Macroscopically deterministic, Markovian thermalization in finite   quantum spin systems
  A key feature of non-equilibrium thermodynamics is the Markovian, deterministic relaxation of coarse observables such as, for example, the temperature difference between two macroscopic objects which evolves independently of almost all details of the initial state. We demonstrate that the unitary dynamics for moderately sized spin-1/2 systems may yield the same type of relaxation dynamics for a given magnetization difference. This observation might contribute to the understanding of the emergence of thermodynamics within closed quantum systems. 
Hendrik Niemeyer and Kristel Michielsen and Hans de Raedt and Jochen   Gemmer
quant-ph cond-mat.stat-mech