Using full configuration interaction quantum Monte Carlo in a seniority   zero space to investigate the correlation energy equivalence of pair coupled   cluster doubles and doubly occupied configuration interaction
  Over the past few years pair coupled cluster doubles (pCCD) has shown promise for the description of strong correlation. This promise is related to its apparent ability to match results from doubly occupied configuration interaction (DOCI), even though the latter method has exponential computational cost. Here, by modifying the full configuration interaction quantum Monte Carlo (FCIQMC) algorithm to sample only the seniority zero sector of Hilbert space, we show that the DOCI and pCCD energies are in agreement for a variety of 2D Hubbard models, including for systems well out of reach for conventional configuration interaction algorithms. Our calculations are aided by the sign problem being much reduced in the seniority zero space compared with the full space. We present evidence for this, and then discuss the sign problem in terms of the wave function of the system which appears to have a simplified sign structure. 
James J. Shepherd and Thomas M. Henderson and Gustavo E. Scuseria
physics.chem-ph cond-mat.str-el