A study on the growth mechanism and the process parameters controlling   aluminum oxide thin films deposition by pulsed pressure MOCVD
  Aluminum oxide thin films were deposited on silicon substrates under different deposition conditions using pulse pressure metal organic chemical vapour deposition (PP-MOCVD). The current study investigates into the growth mechanism of the deposited film and the control of the film morphology by varying the processing parameters of PP-MOCVD - choice of solvent, concentration, and presence of a shield. Aluminum sec-butoxide (ASB) was used as the aluminum source while hexane and toluene were used as the solvents. The films were deposited at 475oC at different precursor concentrations. It was observed that the choice of solvent has no effect on the surface morphology, but it influenced the deposition rate. The improved deposition rate, relatively close enthalpy of vaporisation ({\Delta}H) values and uniformity of the film, irrespective of the growth conditions, showed that hexane was a better solvent for ASB than toluene. A hybrid mode of vapour deposition and vapour condensation model for thin film growth is proposed where five different mechanisms lead to a solid film formation. These include vapour phase deposition under low arrival rate, vapour phase deposition under high arrival rate, Leidenfrost aerosol formation, heterogeneous particle formation and liquid droplet impingement. The important parameter that needs to be controlled is the precursor flux arrival rate which can be controlled by varying the precursor concentration, use of a solvent with a low {\Delta}H and the presence of a shield over the substrate, which influences the surface morphology and the growth rate of the films. 
Hari Murthy, S.S Miya, Susan Krumdieck
cond-mat.mtrl-sci