Molecular fingerprint-region spectroscopy from 5-12 \mu m using an   orientation-patterned gallium phosphide optical parametric oscillator
  We report a femtosecond optical parametric oscillator (OPO) based on the new semiconductor gain material orientation patterned gallium phosphide (OP-GaP), which enables the production of high-repetition-rate femtosecond pulses spanning 5-12 \mu m with average powers in the few to tens of milliwatts range. This is the first example of a broadband OPO operating across the molecular fingerprint region, and we demonstrate its potential by conducting broadband Fourier-transform spectroscopy using water vapor and a polystyrene reference standard. 
Luke Maidment, Peter G. Schunemann and Derryck T. Reid
physics.optics