Chemistry of Transition Metal/Main Group Element Complexes
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{'SignBlockName': 'Jon F. Parcher', 'PO_EMAI': None, 'PO_PHON': None}
The focus of this project in the Inorganic, Bioinorganic and                    Organometallic Chemistry Program is structure, bonding and                      reactivity in transition metal/main group element compounds.                    Much of the work utilizes as a template a chiral rhenium                        complex, which is readily available in optically active form.                   This facilitates mechanistic tests and application of the                       findings in asymmetric synthesis. Specific goals include the                    synthesis and study of (1) alkyl halide complexes, a virtually                  unknown class of compounds; (2) complexes of unsaturated                        organosilicon ligands, such as silylene, disilene and silene                    complexes; and (3) phosphido, amide and sulfoxide complexes. It                 is probable that general methods for the activation of alkyl                    halides and for asymmetric oxidation of sulfides will be                        developed.                                                                                                                                                      Basic research on the molecular chemistry of phosphorus and                     silicon is important because of the many uses which these main                  group elements find in materials science (photoresists,                         ceramics, composits, etc.), often in combination with a metal.
{'FirstName': 'John', 'LastName': 'Gladysz', 'PI_MID_INIT': 'A', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'John A Gladysz', 'EmailAddress': 'gladysz@mail.chem.tamu.edu', 'NSF_ID': '000329445', 'StartDate': '06/01/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'University of Utah', 'CityName': 'SALT LAKE CITY', 'ZipCode': '841129049', 'PhoneNumber': '8015816903', 'StreetAddress': '201 PRESIDENTS CIR', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Utah', 'StateCode': 'UT', 'CONGRESSDISTRICT': '01', 'CONGRESS_DISTRICT_ORG': 'UT01', 'ORG_UEI_NUM': 'LL8GLEVH6MG3', 'ORG_LGL_BUS_NAME': 'UNIVERSITY OF UTAH', 'ORG_PRNT_UEI_NUM': None}
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