Studies of Vibrationally and Rotationally Exited Polyatomic Molecules Using Almost Degenerate Perturbation Theory
{'Code': '03090004', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'David M. Stanbury', 'PO_EMAI': None, 'PO_PHON': None}
This project in the Theoretical and Computational Chemistry                     Program will investigate intramolecular redistribution of                       rotational and vibrational energy, a key component in many                      aspects of chemical dynamics. With the advent of the laser,                     these chemical events can now be experimentally scrutinized at                  the state-to-state level.  The objective of this research is to                 develop theoretical methods to elucidate the mechanisms and                     pathways of this energy flow.  The method of Almost Degenerate                  Perturbation Theory will be developed to allow investigation of                 energy regimes and densities of states hitherto unattainable by                 other methods.  This will allow for determination of how the                    effects of multiple resonance interactions combined with                        increasing densities of states leads to the statistical like                    properties associated with reaction rate theories.
{'FirstName': 'Edwin', 'LastName': 'Sibert', 'PI_MID_INIT': 'L', 'PI_SUFX_NAME': 'III', 'PI_FULL_NAME': 'Edwin L Sibert', 'EmailAddress': 'sibert@chem.wisc.edu', 'NSF_ID': '000178260', 'StartDate': '01/01/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'University of Wisconsin-Madison', 'CityName': 'MADISON', 'ZipCode': '537151218', 'PhoneNumber': '6082623822', 'StreetAddress': '21 North Park Street', 'StreetAddress2': 'Suite 6301', 'CountryName': 'United States', 'StateName': 'Wisconsin', 'StateCode': 'WI', 'CONGRESSDISTRICT': '02', 'CONGRESS_DISTRICT_ORG': 'WI02', 'ORG_DUNS_NUM': '161202122', 'ORG_LGL_BUS_NAME': 'UNIVERSITY OF WISCONSIN SYSTEM', 'ORG_PRNT_DUNS_NUM': '041188822'}
{'Name': None, 'CityName': None, 'StateCode': None, 'ZipCode': None, 'StreetAddress': None, 'CountryCode': None, 'CountryName': None, 'StateName': None, 'CountryFlag': None, 'CONGRESSDISTRICT': None, 'CONGRESS_DISTRICT_PERF': '""'}
{'Code': '1954', 'Text': 'QUANTUM CALCULATIONS'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1987&All=true', 'xml': '8713749.xml'}