Photochemical Reactions of Metal Carbynes
{'Code': '03090005', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'Margaret A. Cavanaugh', 'PO_EMAI': None, 'PO_PHON': None}
The Inorganic, Bioinorganic and Organometallic Chemistry                        Program supports research in the area of photochemistry of                      transition metal coordination compounds.  In this project Lisa                  McElwee-White of Stanford University will investigate the                       photochemical reactions of metal carbynes which will involve                    activation of the metal-carbon triple bond and subsequent                       reaction to form new chemical compounds through novel reaction                  pathways.  This research will be of importance in the                           understanding of the fundamental processes occurring in the                     photochemistry of organometallic compounds.                                                                                                                     The focus of the research will be low valent molybdenum and                     tungsten carbynes, such as chlorotetrakis(trimethylphosphite)-                  tungsten phenylcarbyne, which contain ancillary ligands which                   are not photoactive.  Studies of the reactivity of the                          activated metal carbyne triple bond will be of two types:                       (a) unimolecular reactions such as ligand rearrangements or                     intramolecular trapping with tethered functionality;                            (b) bimolecular reactions with added reagents.
{'FirstName': 'Lisa', 'LastName': 'McElwee-White', 'PI_MID_INIT': None, 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Lisa McElwee-White', 'EmailAddress': 'lmwhite@chem.ufl.edu', 'NSF_ID': '000407786', 'StartDate': '12/01/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Stanford University', 'CityName': 'STANFORD', 'ZipCode': '943052004', 'PhoneNumber': '6507232300', 'StreetAddress': '450 JANE STANFORD WAY', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'California', 'StateCode': 'CA', 'CONGRESSDISTRICT': '16', 'CONGRESS_DISTRICT_ORG': 'CA16', 'ORG_UEI_NUM': 'HJD6G4D6TJY5', 'ORG_LGL_BUS_NAME': 'THE LELAND STANFORD JUNIOR UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
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{'Code': '1968', 'Text': 'PHYSICAL INORGANIC'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1988&All=true', 'xml': '8814729.xml'}