Phase Behavior of Supercritical Fluid Mixtures for use in   Electroorganic Synthesis
{'Code': '07020000', 'Directorate': {'Abbreviation': 'ENG', 'LongName': 'Directorate For Engineering'}, 'Division': {'Abbreviation': 'CBET', 'LongName': 'Div Of Chem, Bioeng, Env, & Transp Sys'}}
{'SignBlockName': 'Robert M. Wellek', 'PO_EMAI': None, 'PO_PHON': None}
It is the goal of the project to determine the feasibility of                   performing electroorganic reactions in supercritical fluids.  The               synthesis of dimethylformamide, a Kolbe reaction, and the synthesis of          p-aminophenol, from nitrobenzene, have been identified as suitable              candidate reactions.  Initial studies in this project will focus on the         phase behavior of the solvent mixtures of the reacting systems.  In             subsequent electrochemical studies, solution conductivity, surface              overpotential, and reaction selectivity will be determined.  The goal           is to identify combinations of solvents, electrode materials, and               operating conditions where the reactions can be efficiently performed.          Operation in the supercritical region may lead to enhanced mass                 transport, increased selectivity, increased reactant solubility, and            improved product separation.
{'FirstName': 'Mark', 'LastName': 'McHugh', 'PI_MID_INIT': 'A', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Mark A McHugh', 'EmailAddress': 'mmchugh@vcu.edu', 'NSF_ID': '000271327', 'StartDate': '09/01/1986', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Johns Hopkins University', 'CityName': 'BALTIMORE', 'ZipCode': '212182608', 'PhoneNumber': '4439971898', 'StreetAddress': '3400 N CHARLES ST', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Maryland', 'StateCode': 'MD', 'CONGRESSDISTRICT': '07', 'CONGRESS_DISTRICT_ORG': 'MD07', 'ORG_UEI_NUM': 'FTMTDMBR29C7', 'ORG_LGL_BUS_NAME': 'THE JOHNS HOPKINS UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
{'Name': None, 'CityName': None, 'StateCode': None, 'ZipCode': None, 'StreetAddress': None, 'CountryCode': None, 'CountryName': None, 'StateName': None, 'CountryFlag': None, 'CONGRESSDISTRICT': None, 'CONGRESS_DISTRICT_PERF': '""'}
{'Code': '1414', 'Text': 'INTERFAC PROCESSES & THERMODYN'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1986&All=true', 'xml': '8616366.xml'}