$Ab$ $intito$ study on some new spin-gapless semiconductors: The   Zr-based quanternary Heusler alloys
  Employing $ab$ $intito$ electronic structure calculations, we have investigated electronic and magnetic properties of the Zr-based quanternary Heusler alloys: ZrCoVIn, ZrFeVGe, ZrCoFeP, ZrCoCrBe and ZrFeCrZ (Z=In and Ga). Our $ab$ $intito$ calculation results show that all the alloys are (or nearly) spin-gapless semiconductors. All the alloys have large band gaps, indicating the stability of them at room temperature. The Slater-Pauling behaviours of these alloys are discussed as well. The values of Curie temperature of all the alloys are estimated. And it is found that the values of the Curie temperature for all our calculated quanternary Heusler alloys are higher than that of room temperature. 
Qiang Gao, Huan-huan Xie, Lei Li, Gang Lei, Jian-Bo Deng, Xian-Ru Hu
cond-mat.mtrl-sci physics.comp-ph