition in oxygen annealed samples. These results suggest a ferromagnetic correlation in system enhanced by oxygen content. In addition, a low temperature thermal activation resistivity induced by fields was observed in single crystals annealed in oxygen atmosphere. 
X. G. Luo, X. H. Chen, G. Y. Wang, C. H. Wang, Y. M. Xiong, H. B.   Song, H. Li and X. X. Lu