The stereochemical result of a given reaction on a macrocycle capable of adopting several conformations can be modeled by the Curtin-Hammett scenario where two ground state conformations exist in an equilibrium, with some difference in their ground state energies.
The stereochemical result of a given reaction on a macrocycle capable of adopting several conformations can be modeled by the Curtin-Hammett scenario where two ground state conformations exist in an equilibrium. This was with some difference in their ground state energies.