Novel chemistry of lithium oxides and superconducting low-pressure LiO4
  We study the stability of Li-O compounds as a function of pressure, with Li ion battery applications and fundamental chemical interest in mind. Using the ab initio evolutionary algorithm, we predict stability of novel compounds LiO4, Li5O3 and Li6O under pressure. LiO4, formed at the pressure of just 6 GPa, can be seen as {\epsilon}-O8 accepting two electrons from two Li atoms. This phase is superconducting, with Tc up to 12.2 K at 10 GPa. This is remarkable, because elemental oxygen becomes superconducting at much higher pressure (96 GPa) and has much lower Tc (<0.6 K), and suggests that chemical alloying with other elements has the potential of not only decreasing metallization pressure, but also of increasing Tc. Since {\epsilon}-O8 is called red oxygen, LiO4 can be identified "lithium red-oxid", and is distinct from superoxide. Additionally, Li5O3 is stable at pressures above 70 GPa and can be represented as a hybrid structure 4Li2O {\cdot} Li2O2, and electride suboxide Li6O is stable above 62 GPa. 
Xiao Dong, Yan-Ling Li, Artem R. Oganov, Kuo Li, Haiyan Zheng and   Ho-kwang Mao
cond-mat.mtrl-sci