Semiconductor, topological semimetal, indirect semimetal, and   topological Dirac semimetal phases of Ge$_{1-x}$Sn$_{x}$ alloys
  Electronic structures of Ge$_{1-x}$Sn$_{x}$ alloys (0 $\leq$ $x$ $\leq$ 1) are theoretically studied by nonlocal empirical pseudopotential method. For relaxed Ge$_{1-x}$Sn$_{x}$, a topological semimetal is found for $\textit x$ $>$ 41$\%$ with gapless and band inversion at ${\Gamma}$ point, while there is an indirect-direct bandgap transition at $x$ = 8.5$\%$. For strained Ge$_{1-x}$Sn$_{x}$ on a Ge substrate, semimetals with a negative indirect bandgap appear for $x$ $>$ 43$\%$, and the strained Ge$_{1-x}$Sn$_{x}$ on Ge is always an indirect bandgap semiconductor for $x$ $<$ 43$\%$. With appropriate biaxial compressive strains, a topological Dirac semimetal is found with band inversion at ${\Gamma}$ and one pair of Dirac cones along the [001] direction. 
H.-S. Lan, S. T. Chang, and C. W. Liu
cond-mat.mes-hall cond-mat.mtrl-sci