Suspended Pt nanoparticles over TiO2 nanotubes for enhanced   photocatalytic H2 evolution
  In the present work we introduce a technique to form a photocatalyst, based on Pt nanoparticles suspended over the mouth of TiO2 nanotubes. These structures are obtained by the decoration of the top end of highly ordered TiO2 nanotubes with a web of TiO2 nanofibrils, followed by sputter deposition of a minimum amount of Pt. A subsequent thermal dewetting step forms 3-6 nm-sized Pt nanoparticles along the nanofibrils. These structures, when compared to conventional Pt decoration techniques of TiO2 nanotubes, show a strongly enhanced photocatalytic H2 evolution efficiency. 
Nhat Truong Nguyen, JeongEun Yoo, Marco Altomare, Patrik Schmuki
physics.chem-ph