Ligand Effects on the Redox Chemistry of (Oxo)Ruthenium(IV) Complexes
{'Code': '03090005', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'Margaret A. Cavanaugh', 'PO_EMAI': None, 'PO_PHON': None}
The Inorganic, Bioinorganic and Organometallic Chemistry                        Program supports research in the area of potential new                          catalysts for chemical transformations.  In this project                        Kenneth J. Takeuchi of The State Universsity of New York at                     Buffalo will investigate the synthesis and properties of                        several new series of ruthenium coordination compounds which                    may be potential catalysts for the oxidation of inorganic and                   organic substrates as well as possible model compounds for                      metal oxide surfaces, which are used as heterogeneous catalysts                 in many important industrial processes.                                                                                                                         Several new families of oxoruthenium(IV) complexes will be                      synthesized with various auxiliary ligands such as tertiary                     phosphines, cyclopentadienyl, macrocycles (for example,                         bisı{difluoro}dioximato!) and a (clathrochelate)cobalt ligand.                  The kinetics and mechanisms of organic and inorganic substrate                  oxidation reactions with these compounds behaving as                            stoichiometric or catalytic reagents will be studied.  The                      steric and hydrophobic effects of the auxiliary ligands on                      these reactions will be assessed.
{'FirstName': 'Kenneth', 'LastName': 'Takeuchi', 'PI_MID_INIT': 'J', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Kenneth J Takeuchi', 'EmailAddress': 'kenneth.takeuchi.1@stonybrook.edu', 'NSF_ID': '000621733', 'StartDate': '12/01/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'SUNY at Buffalo', 'CityName': 'AMHERST', 'ZipCode': '142282577', 'PhoneNumber': '7166452634', 'StreetAddress': '520 LEE ENTRANCE STE 211', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'New York', 'StateCode': 'NY', 'CONGRESSDISTRICT': '26', 'CONGRESS_DISTRICT_ORG': 'NY26', 'ORG_UEI_NUM': 'LMCJKRFW5R81', 'ORG_LGL_BUS_NAME': 'RESEARCH FOUNDATION FOR THE STATE UNIVERSITY OF NEW YORK, THE', 'ORG_PRNT_UEI_NUM': 'GMZUKXFDJMA9'}
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{'Code': '1968', 'Text': 'PHYSICAL INORGANIC'}
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