Optical properties of VO$_2$ films at the phase transition: influence of   substrate and electronic correlations
  Thin films of VO$_2$ on different substrates, Al$_2$O$_3$ and SiO$_2$/Si, have been prepared and characterized from room temperature up to 360 K. From the band structure in the rutile metallic phase and in the monoclinic insulating phase the optical properties are calculated and compared with reflection measurements as a function of temperatures. Various interband transitions can be assigned and compared with previous speculations. We extract the parameters of the metallic charge carriers that evolve upon crossing the insulator-to-metal phase transition and find effects by the substrate. The effect of electronic correlations becomes obvious at the phase transition. 
Tobias Peterseim, Martin Dressel, Marc Dietrich, and Angelika Polity
cond-mat.str-el