X-Ray Absorption Spectroscopy of Electrochemically GeneratedSpecies
{'Code': '03090006', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'Henry N. Blount, III', 'PO_EMAI': None, 'PO_PHON': None}
This project is in the general area of analytical and surface                   chemistry and in the subfield of spectroelectrochemistry.  The                  thrust of this project is to combine x-ray absorption                           spectroscopy and thin-layer electrochemistry and to carry out                   in situ characterization of electrochemically generated species                 in terms of oxidation state, coordination number, donor atom                    type, and bond length.  The materials to be studied include                     metal complexes in polymer-modified electrodes and metal-metal                  bonded molybdenum and tungsten dimers.  The principal                           investigators will also design and build electrochemical cells                  which may reduce or prevent x-ray induced sample damages.  Such                 cells may be extremely useful for x-ray absorption                              spectroscopic studies of bioinorganic materials.  This research                 should be important to an enhanced understanding of structural                  aspects of electron transfer reactions.
[{'FirstName': 'William', 'LastName': 'Heineman', 'PI_MID_INIT': 'R', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'William R Heineman', 'EmailAddress': 'william.heineman@uc.edu', 'NSF_ID': '000376793', 'StartDate': '07/01/1987', 'EndDate': None, 'RoleCode': 'Co-Principal Investigator'}, {'FirstName': 'Richard', 'LastName': 'Elder', 'PI_MID_INIT': 'C', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Richard C Elder', 'EmailAddress': None, 'NSF_ID': '000393911', 'StartDate': '07/01/1987', 'EndDate': None, 'RoleCode': 'Principal Investigator'}]
{'Name': 'University of Cincinnati Main Campus', 'CityName': 'CINCINNATI', 'ZipCode': '452202872', 'PhoneNumber': '5135564358', 'StreetAddress': '2600 CLIFTON AVE', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Ohio', 'StateCode': 'OH', 'CONGRESSDISTRICT': '01', 'CONGRESS_DISTRICT_ORG': 'OH01', 'ORG_UEI_NUM': 'DZ4YCZ3QSPR5', 'ORG_LGL_BUS_NAME': 'CINCINNATI UNIV OF', 'ORG_PRNT_UEI_NUM': 'DZ4YCZ3QSPR5'}
{'Name': None, 'CityName': None, 'StateCode': None, 'ZipCode': None, 'StreetAddress': None, 'CountryCode': None, 'CountryName': None, 'StateName': None, 'CountryFlag': None, 'CONGRESSDISTRICT': None, 'CONGRESS_DISTRICT_PERF': '""'}
{'Code': '197200', 'Text': 'ELECTROCHEMISTRY & SURFACE CHE'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1987&All=true', 'xml': '8701254.xml'}