A Novel, Compact Optical Device for Estimating the Methane Emissions in   Geological Environment
  Quantifying spontaneous, fugitive and venting related methane emissions are often difficult and cumbersome. However, auditing the methane emissions due to conventional and un-conventional hydrocarbon exploitation techniques are becoming necessary. Present generation compact chemical sensors are slower, degrade very fast, and are sensitive broad-spectrum gases. On the other hand, optical sensors are very fast in detection of gases and more precise and can be easily employed in various environments like boreholes and soils. In this study, we report development of an optical sensor that is methane specific, fast for real time applications and has tremendous application potential in the exploration of coal bed methane and other hydrocarbon reserves with methane as a major constituent. The detection process is based on the principle of spectroscopic absorption of light. The detector, NiSi Schottky diode, was fabricated and characterized exclusively for the 1.65 um, narrow bandwidth methane absorption. The probe is of 20 cm length and comprises of a laser source and the NiSi detector aligned optically. This probe can be employed in boreholes, mine vents and soil layers for measuring real-time fluxes in methane concentrations. From the laboratory based experiments it is observed that the detection limits of the developed device is very low (3% by volume) and the response time of detection is very rapid (about 2 seconds). Based on the materials used, fabrication procedures adopted, sensitivity of the device and its compactness, the developed sensor can be considered as a novel, economic device for exploration of coal bed methane. 
Sandipta Roy, Ramakrishnan Desikan, Siddhartha P. Duttagupta
physics.ins-det