The origin of the unusual anisotropic electrical conductivity of   Ba3Al2As4
  Ba3Al2As4 exhibits an unusual anisotropic electrical conductivity, that is, the electrical conductivity along the chain is smaller than those along other two directions which conflicts previous conclusion. Earlier studies on Ca5M2Pn6 showed a high electrical conductivity along the chain. The band decomposed charge density is used to explain such unusual behavior. The results indicate that the existence of a conductive pathway near the Fermi level is responsible for the electrons transport. Further, the Ba-As bonding of Ba3Al2As4 is some degree covalency which is novel for the Zintl compounds. 
Gui Yang and Yuanxu Wang
cond-mat.mes-hall