Industry/University Cooperative Project:  Thermodynamic     Properties of Ionic Organic Molecules in Aqueous Solutions
{'Code': '07020000', 'Directorate': {'Abbreviation': 'ENG', 'LongName': 'Directorate For Engineering'}, 'Division': {'Abbreviation': 'CBET', 'LongName': 'Div Of Chem, Bioeng, Env, & Transp Sys'}}
{'SignBlockName': 'Robert M. Wellek', 'PO_EMAI': None, 'PO_PHON': None}
A theory for the thermodynamic properties (solubilities, vapor                  pressures, distribution coefficients) of ionic organic molecules is to          be developed.  Experiments are performed to test its accuracy and               limitations.   The theory is to be created from two existing, but               unrelated theories, the Perturbed Anisotropic Chain Theory (PACT) and           the Restricted Primative Model (RPM).  The PACT treats molecular                attractions (van der Waals forces, dipoles, quadrupoles, hydrogen               bonding) as perturbations about the hard sphere potential.  It includes         the effects of rotational and vibrational degrees of freedom and hence          can be used for small, medium, or large molecules, including polymers.          The Restricted Primative Model allows the prediction of ion-ion                 interactions. By combining these two theories, it is possible to                predict accurately the properties of ionic organic molecules (e.g.,             amino acids, alkanol amines) and ionic polymers (proteins).  Two kinds          of experiments are performed using electrolytic systems:  vapor-liquid          equilibria are measured for some systems and the other measures                 liquid-liquid distribution coefficients.
[{'FirstName': 'Marc', 'LastName': 'Donohue', 'PI_MID_INIT': 'D', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Marc D Donohue', 'EmailAddress': 'mdd@jhu.edu', 'NSF_ID': '000180045', 'StartDate': '01/01/1986', 'EndDate': None, 'RoleCode': 'Principal Investigator'}, {'FirstName': 'Theresa', 'LastName': 'Buck', 'PI_MID_INIT': 'K', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Theresa K Buck', 'EmailAddress': None, 'NSF_ID': '000325250', 'StartDate': '01/01/1986', 'EndDate': None, 'RoleCode': 'Co-Principal Investigator'}]
{'Name': 'Johns Hopkins University', 'CityName': 'BALTIMORE', 'ZipCode': '212182608', 'PhoneNumber': '4439971898', 'StreetAddress': '3400 N CHARLES ST', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Maryland', 'StateCode': 'MD', 'CONGRESSDISTRICT': '07', 'CONGRESS_DISTRICT_ORG': 'MD07', 'ORG_UEI_NUM': 'FTMTDMBR29C7', 'ORG_LGL_BUS_NAME': 'THE JOHNS HOPKINS UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
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[{'Code': '1414', 'Text': 'INTERFAC PROCESSES & THERMODYN'}, {'Code': '9110', 'Text': 'INDUSTRY/UNIV COOP RESEAR'}]
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