Structure and Dynamics of Small Clusters and Transient      Species
{'Code': '03090004', 'Directorate': {'Abbreviation': 'MPS', 'LongName': 'Direct For Mathematical & Physical Scien'}, 'Division': {'Abbreviation': 'CHE', 'LongName': 'Division Of Chemistry'}}
{'SignBlockName': 'Francis J. Wodarczyk', 'PO_EMAI': None, 'PO_PHON': None}
This research, part of the Experimental Physical Chemistry                      Program, is designed to observe the microwave spectra of binary                 and higher order clusters containing rare gas and small                         molecular species.  This research provides the data necessary                   to understand the chemical bonding, dynamics and structure of                   these simple molecular species.  In addition unique nozzle                      designs necessary for the simultaneous pyrolytic decompositon                   and expansion of a molecule to yield reaction intermediates                     will be developed.                                                                                                                                              Among the species to be studied are argon clusters with HF                      containing up to five argon atoms and 6 HF molecular units,                     carbon dioxide dimers and clusters containing carbon dioxide                    and hydrogen cyanide.  Nozzle designs will be developed to                      directly observe reaction intermediates which have been                         simultaneously formed by pyrolysis and cooled by supersonic                     cooling.  This expansion in a rare gas bath will both simplify                  the observed spectrum and isolate the reactive intermediate.                    Species to be studied include some silicon carbon prototypical                  molecules.
{'FirstName': 'H.', 'LastName': 'Gutowsky', 'PI_MID_INIT': 'S', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'H. S Gutowsky', 'EmailAddress': None, 'PI_PHON': None, 'NSF_ID': '000292576', 'StartDate': '11/01/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'University of Illinois at Urbana-Champaign', 'CityName': 'URBANA', 'ZipCode': '618013620', 'PhoneNumber': '2173332187', 'StreetAddress': '506 S WRIGHT ST', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Illinois', 'StateCode': 'IL', 'CONGRESSDISTRICT': '13', 'CONGRESS_DISTRICT_ORG': 'IL13', 'ORG_UEI_NUM': 'Y8CWNJRCNN91', 'ORG_LGL_BUS_NAME': 'UNIVERSITY OF ILLINOIS', 'ORG_PRNT_UEI_NUM': None}
{'Name': None, 'CityName': None, 'StateCode': None, 'ZipCode': None, 'StreetAddress': None, 'CountryCode': None, 'CountryName': None, 'StateName': None, 'CountryFlag': None, 'CONGRESSDISTRICT': None, 'CONGRESS_DISTRICT_PERF': '""'}
{'Code': '1962', 'Text': 'SPECTROSCOPY'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1988&All=true', 'xml': '8820359.xml'}