Existence of orbital polarons in ferromagnetic insulating   La$_{1-x}$Sr$_x$MnO$_{3}$ (0.11$<x<$0.14) evidenced by giant phonon softening
  We present an inelastic light scattering study of single crystalline (La$_{1-y}$Pr$_y$)$_{1-x}$Sr$_{x}$MnO$_3$ ($0\leq x\leq0.14$,$y=0$ and $x=1/8$,$0\leq y\leq0.5$). A giant softening up to 20 - 30 cm$^{-1}$ of the Mn-O breathing mode has been observed only for the ferromagnetic insulating (FMI) samples ($0.11\leq x \leq 0.14$) upon cooling below the Curie temperature. With increasing Pr-doping the giant softening is gradually suppressed. This is attributed to a coupling of the breathing mode to orbital polarons which are present in the FMI phase. 
K.-Y. Choi, P. Lemmens, G. G\"untherodt, Yu. G. Pashkevich, V. P.   Gnezdilov, P. Reutler, L. Pinsard-Gaudart, B. B\"uchner,...