New Carbanion Chemistry for Polymer Synthesis
{'Code': '03070007', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'DMR', 'LongName': 'Division Of Materials Research'}}
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This research deals with various uses of delocalized carbanions                 in polymer synthesis.  For example, they can be used for the                    preparation of novel monomers, can initiate the polymerization                  process, or form macromers.  The work to be carried out will deal               with the preparation of new silarylene and silarylene siloxane                  polymers with potential utility as photoresists, membranes, and                 materials resistant to extreme conditions.  New catenanes will                  also be prepared, as will new types of comb polymers and block                  polymers.  The polymerization process itself and the kinetics of                propagation will be studied by advanced nuclear magnetic                        resonance techniques, with particular attention to the early                    stages of the reaction.
{'FirstName': 'Bernard', 'LastName': 'Gordon', 'PI_MID_INIT': None, 'PI_SUFX_NAME': 'III', 'PI_FULL_NAME': 'Bernard Gordon', 'EmailAddress': 'bg3@polychemistry.com', 'NSF_ID': '000442170', 'StartDate': '04/15/1989', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Pennsylvania State Univ University Park', 'CityName': 'UNIVERSITY PARK', 'ZipCode': '168021503', 'PhoneNumber': '8148651372', 'StreetAddress': '201 OLD MAIN', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Pennsylvania', 'StateCode': 'PA', 'CONGRESSDISTRICT': '15', 'CONGRESS_DISTRICT_ORG': 'PA15', 'ORG_UEI_NUM': 'NPM2J7MSCF61', 'ORG_LGL_BUS_NAME': 'THE PENNSYLVANIA STATE UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
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{'Code': '1773', 'Text': 'POLYMERS'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1988&All=true', 'xml': '8822938.xml'}