Antiferromagnetic dichroism and Davydov splitting of 3d-excitons in a   complex multisublattice magnetoelectric CuB2O4
  The space and time symmetry breaking at magnetic phase transitions in multiferroics results in a number of strongly pronounced optical effects. Our high-resolution spectroscopic study of 3d- excitons in a complex multi-sublattice magnetoelectric CuB2O4 demonstrates that, among those, a large antiferromagnetic linear dichroism is observed which is highly sublattice-sensitive to subtle changes in the spin subsystems. We prove that the discovered linear dichroism is related microscopically to the magnetic Davydov splitting of the exciton states. We announce a novel magnetic phase transition and argue that an elliptical spiral structure rather than a simple circular helix is realized in the incommensurate phase, these findings being overlooked in previous studies by optical and other techniques. We claim that this spectroscopic method can be effectively applied to other materials for revealing hidden features of magnetic structures and phase transitions. 
K. N. Boldyrev, R. V. Pisarev, L. N. Bezmaternykh and M. N. Popova
cond-mat.mtrl-sci cond-mat.str-el