Oxidation-Reduction Mechanisms
{'Code': '03090005', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'Margaret A. Cavanaugh', 'PO_EMAI': None, 'PO_PHON': None}
In this project within the Inorganic, Bioinorganic and                          Organometallic Chemistry Program, Henry Taube (Nobel Laureate                   in Chemistry, 1983) of Stanford University will investigate the                 coordination chemistry of vanadium in the oxidation states 2+                   to 5+ in non-aqueous and aqueous solvents. The ultimate aim is                  to devise a useful catalytic system for the oxidation of                        organic substrates by dioxygen. Such a system has important                     implications in synthetic organic chemistry as well as in the                   understanding of fundamental oxygen transfer processes.                                                                                                         The effort will include investigations of the stabilization of                  the different oxidation states of vanadium by various ligands                   and solvents, the structure and composition of the higher                       oxidation state species, the redox chemistry of the various                     oxidation states of vanadium, and the kinetics of the                           substitution and oxygen transfer reactions.
{'FirstName': 'Henry', 'LastName': 'Taube', 'PI_MID_INIT': None, 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Henry Taube', 'EmailAddress': 'HF.CPI@FORSYTHE.STANFORD.EDU', 'NSF_ID': '000299097', 'StartDate': '01/01/1989', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Stanford University', 'CityName': 'STANFORD', 'ZipCode': '943052004', 'PhoneNumber': '6507232300', 'StreetAddress': '450 JANE STANFORD WAY', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'California', 'StateCode': 'CA', 'CONGRESSDISTRICT': '16', 'CONGRESS_DISTRICT_ORG': 'CA16', 'ORG_UEI_NUM': 'HJD6G4D6TJY5', 'ORG_LGL_BUS_NAME': 'THE LELAND STANFORD JUNIOR UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
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{'Code': '1968', 'Text': 'PHYSICAL INORGANIC'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1988&All=true', 'xml': '8816422.xml'}