Electron transport through a single-molecule junction with multiple   pathways under time-periodic fields: A Floquet-scattering formalism
  We develop a new general formulation to explore light-driven electron transport through a single-molecule device with multiple pathways. Three individual systems are proposed including (i) a two-terminal molecular junction based on phenyl-acetylene macrocycle (PAM), (ii) PAM with three terminals, and (iii) a parallel molecular circuit. The computations show that PAM-based optoelectronic switches have robust large on-off ratios and weak-field operating conditions, which are not sensitive to asymmetric molecule-lead couplings. In addition, field-amplitude power laws for one- and two-photon assisted tunneling are evident in the computational results, and the laws can be proven by using perturbation analysis. For PAM-based optoelectronic routers, we show that it is possible to manipulate the direction of electric current through the PAM molecule by using a weak linearly polarized laser field. For parallel circuits made of molecular quantum dots, the condition of coherent destruction of tunneling is derived by using the rotating wave approximation and the high-frequency approximation. 
Liang-Yan Hsu and Herschel Rabitz
cond-mat.mes-hall