Structure order, local potentials, and physical anomalies of water ice
  Hydrogen-bond forms a pair of asymmetric, coupled, H-bridged oscillators with ultra-short-range interactions and memory. hydrogen bond cooperative relaxation and the associated binding electron entrapment and nonbonding electron polarization discriminate water and ice from other usual materials in the physical anomalies.   As a strongly correlated fluctuating system, water prefers the statistically mean of tetrahedrally-coordinated structure with a supersolid skin that is elastic, polarized, ice like, hydrophobic, with 3/4 density. 
Chang Q Sun
cond-mat.soft