Interdiffusion in epitaxial ultrathin Co2FeAl/MgO heterostructures with   interface-induced perpendicular magnetic anisotropy
  The structures of epitaxial ultrathin Co2FeAl/MgO(001) heterostructures relating to the interface-induced perpendicular magnetic anisotropy (PMA) were investigated using scanning transmission electron microscopy, energy dispersive x-ray spectroscopy, and x-ray magnetic circular dichroism. We found that Al atoms from the Co2FeAl layer significantly interdiffuse into MgO, forming an Al-deficient Co-Fe-Al/Mg-Al-O structure near the Co2FeAl/MgO interface. This atomic replacement may play an additional role for enhancing PMA, which is consistent with the observed large perpendicular orbital magnetic moments of Fe atoms at the interface. This work suggests that control of interdiffusion at ferromanget/barrier interfaces is critical for designing an interface-induced PMA system. 
Zhenchao Wen, Jason Paul Hadorn, Jun Okabayashi, Hiroaki Sukegawa,   Tadakatsu Ohkubo, Koichiro Inomata, Seiji Mitani, and K...
cond-mat.mtrl-sci