Tight-Binding Approximations to Time-Dependent Density Functional Theory   - a fast approach for the calculation of electronically excited states
  We propose a new method of calculating electronically excited states that combines a density functional theory (DFT) based ground state calculation with a linear response treatment that employs approximations used in the time-dependent density functional based tight binding (TD-DFTB) approach. The new method termed TD-DFT+TB does not rely on the DFTB parametrization and is therefore applicable to systems involving all combinations of elements. We show that the new method yields UV/Vis absorption spectra that are in excellent agreement with computationally much more expensive time-dependent density functional theory (TD-DFT) calculations. Errors in vertical excitation energies are reduced by a factor of two compared to TD-DFTB. 
Robert R\"uger, Erik van Lenthe, Thomas Heine and Lucas Visscher
physics.chem-ph