Majorana approach to the stochastic theory of lineshapes
  Motivated by recent Mossbauer experiments on strongly correlated mixed-valence systems, we revisit the Kubo-Anderson stochastic theory of spectral lineshapes. Using a Majorana representation for the nuclear spin we demonstrate how to recast the classic lineshape theory in a field-theoretic and diagrammatic language. We show that the leading contribution to the self-energy can reproduce most of the observed lineshape features including splitting and lineshape narrowing, while the vertex and the self-consistency corrections can be systematically included in the calculation. This new approach permits us to predict the line-shape produced by an arbitrary bulk charge fluctuation spectrum providing a model-independent way to extract the local charge fluctuation spectrum of the surrounding medium. We also derive an inverse formula to extract the charge fluctuation from the measured lineshape. 
Yashar Komijani, Piers Coleman
cond-mat.str-el