Change in the magnetic structure of (Bi,Sm)FeO3 thin films at the   morphotropic phase boundary probed by neutron diffraction
  We report on the evolution of the magnetic structure of BiFeO3 thin films grown on SrTiO3 substrates as a function of Sm doping. We determined the magnetic structure using neutron diffraction. We found that as Sm increases, the magnetic structure evolves from a cycloid to a G-type antiferromagnet at the morphotropic phase boundary, where there is a large piezoelectric response due to an electric-field induced structural transition. The occurrence of the magnetic structural transition at the morphotropic phase boundary offers another route towards room temperature multiferroic devices. 
Shingo Maruyama, Varatharajan Anbusathaiah, Amy Fennell, Mechthild   Enderle, Ichiro Takeuchi, and William D. Ratcliff
cond-mat.mtrl-sci