Minimising biases in Full Configuration Interaction Quantum Monte Carlo
  We show that Full Configuration Interaction Quantum Monte Carlo (FCIQMC) is a Markov Chain in its present form. We construct the Markov matrix of FCIQMC for a two determinant system and hence compute the stationary distribution. These solutions are used to quantify the dependence of the population dynamics on the parameters defining the Markov chain. Despite the simplicity of a system with only two determinants, it still reveals a population control bias inherent to the FCIQMC algorithm. We investigate the effect of simulation parameters on the population control bias for the neon atom and suggest simulation setups to in general minimise the bias. We show a reweighting scheme to remove the bias caused by population control commonly used in Diffusion Monte Carlo [J. Chem. Phys. 99, 2865 (1993)] is effective and recommend its use as a post processing step. 
W. A. Vigor, J. S. Spencer, M. J. Bearpark, and A. J. W. Thom
physics.chem-ph