Synthesis and Reactions of 2-Arenesulfonoxy Carbonyl        Compounds (Chemistry)
{'Code': '03090003', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'George M. Rubottom', 'PO_EMAI': None, 'PO_PHON': None}
This project in the Organic and Macromolecular Chemistry Program                is a continuation of studies on the design and development of                   fundamentally new reactions and reagents for organic synthesis.                                                                                                 The project will investigate the synthesis and use of 2-                        arenesulfonoxy carbonyl compounds as synthetic intermediates for                the selective and controlled preparation of a variety of carbonyl               derivatives.  This effort is based on the observation that these                materials are distinctly different in their reactivity than                     functionally similar 2-halo carbonyl compounds.  Four specific                  objectives of the project are: (1) to prepare 2-arenesulfonoxy                  derivatives of esters and amides, (2) to utilize the acidity of                 the 2-position to elaborate simple 2-arenesulfonoxy carbonyls                   into more complex ones, (3) to examine the alpha-substitution of                these compounds as a facile route to substituted carbonyl                       compounds, and (4) to the apply methods of synthesis of 2-                      arenesulfonoxy carbonyl compounds as a new method for the                       generation and trapping of oxonium and iminium ions.
{'FirstName': 'Robert', 'LastName': 'Hoffman', 'PI_MID_INIT': 'V', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Robert V Hoffman', 'EmailAddress': 'rhoffman@nmsu.edu', 'NSF_ID': '000280218', 'StartDate': '07/01/1987', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'New Mexico State University', 'CityName': 'LAS CRUCES', 'ZipCode': '88003', 'PhoneNumber': '5756461590', 'StreetAddress': '1050 STEWART ST.', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'New Mexico', 'StateCode': 'NM', 'CONGRESSDISTRICT': '02', 'CONGRESS_DISTRICT_ORG': 'NM02', 'ORG_UEI_NUM': 'J3M5GZAT8N85', 'ORG_LGL_BUS_NAME': 'NEW MEXICO STATE UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
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[{'Code': '194800', 'Text': 'SYNTHESIS'}, {'Code': '195000', 'Text': 'METHODOLOGY'}]
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1987&All=true', 'xml': '8709853.xml'}