Laser pulses for coherent xuv Raman excitation
  We combine multi-channel electronic structure theory with quantum optimal control to derive Raman pulse sequences that coherently populate a valence excited state. For a neon atom, Raman target populations of up to 13% are obtained. Superpositions of the ground and valence Raman states with a controllable relative phase are found to be reachable with up to 4.5% population and phase control facilitated by the pump pulse carrier envelope phase. Our results open a route to creating core-hole excitations in molecules and aggregates that locally address specific atoms and represent the first step towards realization of multidimensional spectroscopy in the xuv and x-ray regimes. 
Loren Greenman, Christiane P. Koch, K. Birgitta Whaley
quant-ph physics.atom-ph physics.chem-ph