The shifts X-Ray Mn K{\alpha} and 2p spectra of Mn-Heusler alloys
  X-ray emission K{\alpha}1,2 spectra of Mn in Heusler alloys Co2MnMe (Me = Al, Ga, Sb), Ni2MnIn, Cu2MnAl were studied. Shifts of Mn K{\alpha}1,2 lines relatively pure Mn in high-energy region and low-energy shifts of binding energy Mn 2p XPS is detected. X-ray emission and XPS shifts are in qualitative agreement. 
A.S.Shkvarin, Y.M. Yarmoshenko
cond-mat.mtrl-sci