Interactions of the Cage Compounds ?RA1NR'! with Transition Metal Carbonyl Complexes
{'Code': '03090005', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'John B. Hunt'}
This award is a Research Planning Grant under the Research                      Opportunities for Women Program. The research project which                     will be planned under this grant involves the use of cage-like                  compounds of aluminum and nitrogen to simulate some of the                      features of activated metal oxide surfaces which are used as                    catalyst supports. These cage compounds resemble the surfaces                   in electronic properties, low coordination number, and                          multiplicity of active sites. The goal of the research is to                    induce and characterize multiple interactions of the cage                       compounds with transition metal carbonyl complexes. The                         reaction chemistry and photochemistry of the cage-transition                    metal compounds will be examined. These homogeneous systems                     will provide interesting contrasts to the chemistry of                          catalysts composed of transition metal compounds supported on                   metal oxide surfaces. A better understanding of the                             relationship between surface effects and the catalytic activity                 of the heterogeneous species is expected to result from the                     work.
{'FirstName': 'Claire', 'LastName': 'Tessier', 'EmailAddress': 'Tessier@uakron.edu', 'StartDate': '07/01/1987', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Case Western Reserve University', 'CityName': 'CLEVELAND', 'ZipCode': '441064901', 'PhoneNumber': '2163684510', 'StreetAddress': 'Nord Hall, Suite 615', 'CountryName': 'United States', 'StateName': 'Ohio', 'StateCode': 'OH'}
{'Code': '1966', 'Text': 'SYNTHETIC INORGANIC'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1987&All=true', 'xml': '8708031.xml'}