Single-Atom Peri-Bridged Arenes and Hetarenes: Carbenic     and Silicanionic Processes (Chemistry)
{'Code': '03090003', 'Directorate': {'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'George M. Rubottom'}
This project is being supported by the Organic and                              Macromolecular Chemistry Program.  A variety of novel                           structure-types and novel chemical reactions are being                          investigated which include pentacoordinate organosilicon                        compounds, strained-bridged aromatic compounds, and unusual                     carbenoid and radical containing organic compounds.                                                                                                             Study is being made of (1) synthesis and the chemistry of novel                 single-atom peri-bridged arenes and their derivatives, (2) the                  products, stereochemistry and mechanisms of pentacoordinate                     addition-rearrangement-ejection reactions of                                    alpha-haloalkylsilanes with nucleophiles, (3) generation and                    the behavior of metallized carbenes, carbynes and alpha-diazo                   radicals and (4) carbenic capture and aromatic substitution and                 expansion processes involving conjugative alpha-elimination and                 addition.
{'FirstName': 'Harold', 'LastName': 'Shechter', 'EmailAddress': None, 'StartDate': '07/01/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Ohio State University Research Foundation -DO NOT USE', 'CityName': 'Columbus', 'ZipCode': '432101016', 'PhoneNumber': '6146888734', 'StreetAddress': '1960 KENNY RD', 'CountryName': 'United States', 'StateName': 'Ohio', 'StateCode': 'OH'}
{'Code': '1950', 'Text': 'METHODOLOGY'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1988&All=true', 'xml': '8805511.xml'}