Multi-layered chalcogenides with potential for magnetism and   superconductivity
  Layered thallium copper chalcogenides can form single, double, or triple layers of Cu-Ch separated by Tl sheets. Here we report on the preparation and properties of Tl-based materials of TlCu2Se2, TlCu4S3, TlCu4Se3 and TlCu6S4, and compare to reports on layered ACu2nChn+1 materials with A = Ba, K, Rb, and Cs, and Ch = S, Se. Having no long-range magnetism for these materials is quite surprising considering the possibilities of inter- and intra-layer exchange interactions through Cu 3d, and we measure by magnetic susceptibility and confirm by neutron diffraction. First principles density-functional theory calculations for both the single-layer TlCu2Se2 (isostructural to the 122 iron-based superconductors) and the double-layer TlCu4Se3 suggest a lack of Fermi-level spectral weight that is needed to drive a magnetic or superconducting instability. The electronic structure calculations show a much greater likelihood of magnetism for multiple structural layers with Fe. 
L. Li, D.S. Parker, C.R. dela Cruz, and A.S. Sefat
cond-mat.supr-con cond-mat.mtrl-sci