Electrocatalytic Organic Oxidations by Some Mono and        Binuclear Complexes of Ruthenium, Osmium, and Manganese
{'Code': '07020000', 'Directorate': {'Abbreviation': 'ENG', 'LongName': 'Directorate For Engineering'}, 'Division': {'Abbreviation': 'CBET', 'LongName': 'Div Of Chem, Bioeng, Env, & Transp Sys'}}
{'SignBlockName': 'Farley Fisher', 'PO_EMAI': None, 'PO_PHON': None}
This is a study of the electrocatalytic properties of mononuclear               and binuclear complexes of ruthenium, osmium, and manganese                     towards oxidation of organic  substrates.  The ligands used                     should stabilize high oxidation states; these will be prepared                  chemically or electrochemically and characterized by such                       techniques as cyclic voltammentry and spectroelectrochemistry.                  The electrocatalytic behavior of these species will then be                     studied under two different circumstances:  with the                            electrocatalyst bound to the electrode, and with the                            electrocatalyst in the electrolyte solution.  Current                           distribution and electrochemical kinetics will be measured.                     Potential (but clearly future) applications of this work include                fuel cells, electrosynthesis, and detoxification of hazardous                   waste.
{'FirstName': 'Shantha', 'LastName': 'Sarangapani', 'PI_MID_INIT': None, 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Shantha Sarangapani', 'EmailAddress': '74763.2400@compuserve.com', 'NSF_ID': '000122844', 'StartDate': '01/01/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Tufts University', 'CityName': 'SOMERVILLE', 'ZipCode': '021442401', 'PhoneNumber': '6176273696', 'StreetAddress': '169 HOLLAND ST', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Massachusetts', 'StateCode': 'MA', 'CONGRESSDISTRICT': '07', 'CONGRESS_DISTRICT_ORG': 'MA07', 'ORG_UEI_NUM': 'WL9FLBRVPJJ7', 'ORG_LGL_BUS_NAME': 'TRUSTEES OF TUFTS COLLEGE', 'ORG_PRNT_UEI_NUM': 'S6ZWCYHRQQB3'}
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[{'Code': '1401', 'Text': 'Catalysis'}, {'Code': '9120', 'Text': 'CROSS-DIRECTORATE PROGRAMS'}]
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1987&All=true', 'xml': '8704587.xml'}