U.S.-China Cooperative Research:  Kinetics and Mechanisms ofOxygen Atom Transfer Reactions to Metal Carbonyls
{'Code': '01090000', 'Directorate': {'Abbreviation': 'O/D', 'LongName': 'Office Of The Director'}, 'Division': {'Abbreviation': 'OISE', 'LongName': 'Office Of Internatl Science &Engineering'}}
{'SignBlockName': 'Tonya Butler', 'PO_EMAI': None, 'PO_PHON': None}
This proposal on "Kinetics and Mechanisms of Oxygen Atom                        Transfer" between Dr. Fred Basolo of Northwestern University and                Professor Qizhen Shi of Lanzhou University, China, is jointly                   sponsored by the National Science Foundation (NSF) and the                      Chinese State Educational Commission (SEDC).                                                                                                                    In this renewal of their earlier grant, the investigators                       propose to continue their research on the kinetics and                          mechanisms of O-atom transfer reactions to CO of a metal                        carbonyl, extending it to other O-atom transfer reagents and to                 attempt to understand better the properties responsible for a                   good O-atom transfer reagent.  The investigators will conduct                   experiments to understand why (CH3)3NO is such a strong                         nucleophile of the carbon atom of CO in certain metal                           carbonyls.  Since these types of reactions are often used in the                syntheses of organometallic compounds and in their use as                       homogeneous catalysts, the knowledge gained on this project                     should be of value to research chemists in industry working on                  more applied related problems.
{'FirstName': 'Fred', 'LastName': 'Basolo', 'PI_MID_INIT': None, 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Fred Basolo', 'EmailAddress': None, 'NSF_ID': '000316353', 'StartDate': '02/15/1989', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Northwestern University', 'CityName': 'EVANSTON', 'ZipCode': '602080001', 'PhoneNumber': '3125037955', 'StreetAddress': '633 CLARK ST', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Illinois', 'StateCode': 'IL', 'CONGRESSDISTRICT': '09', 'CONGRESS_DISTRICT_ORG': 'IL09', 'ORG_UEI_NUM': 'EXZVPWZBLUE8', 'ORG_LGL_BUS_NAME': 'NORTHWESTERN UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
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{'Code': '9200', 'Text': 'US CHINA COOP IN BASIC SCIENCE'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1988&All=true', 'xml': '8814696.xml'}