Free-Radical Reactions in Supercritical Fluids
{'Code': '07020000', 'Directorate': {'Abbreviation': 'ENG', 'LongName': 'Directorate For Engineering'}, 'Division': {'Abbreviation': 'CBET', 'LongName': 'Div Of Chem, Bioeng, Env, & Transp Sys'}}
{'SignBlockName': 'Maria Burka', 'PO_EMAI': None, 'PO_PHON': None}
The objectives of this research are to investigate the kinetics of              free-radical initiation reactions carried out in the single-phase,              mixture-critical region.  Research will determine the effect of the             solvent properties of mixtures in their critical region (enhanced               diffusivity, reduced viscosity, and enhanced solvent power) on the rate         of formation of primary radicals via homolytic scission.  The                   information generated in this study should suggest novel and more               efficient means for performing reactions and separating reaction                mixtures for many free-radical reactions such as polymerizations and            oxidations.  There is a change in mechanisms (viscosity and energy-             transfer effects) which occur in going from a gas-phase to a liquid-            phase reaction medium.
{'FirstName': 'Mark', 'LastName': 'McHugh', 'PI_MID_INIT': 'A', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Mark A McHugh', 'EmailAddress': 'mmchugh@vcu.edu', 'NSF_ID': '000271327', 'StartDate': '04/01/1987', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Johns Hopkins University', 'CityName': 'BALTIMORE', 'ZipCode': '212182608', 'PhoneNumber': '4439971898', 'StreetAddress': '3400 N CHARLES ST', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Maryland', 'StateCode': 'MD', 'CONGRESSDISTRICT': '07', 'CONGRESS_DISTRICT_ORG': 'MD07', 'ORG_UEI_NUM': 'FTMTDMBR29C7', 'ORG_LGL_BUS_NAME': 'THE JOHNS HOPKINS UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
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[{'Code': '1401', 'Text': 'Catalysis'}, {'Code': '1403', 'Text': 'Proc Sys, Reac Eng & Mol Therm'}]
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1986&All=true', 'xml': '8617353.xml'}