Elucidating the Correlation of the Quasar \ion{Fe}{2}/\ion{Mg}{2} Ratio   with Redshift
  Interpretation of the \ion{Fe}{2}(UV)/\ion{Mg}{2} emission ratios from quasars has a major cosmological motivation. Both Fe and Mg are produced by short-lived massive stars. In addition, Fe is produced by accreting white dwarf supernovae somewhat after star formation begins. Therefore, we expect that the Fe/Mg ratio will gradually decrease with redshift. We have used data from the Sloan Digital Sky Survey to explore the dependence of the \ion{Fe}{2}(UV)/\ion{Mg}{2} ratio on redshift and on luminosity in the redshift range of $0.75< z< 2.20$, and we have used predictions from our 830-level model for the \ion{Fe}{2} atom in photoionization calculations to interpret our findings.   We have split the quasars into several groups based upon the value of their \ion{Fe}{2}(UV)/\ion{Mg}{2} emission ratios, and then checked to see how the fraction of quasars in each group varies with the increase of redshift. We next examined the luminosity dependence of the \ion{Fe}{2}(UV)/\ion{Mg}{2} ratio, and we found that beyond a threshold of \ion{Fe}{2}(UV)/\ion{Mg}{2} =~ 5, and $M_{2500} < -25\rm mag$, the \ion{Fe}{2}(UV)/\ion{Mg}{2} ratio increases with luminosity, as predicted by our model.   We interpret our observed variation of the \ion{Fe}{2}(UV)/\ion{Mg}{2} ratio with redshift as a result of the correlation of redshift with luminosity in a magnitude limited quasar sample. 
E. Verner and B. A. Peterson