Colloidal Surfaces with Boundaries, Apex Boojums and Nested Elastic   Self-Assembly of Nematic Colloids
  Self-assembly of colloidal particles is poised to become a powerful composite material fabrication technique, but remains challenged by a limited control over the ensuing structures. We develop a new breed of nematic colloids that are physical analogs of a mathematical surface with boundary, interacting with the molecular alignment field without inducing defects when flat. However, made from a thin nanofoil, they can be shaped to prompt formation of self-compensating defects that drive pre-programmed elastic interactions mediated by the nematic host. To show this, we wrap the nanofoil on all triangular side faces of a pyramid, except its square base. The ensuing pyramidal cones induce point defects with fractional hedgehog charges of opposite signs, spontaneously align with respect to the far-field director to form elastic dipoles and nested assemblies with tunable spacing. Nanofoils shaped into octahedrons interact as elastic quadrupoles. Our findings may drive realization of low-symmetry colloidal phases. 
Sungoh Park, Qingkun Liu, and Ivan I. Smalyukh
cond-mat.soft