Thermal Stability and Anisotropic Sublimation of Two-Dimensional   Colloidal Bi2Te3 and Bi2Se3 Nanocrystals
  The structural and compositional stabilities of two dimensional 2D Bi2Te3 and Bi2Se3 nanocrystals, produced by both colloidal synthesis and by liquid phase exfoliation, were studied by in situ transmission electron microscopy TEM during annealing at temperatures between 350 and 500 C. The sublimation process induced by annealing is structurally and chemically anisotropic and takes place through the preferential dismantling of the prismatic 011-0 type planes, and through the preferential sublimation of Te or Se. 
Joka Buha, Roberto Gaspari, Antonio Esau Del Rio Castillo, Francesco   Bonaccorso, and Liberato Manna
physics.chem-ph