R-graphyne: a new two-dimension carbon allotrope with versatile   Dirac-like point in nanoribbons
  A novel two-dimensional carbon allotrope, rectangular graphyne (R-graphyne) with tetra-rings and acetylenic linkages, is proposed by first-principles calculations. Although the bulk R-graphyne exhibits metallic property, the nanoribbons of R-graphyne show distinct electronic structures from the bulk. The most intriguing feature is that band gaps of R-graphene nanoribbons oscillate between semiconductor and metal as a function of width. Particularly, the zigzag edge nanoribbons with half-integer repeating unit cell exhibits unexpected Dirac-like fermions in the band structures. The Dirac-like fermions of the R-graphyne nanoribbons originate from the central symmetry and two sub-lattices. The extraordinary properties of R-graphene nanoribbons greatly expand our understanding on the origin of Dirac-like point. Such findings uncover a novel fascinating property of nanoribbons, which may have broad potential applications for carbon-based nano-size electronic devices. 
Wen-Jin Yin, Yue-E Xie, Li-Min Liu, Ru-Zhi Wang, Leo Lau, Jian-Xin   Zhong, Yuan-Ping Chen
cond-mat.mes-hall cond-mat.mtrl-sci physics.chem-ph