Exceptional magneto-electric coupling and spontaneous electric   polarization in anti-ferromagnet Co4Nb2O9
  Synthesis and extensive structural, pyroelectric, magnetic, dielectric and magneto-electric characterizations are reported for polycrystalline Co4Nb2O9 towards unraveling the multiferroic state especially in reference to the magnetic spin flop transition. Magnetic measurements confirm the Co4Nb2O9 becomes antiferromagnetic (AFM) at around 28 K but no clear evidence for spin-flop effect was found. Associated with the magnetic phase transition, a sharp peak in pyroelectric current indicates the appearance of the strong magneto-electric coupling below Neel temperature (TN) with a large coupling constant upto 17.8 uC/m^2T. Using temperature oscillation technique, we establish Co4Nb2O9 to be a genuine multiferroic with spontaneous electric polarization in the anti-ferromagnetic state. 
P. Srivastava, S. Chaudhary, J. Saha and S. Patnaik
cond-mat.mtrl-sci cond-mat.other cond-mat.str-el