An Investigation of the Structure of and Chemisorption on   Model Supported Oxides by Electron Spectroscopies
{'Code': '07020000', 'Directorate': {'Abbreviation': 'ENG', 'LongName': 'Directorate For Engineering'}, 'Division': {'Abbreviation': 'CBET', 'LongName': 'Div Of Chem, Bioeng, Env, & Transp Sys'}}
{'SignBlockName': 'Farley Fisher', 'PO_EMAI': None, 'PO_PHON': None}
Thin films of vanadia or molybdena on single crystals of titania                or alumina are investigated using electron spectroscopies                       including low-energy electron diffraction (LEED), Auger                         spectroscopy, and high-resolution electron energy-loss                          spectroscopy (HREELS), as well as chemisorption and measurement                 of catalytic activity.  Ordered monolayer structures may form on                the single crystal substrates, and, if so, the influence of these               structures on catalytic activity will be observed.  Results will                be compared with and related to data on high-surface catalysts of               the same composition.                                                                                                                                           Oxides supported on oxides comprise a significant fraction of                   industrial catalysts; they are widely used for the selective                    oxidation of hydrocarbons.  Real catalysts have been studied, but               this is a proposal to study "model" catalysts - near planar                     structures similar in chemical composition to the very porous                   real catalysts.  For many techniques, model systems are much                    easier to study and give more detailed information.
{'FirstName': 'Gary', 'LastName': 'Haller', 'PI_MID_INIT': None, 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Gary Haller', 'EmailAddress': 'gary.haller@yale.edu', 'NSF_ID': '000404295', 'StartDate': '05/01/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Yale University', 'CityName': 'NEW HAVEN', 'ZipCode': '065113572', 'PhoneNumber': '2037854689', 'StreetAddress': '150 MUNSON ST', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Connecticut', 'StateCode': 'CT', 'CONGRESSDISTRICT': '03', 'CONGRESS_DISTRICT_ORG': 'CT03', 'ORG_UEI_NUM': 'FL6GV84CKN57', 'ORG_LGL_BUS_NAME': 'YALE UNIV', 'ORG_PRNT_UEI_NUM': 'FL6GV84CKN57'}
{'Name': None, 'CityName': None, 'StateCode': None, 'ZipCode': None, 'StreetAddress': None, 'CountryCode': None, 'CountryName': None, 'StateName': None, 'CountryFlag': None, 'CONGRESSDISTRICT': None, 'CONGRESS_DISTRICT_PERF': '""'}
{'Code': '1401', 'Text': 'Catalysis'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1987&All=true', 'xml': '8713926.xml'}