Acquisition of a EPR/ENDOR Spectrometer
{'Code': '03090002', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'George M. Rubottom', 'PO_EMAI': None, 'PO_PHON': None}
Electron Paramagnetic Resonance (EPR)/Electron-Nuclear Double                   Resonance (ENDOR) spectroscopy allows chemists to conduct                       extremely precise high resolution studies on materials                          containing unpaired electrons (paramagnetic compounds).  Such                   studies reveal information on molecular structure that is                       unavailable by any other technique.                                                                                                                             The Department of Chemistry at Princeton will purchase an                       EPR/ENDOR spectrometer with the help of this award from the                     Chemistry Shared Instrumentation Program.  The areas of                         chemistry that will be enhanced by this acquisition include the                 following:                                                                                                                                                         1) Metallo-enzymes and synthetic analogs in photosynthesis                      2) Surface chemistry at semi-conductor and electrolyte                             interfaces                                                                   3) Metal-oxo and metal-peroxo intermediates in oxidative                           catalysis                                                                    4) The migration and trapping of exciton states in crystals                        by impurity ions                                                             5) Determination of the nuclear moments of unstable isotopes                       of elements                                                                  6) Mechanistic studies of alpha-ketoacid dioxygenases                           7) Determination of odd-electron intermediates in                                  organometallic reagent development                                           8) Mechanisms in organic synthesis using transition metal                          ions                                                                         9) Magnetic resonance in dense low-dimensional solids                          10) Metal centers in biology: hemes, iron-sulfur and copper                         proteins
{'FirstName': 'Thomas', 'LastName': 'Spiro', 'PI_MID_INIT': 'G', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Thomas G Spiro', 'EmailAddress': 'spiro@princeton.edu', 'NSF_ID': '000468045', 'StartDate': '08/01/1987', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Princeton University', 'CityName': 'PRINCETON', 'ZipCode': '085442001', 'PhoneNumber': '6092583090', 'StreetAddress': '1 NASSAU HALL', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'New Jersey', 'StateCode': 'NJ', 'CONGRESSDISTRICT': '12', 'CONGRESS_DISTRICT_ORG': 'NJ12', 'ORG_UEI_NUM': 'NJ1YPQXQG7U5', 'ORG_LGL_BUS_NAME': 'THE TRUSTEES OF PRINCETON UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
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{'Code': '1938', 'Text': 'Chemical Instrumentation'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1987&All=true', 'xml': '8713405.xml'}