Amine Directed, Cobalt Catalyzed Cyclizations in Organic    Synthesis (Chemistry)
{'Code': '03090003', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'George M. Rubottom', 'PO_EMAI': None, 'PO_PHON': None}
This grant in the Organic and Macromolecular Chemistry Program is               directed towards the development of new synthetic organic methods,              which will permit the preparation of new materials of biological and            theoretical interest.                                                                                                                                           New synthetic methodology will be developed for the regiospecific               formation of carbon-carbon bonds using a cobalt-catalyzed cyclization.          Regiospecificity is to be obtained by the use of a directing ligand on          one of the two cyclization substrates.  Specificity of the ligand               directed-olefin-acetylene cyclization to form cyclopentenones has               already been demonstrated.  The functionality generated in an olefin-           acetylene cyclization (Khand-Pauson reaction) can be utilized in a              three-carbon ring expansion sequence.  Potential applications of the            ring expansion to problems in natural product synthesis are envisioned.
{'FirstName': 'Marie', 'LastName': 'Krafft', 'PI_MID_INIT': 'E', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Marie E Krafft', 'EmailAddress': 'mek@chem.fsu.edu', 'NSF_ID': '000246503', 'StartDate': '06/01/1987', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Florida State University', 'CityName': 'TALLAHASSEE', 'ZipCode': '323060001', 'PhoneNumber': '8506445260', 'StreetAddress': '874 TRADITIONS WAY', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Florida', 'StateCode': 'FL', 'CONGRESSDISTRICT': '02', 'CONGRESS_DISTRICT_ORG': 'FL02', 'ORG_UEI_NUM': 'JF2BLNN4PJC3', 'ORG_LGL_BUS_NAME': 'FLORIDA STATE UNIVERSITY', 'ORG_PRNT_UEI_NUM': 'D4GCCCMXR1H3'}
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{'Code': '1950', 'Text': 'METHODOLOGY'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1987&All=true', 'xml': '8704933.xml'}