Synthesis and Properties of Crystalline Alkalides           and Electrides
{'Code': '03070007', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'DMR', 'LongName': 'Division Of Materials Research'}}
{'SignBlockName': 'David Nelson', 'PO_EMAI': None, 'PO_PHON': None}
Crystalline salts that contain alkali metal anions (alkalides) or               trapped electrons (electrides) and cations complexed by cyclic or               bicyclic poly-oxa or poly-aza molecules will be synthesized and                 characterized.  Emphasis will be placed on the search for                       thermally stable alkalides and electrides.  Species                             identification will be made by optical spectroscopy alkali metal                NMR spectroscopy and magnetic susceptibilities.  Structural                     studies by x-ray powder and single crystal diffraction will be                  made in order to correlate structure and properties.                            Conductivities, susceptibilities, EPR, and alkali metal NMR                     studies will be made on powders and, where feasible, on single                  crystals.  The utilization of solutions of alkalides and                        electrides in aprotic solvents such as dimethyl ether and THF to                carry out reductions of salts to elemental metals will be                       explored.
{'FirstName': 'James', 'LastName': 'Dye', 'PI_MID_INIT': 'L', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'James L Dye', 'EmailAddress': 'dye@msu.edu', 'NSF_ID': '000380210', 'StartDate': '11/15/1987', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Michigan State University', 'CityName': 'EAST LANSING', 'ZipCode': '488242600', 'PhoneNumber': '5173555040', 'StreetAddress': '426 AUDITORIUM RD RM 2', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Michigan', 'StateCode': 'MI', 'CONGRESSDISTRICT': '07', 'CONGRESS_DISTRICT_ORG': 'MI07', 'ORG_UEI_NUM': 'R28EKN92ZTZ9', 'ORG_LGL_BUS_NAME': 'MICHIGAN STATE UNIVERSITY', 'ORG_PRNT_UEI_NUM': 'VJKZC4D1JN36'}
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{'Code': '1762', 'Text': 'SOLID STATE & MATERIALS CHEMIS'}
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