Isomerizations of Isotopically Labeled Hydrocarbons
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{'SignBlockName': 'Koop Lammertsma', 'PO_EMAI': None, 'PO_PHON': None}
This grant in Organic and Macromolecular Chemistry provides                   support for the work of Professor John Baldwin, Syracuse                        University. The work focuses on how simple organic molecules                    undergo a variety of chemical reactions. These reactions are                    particularly important for a fundamental understanding of the                   dynamic behavior of such molecules, particularly at the                         interface between experiment and theory.                                          New quantitative information on basic types of thermal                        isomerization reactions will be obtained by preparing labeled                   compounds and carrying out reactions which track the labels.                    Among the systems to be investigated are stable,                                isotope-labeled versions of the simple hydrocarbons                             cyclopropane, cyclobutane, cyclopentane, cyclopentane,                          cis-1,3-pentadiene, cis,cis-1,3,5-heptatriene,                                  cycloheptatriene, and three bicyclic olefins. Reaction                          stereochemistry, kinetics, kinetic isotope effects, and                         mechanisms will be determined. Both established and novel                       techniques, including tunable diode laser and vibrational                       circular dichroism spectroscopy, will be used in these studies.
{'FirstName': 'John', 'LastName': 'Baldwin', 'PI_MID_INIT': 'E', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'John E Baldwin', 'EmailAddress': 'jbaldwin@syr.edu', 'NSF_ID': '000309471', 'StartDate': '02/01/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Syracuse University', 'CityName': 'SYRACUSE', 'ZipCode': '13244', 'PhoneNumber': '3154432807', 'StreetAddress': '900 S CROUSE AVE', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'New York', 'StateCode': 'NY', 'CONGRESSDISTRICT': '22', 'CONGRESS_DISTRICT_ORG': 'NY22', 'ORG_UEI_NUM': 'C4BXLBC11LC6', 'ORG_LGL_BUS_NAME': 'SYRACUSE UNIVERSITY', 'ORG_PRNT_UEI_NUM': None}
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{'Code': '194200', 'Text': 'UNIMOLECULAR PROCESSES'}
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