Quantifying the failure of Schr\"odinger dynamics in the free expansion   of relativistic particles
  It is known that Schr\"odinger equation fails in describing the dynamics of highly energetic particles. We propose to quantify this lack of Lorentz covariance by evaluating the probability for a particle to be measured outside the set of light cones which are compatible to its initial wave function. We consider a simple case of a particle released from a box, which, in turn, is inside a larger container. It is shown that besides the increasing error at relativistic energies, there may be a complete breakdown, with Schr\"odinger dynamics implying in deterministic, superluminal signaling for Lorentz factors above 129. In addition, we give an exact asymptotic expression for the violation in local causality by employing the stationary exponent method, from which the Compton wave length of the particle naturally arises as the relevant scale for the stationary points. 
Ricardo Ximenes and Fernando Parisio
quant-ph