Relative Stabilities of Organic Aqueous Species in          Geochemical Processes
{'Code': '06030101', 'Directorate': {'Abbreviation': 'GEO', 'LongName': 'Directorate For Geosciences'}, 'Division': {'Abbreviation': 'EAR', 'LongName': 'Division Of Earth Sciences'}}
{'SignBlockName': 'John A. Maccini', 'PO_EMAI': None, 'PO_PHON': None}
This research project in theoretical organic geochemistry                  will address problems of critical importance to the understanding               of the chemical transformations which organic compounds undergo                 in geochemical processes.  Research objectives include                          calculation of relative stabilities and activities of organic                   aqueous species as functions of temperature, pressure, fugacities               of various gases (O2, CO2, CH4, NH3, etc.) and activities of                    inorganic aqueous species, estimation of thermodynamic data and                 equation of state parameters for organic aqueous species,                       prediction of pKa values for organic acids and bases at high                    temperatures and pressures, and estimation of activity                          coefficients for aqueous species in electrolyte solutions.  The                 focus of this research will be on the conditions of diagenesis                  with the goals of enhancing understanding of the observed                       distribution of organic aqueous species in sedimentary basin                    solutions, identifying plausible chemical reactions between these               species, organic matter (kerogen and petroleum) and minerals, and               predicting which organic aqueous species should be found in                     future extended searches of natural solutions.  This research                   requires an interdisciplinary approach combining theoretical                    equations, thermodynamic data, computer techniques, and field and               laboratory observations to achieve these goals.
{'FirstName': 'Everett', 'LastName': 'Shock', 'PI_MID_INIT': 'L', 'PI_SUFX_NAME': None, 'PI_FULL_NAME': 'Everett L Shock', 'EmailAddress': 'eshock@asu.edu', 'NSF_ID': '000456786', 'StartDate': '11/15/1988', 'EndDate': None, 'RoleCode': 'Principal Investigator'}
{'Name': 'Washington University', 'CityName': 'SAINT LOUIS', 'ZipCode': '63110', 'PhoneNumber': '3147474134', 'StreetAddress': 'ONE BROOKINGS DR', 'StreetAddress2': None, 'CountryName': 'United States', 'StateName': 'Missouri', 'StateCode': 'MO', 'CONGRESSDISTRICT': '01', 'CONGRESS_DISTRICT_ORG': 'MO01', 'ORG_UEI_NUM': 'L6NFUM28LQM5', 'ORG_LGL_BUS_NAME': 'WASHINGTON UNIVERSITY, THE', 'ORG_PRNT_UEI_NUM': None}
{'Name': None, 'CityName': None, 'StateCode': None, 'ZipCode': None, 'StreetAddress': None, 'CountryCode': None, 'CountryName': None, 'StateName': None, 'CountryFlag': None, 'CONGRESSDISTRICT': None, 'CONGRESS_DISTRICT_PERF': '""'}
{'Code': '1571', 'Text': 'SCEC'}
{'url': 'https://www.nsf.gov/awardsearch/download?DownloadFileName=1988&All=true', 'xml': '8803822.xml'}