Photoinduced Electron Transfer
{'Code': '03090005', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'Margaret A. Cavanaugh', 'PO_EMAI': None, 'PO_PHON': None}
The Inorganic, Bioinorganic and Organometallic Chemisty Program                 supports research on intramolecular light-induced electron                      transfer in chemical systems.  The research may give insight                    into the ability of the photosynthetic reaction center to                       continue to function at low temperatures.                                                                                                                       Investigations of photoinduced electron and energy transfer in                  complex intramolecular systems will be continued. The studies                   will be based on the metal-to-ligand charge transfer (MLCT)                     excited states of polypyridyl complexes of Ru(II), Os(II) or                    Re(I), incorporated into chromophore-quencher or                                ligand-bridged, dimeric metal complex assemblies.  In properly                  designed cases, it will be possible to explore intramolecular                   electron and energy transfer and competition between these                      processes in complex molecules, the appearance and decay of                     long-lived charge separated states and the role of solvent and,                 in some cases, pH, in dictating transition rates and lifetimes.
{'FirstName': 'Thomas', 'LastName': 'Meyer', 'PI_MID_INIT': 'J', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Thomas J Meyer', 'EmailAddress': 'tjmeyer@unc.edu', 'NSF_ID': '000277206', 'StartDate': '07/15/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'University of North Carolina at Chapel Hill', 'CityName': 'CHAPEL HILL', 'ZipCode': '275995023', 'PhoneNumber': '9199663411', 'StreetAddress': '104 AIRPORT DR STE 2200', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'North Carolina', 'StateCode': 'NC', 'CONGRESSDISTRICT': '04', 'CONGRESS_DISTRICT_ORG': 'NC04', 'ORG_UEI_NUM': 'D3LHU66KBLD5', 'ORG_LGL_BUS_NAME': 'UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL', 'ORG_PRNT_UEI_NUM': 'N8DMK1K4C2K5'}
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[{'Code': '1968', 'Text': 'PHYSICAL INORGANIC'}, {'Code': '9120', 'Text': 'CROSS-DIRECTORATE PROGRAMS'}]
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