Gas Phase Organometallic Chemistry
{'Code': '03090004', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'Lawrence L. Lohr, Jr.', 'PO_EMAI': None, 'PO_PHON': None}
Professor Beauchamp will apply modern techniques of                        experimental physical chemistry to investigate the detailed                     reaction dynamics of small molecules at transition metal                        centers in the gas phase.  In conjunction with ab-initio                        theoretical calculations, these studies are directed at                         characterizing important features of potential energy surfaces                  for organometallic reactions, from the initial interaction of                   the reactants to a study of energy disposal in the products.                    These studies will be accomplished by using Fourier transform                   ion cyclotron resonance spectroscopy, ion beam techniques, and                  laser photochemical methods.                                                                                                                                         Research goals of this work include the determination of                   accurate metal-ligand bond dissociation energies determination                  of activation parameters for elementary reaction steps, the                     measurement of product kinetic energy distributions, and a                      comparison of the effect of translational, vibrational, and                     electronic energy in promoting organometallic reactions.  The                   fundamental information derived in these studies is of                          considerable importance in the general areas of homogeneous and                 heterogeneous catalysis.
{'FirstName': 'Jesse', 'LastName': 'Beauchamp', 'PI_MID_INIT': 'L', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Jesse L Beauchamp', 'EmailAddress': 'jlbchamp@caltech.edu', 'NSF_ID': '000460679', 'StartDate': '12/01/1987', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'California Institute of Technology', 'CityName': 'PASADENA', 'ZipCode': '911250001', 'PhoneNumber': '6263956219', 'StreetAddress': '1200 E CALIFORNIA BLVD', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'California', 'StateCode': 'CA', 'CONGRESSDISTRICT': '28', 'CONGRESS_DISTRICT_ORG': 'CA28', 'ORG_UEI_NUM': 'U2JMKHNS5TG4', 'ORG_LGL_BUS_NAME': 'CALIFORNIA INSTITUTE OF TECHNOLOGY', 'ORG_PRNT_UEI_NUM': None}
{'Name': None, 'CityName': None, 'StateCode': None, 'ZipCode': None, 'StreetAddress': None, 'CountryCode': None, 'CountryName': None, 'StateName': None, 'CountryFlag': None, 'CONGRESSDISTRICT': None, 'CONGRESS_DISTRICT_PERF': '""'}
{'Code': '1960', 'Text': 'STRUCTURE AND REACTIVITY'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1987&All=true', 'xml': '8711567.xml'}