Synthetic Studies in Homogeneous Catalysis and              Organometallic Chemistry
{'Code': '03090005', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'Raymond Mackay', 'PO_EMAI': None, 'PO_PHON': None}
This project in the Inorganic, Bioinorganic and Organometallic                  Chemistry Program is in the general area of organometallic                      chemistry and deals specifically with the chemistry of                          metalloporphyrin compounds. The research is intended to produce                 a set of new and unusual substances whose physical and chemical                 properties will add to the fundamental understanding of the                     structural chemistry of heavy metal compounds, and which may                    also be useful as catalysts or as magnetic polymers.                                                                                                            The project encompasses synthetic and physical studies of 4d                    and 5d metalloporphyrin complexes in the following five areas:                  multiple metal-metal bonded dimers, organometallic chemistry,                   electrically conducting and ferromagnetic polymers, electrode                   catalysts for multielectron reduction of dioxygen and                           dinitrogen, and dioxygen binding by complexes of ruthenium,                     osmium and rhodium "picnic basket" porphyrins. Among the                        different methodologies to be employed are inorganic and                        organic synthesis, structure determination, electrochemistry,                   NMR spectroscopy, measurements of magnetism, polymer chemistry                  and conductivity measurements.
{'FirstName': 'James', 'LastName': 'Collman', 'PI_MID_INIT': 'P', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'James P Collman', 'EmailAddress': 'jpc@stanford.edu', 'NSF_ID': '000403372', 'StartDate': '12/01/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Stanford University', 'CityName': 'STANFORD', 'ZipCode': '943052004', 'PhoneNumber': '6507232300', 'StreetAddress': '450 JANE STANFORD WAY', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'California', 'StateCode': 'CA', 'CONGRESSDISTRICT': '16', 'CONGRESS_DISTRICT_ORG': 'CA16', 'ORG_UEI_NUM': 'HJD6G4D6TJY5', 'ORG_LGL_BUS_NAME': 'THE LELAND STANFORD JUNIOR UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
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{'Code': '1966', 'Text': 'SYNTHETIC INORGANIC'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1988&All=true', 'xml': '8814949.xml'}