Engineered Zeolites and Their Use in Continuous             Regioselective Chlorination
{'Code': '15030000', 'Directorate': {'Abbreviation': 'TIP', 'LongName': 'Dir for Tech, Innovation, & Partnerships'}, 'Division': {'Abbreviation': 'TI', 'LongName': 'Translational Impacts'}}
{'SignBlockName': 'Ritchie B. Coryell', 'PO_EMAI': None, 'PO_PHON': None}
This is an investigation of zeolite (aluminosilicate) crystals with             oliophilic cores and oliophobic shells and the use of such materials            to promote terminal photochemical chlorination of higher hydrocarbons.          Synthesis conditions and reactor designs are established to produce             zeolites with surfaces high in aluminum and cores devoid of aluminum.           Previous results show that such materials produce strong                        regioselectivity for the terminal methly group in photochlorination of          long-chain hydrocarbons.  The mechanism and scope of this effect is             probed.  A fluidized-bed chlorination system to exploit this                    phenomenon is being designed and built.                                                                                                                         This work suggests that a technology based on continuous                        regioselective photochlorination processes is feasible.  This would             make available new (or more efficient synthesis of old) moieties for            surfactants, polymers, lubricants, textile finishes, flame retardants,          and other materials.
{'FirstName': 'Warren', 'LastName': 'Ruderman', 'PI_MID_INIT': None, 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Warren Ruderman', 'EmailAddress': 'inrad@aol.com', 'PI_PHON': '2017671910', 'NSF_ID': '000119943', 'StartDate': '09/01/1989', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'INRAD, Inc.', 'CityName': 'NORTHVALE', 'ZipCode': '076472404', 'PhoneNumber': '2017671910', 'StreetAddress': '181 LEGRAND AVE', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'New Jersey', 'StateCode': 'NJ', 'CONGRESSDISTRICT': '05', 'CONGRESS_DISTRICT_ORG': 'NJ05', 'ORG_UEI_NUM': 'HWMBNYNGLSL3', 'ORG_LGL_BUS_NAME': 'INRAD OPTICS, INC.', 'ORG_PRNT_UEI_NUM': 'HWMBNYNGLSL3'}
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{'Code': '5373', 'Text': 'SBIR Phase II'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1989&All=true', 'xml': '8900386.xml'}