Thermochemical and Kinetics Studies of Important Radicals   and the Thermochemistry of Aqueous Solutions and            Solid Salts
{'Code': '03090004', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'Francis J. Wodarczyk', 'PO_EMAI': None, 'PO_PHON': None}
This research, in chemical kinetics, is supported as part                   of the Physical Chemistry Experimental Program.  It is                          important for the understanding of the basic processes that                     take place in simple gas phase chemical reactions.                                   A unique very low pressure reactor has been implemented to                 study the chemical kinetics, including elementary processes                     rate constants, of reactions involving hydrogen atom addition                   to allylic species.  These reactions will be used to generate                   radicals such as the ethyl, isopropyl, tertiary butyl, HO2,                     RO2, phenyl, etc.  Disproportionation of these species and                      their reactions with halogen and hydrogen atoms will be                         studied.  Outputs of this research will be elementary chemical                  kinetic data and enthalpies of formation of these radicals as                   well as basic information on chemical bonding and reactivity.
{'FirstName': 'Sidney', 'LastName': 'Benson', 'PI_MID_INIT': 'W', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Sidney W Benson', 'EmailAddress': None, 'NSF_ID': '000165205', 'StartDate': '12/01/1987', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'University of Southern California', 'CityName': 'LOS ANGELES', 'ZipCode': '90033', 'PhoneNumber': '2137407762', 'StreetAddress': '3720 S FLOWER ST FL 3', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'California', 'StateCode': 'CA', 'CONGRESSDISTRICT': '34', 'CONGRESS_DISTRICT_ORG': 'CA34', 'ORG_UEI_NUM': 'G88KLJR3KYT5', 'ORG_LGL_BUS_NAME': 'UNIVERSITY OF SOUTHERN CALIFORNIA', 'ORG_PRNT_UEI_NUM': None}
{'Name': None, 'CityName': None, 'StateCode': None, 'ZipCode': None, 'StreetAddress': None, 'CountryCode': None, 'CountryName': None, 'StateName': None, 'CountryFlag': None, 'CONGRESSDISTRICT': None, 'CONGRESS_DISTRICT_PERF': '""'}
{'Code': '196200', 'Text': 'SPECTROSCOPY'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1987&All=true', 'xml': '8714647.xml'}