Ultrafast Electronic Band Gap Control in an Excitonic Insulator
  We report on the nonequilibrium dynamics of the electronic structure of the layered semiconductor Ta$_2$NiSe$_5$ investigated by time- and angle-resolved photoelectron spectroscopy. We show that below the critical excitation density of $F_{C} = 0.2$ mJ cm$^{-2}$, the band gap $narrows$ transiently, while it is $enhanced$ above $F_{C}$. Hartree-Fock calculations reveal that this effect can be explained by the presence of the low-temperature excitonic insulator phase of Ta$_2$NiSe$_5$, whose order parameter is connected to the gap size. This work demonstrates the ability to manipulate the band gap of Ta$_2$NiSe$_5$ with light on the femtosecond time scale. 
Selene Mor, Marc Herzog, Denis Gole\v{z}, Philipp Werner, Martin   Eckstein, Naoyuki Katayama, Minoru Nohara, Hide Takagi, T...
cond-mat.str-el