A rational approximation of the arctangent function and a new approach   in computing pi
  We have shown recently that integration of the error function ${\rm{erf}}\left( x \right)$ represented in form of a sum of the Gaussian functions provides an asymptotic expansion series for the constant pi. In this work we derive a rational approximation of the arctangent function $\arctan \left( x \right)$ that can be readily generalized it to its counterpart $ - {\rm{sgn}}\left( x \right)\pi /2 + \arctan \left( x \right)$, where ${\rm{sgn}}\left( x \right)$ is the signum function. The application of the expansion series for these two functions leads to a new asymptotic formula for $\pi$. 
S. M. Abrarov and B. M. Quine
math.GM