New Highly Conducting Molecular Crystals
{'Code': '03070007', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'DMR', 'LongName': 'Division Of Materials Research'}}
{'SignBlockName': 'David Nelson', 'PO_EMAI': None, 'PO_PHON': None}
The program is devoted to the synthesis and characterization of                 novel conductive and magnetic materials based on metal-organic                  (M(L)) complexes.  Section I of this proposal describes the study               of quasi one-dimensional molecular metals that are propared from                metalloporphyrins and phthalocyanines.  These show remarkable                   properties without parallel in other classes of material, in                    particular a new type of low-temperature condensation within an                 M(L) stack that exhibits a one-dimensional spine of metal-ion                   local moments embedded within the "Fermi Sea" of a conducting                   organic framework.                                                                                                                                              Section II describes the synthesis of planar surfur-encircled                   metallomacrocycles that can engage in highly three-dimensional                  interactions.  These compounds will also be used to prepare                     multi-metal porphyrin complexes and well-defined, two-dimensional               metal-linked polymers that will be studied as films and fibers.                                                                                                 Section III describes the preparation of new materials based on                 tris-dichalcogenide complexes of transition-metal ions.  These                  complexes provide inherently three-dimensional building blocks                  for the synthesis of molecular metals, superconductors and                      ferromagnets.
{'FirstName': 'Brian', 'LastName': 'Hoffman', 'PI_MID_INIT': 'M', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Brian M Hoffman', 'EmailAddress': 'bmh@northwestern.edu', 'NSF_ID': '000308456', 'StartDate': '01/01/1989', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Northwestern University', 'CityName': 'EVANSTON', 'ZipCode': '602080001', 'PhoneNumber': '3125037955', 'StreetAddress': '633 CLARK ST', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Illinois', 'StateCode': 'IL', 'CONGRESSDISTRICT': '09', 'CONGRESS_DISTRICT_ORG': 'IL09', 'ORG_UEI_NUM': 'EXZVPWZBLUE8', 'ORG_LGL_BUS_NAME': 'NORTHWESTERN UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
{'Name': None, 'CityName': None, 'StateCode': None, 'ZipCode': None, 'StreetAddress': None, 'CountryCode': None, 'CountryName': None, 'StateName': None, 'CountryFlag': None, 'CONGRESSDISTRICT': None, 'CONGRESS_DISTRICT_PERF': '""'}
{'Code': '176200', 'Text': 'SOLID STATE & MATERIALS CHEMIS'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1988&All=true', 'xml': '8818599.xml'}