Instruct: Given a question, retrieve relevant documents that can help answer the question.
Query: How hot can magnesium get before melting?
Elemental magnesium is a gray-white lightweight metal, two-thirds the density of aluminium. It tarnishes slightly when exposed to air, although, unlike the heavier alkaline earth metals, an oxygen-free environment is unnecessary for storage because magnesium is protected by a thin layer of oxide that is fairly impermeable and difficult to remove. Magnesium has the lowest melting () and the lowest boiling point of all the alkaline earth metals.
Unlike electroplated nickel, electroless nickel deposits do not have a precise melting point but rather have a melting "range". Pure nickel has a melting point of 1455 °C (2650 °F), however EN is an alloy and as the phosphorus content is increased within the film, the deposit begins to soften at lower temperatures and continues to soften until it eventually melts. The melting range decreases linearly as the phosphorus levels increase. The eutectic or lowest melting point for NiP alloys is 880 °C (1620 °F) and occurs at a deposit phosphorus content of 11% b.w. The highest melting point is for low Phosphorus deposits (less than 3%) that claim to have melting points at 1,200 °C (2,200 °F). EN has failed in some high temperature applications since it was not fully recognized that even with a relatively high melting range the deposit may still have a liquid phase at lower temperatures. Figure 3 illustrates what happens when you subject EN to temperatures above its melting point.
The boiling points of the carbon group tend to get lower with the heavier elements. Carbon, the lightest carbon group element, sublimates at 3825 °C. Silicon's boiling point is 3265 °C, germanium's is 2833 °C, tin's is 2602 °C, and lead's is 1749 °C. The melting points of the carbon group elements have roughly the same trend as their boiling points. Silicon melts at 1414 °C, germanium melts at 939 °C, tin melts at 232 °C, and lead melts at 328 °C.
The lowest temperature at which a plain carbon steel can begin to melt, its solidus, is . Steel never turns into a liquid below this temperature. Pure Iron ('Steel' with 0% Carbon) starts to melt at , and is completely liquid upon reaching . Steel with 2.1% Carbon by weight begins melting at , and is completely molten upon reaching . 'Steel' with more than 2.1% Carbon is no longer Steel, but is known as Cast iron.
Of all metals in pure form, tungsten has the highest melting point (3422 °C, 6192 °F), lowest vapor pressure (at temperatures above 1650 °C, 3000 °F), and the highest tensile strength. Although carbon remains solid at higher temperatures than tungsten, carbon sublimes at atmospheric pressure instead of melting, so it has no melting point. Tungsten has the lowest coefficient of thermal expansion of any pure metal. The low thermal expansion and high melting point and tensile strength of tungsten originate from strong covalent bonds formed between tungsten atoms by the 5d electrons.
Alloying small quantities of tungsten with steel greatly increases its toughness.
The temperature required to forge weld is typically 50 to 90 percent of the melting temperature. Iron can be welded when it surpasses the critical temperature (the A temperature) where its allotrope changes from gamma iron (face-centered cubic) to delta iron (body-centered cubic). Since the critical temperatures are affected by alloying agents like carbon, steel welds at a lower temperature-range than iron. As the carbon content in the steel increases, the welding temperature-range decreases in a linear fashion. Iron, different steels, and even cast-iron can be welded to each other, provided that their carbon content is close enough that the welding ranges overlap. Pure iron can be welded when nearly white hot; between and . Steel with a carbon content of 2.0% can be welded when orangish-yellow, between and . Common steel, between 0.2 and 0.8% carbon, is typically welded at a bright yellow heat.
Among the lanthanides, lanthanum is exceptional as it does not have any 4f electrons; indeed, the sudden contraction and lowering of energy of the 4f orbital that is important for the chemistry of the lanthanides only begins to happen at cerium. Thus it is only very weakly paramagnetic, unlike the strongly paramagnetic later lanthanides (with the exceptions of the last two, ytterbium and lutetium, where the 4f shell is completely full). Furthermore, since the melting points of the trivalent lanthanides are related to the extent of hybridisation of the 6s, 5d, and 4f electrons, lanthanum has the second-lowest (after cerium) melting point among all the lanthanides: 920 °C. The lanthanides become harder as the series is traversed: as expected, lanthanum is a soft metal. Lanthanum has a relatively high resistivity of 615 nΩm at room temperature; in comparison, the value for the good conductor aluminium is only 26.50 nΩm. Lanthanum is the least volatile of the lanthanides. Like most of the lanthanides, lanthanum has a hexagonal crystal structure at room temperature. At 310 °C, lanthanum changes to a face-centered cubic structure, and at 865 °C, it changes to a body-centered cubic structure.
During the heating phase, the weld region is heated conductively until melted, without substantial displacement of the material. Pressure is maintained either at a minimum to keep the parts and the hot plate in contact or at zero with a preset displacement. The melt surface reaches approximately 20 °C below the temperature of the hot plate. The viscosity of the melted material can be controlled through the temperature of the hot plate and the heating time. The surface of hot plate is often coated with PTFE to stop the molten plastic from sticking, which limits the hot plate temperature to 270 °C.
The temperature of the parts during this phase can be modeled by assuming a constant temperature boundary condition and using the one-dimensional heat equation:
Silicon crystallises in a giant covalent structure at standard conditions, specifically in a [[diamond cubic]] lattice. It thus has a high melting point of 1414 °C, as a lot of energy is required to break the strong covalent bonds and melt the solid. It is not known to have any allotropes at standard pressure, but several other crystal structures are known at higher pressures. The general trend is one of increasing [[coordination number]] with pressure, culminating in a [[hexagonal close-packed]] allotrope at about 40 [[gigapascal]]s known as Si–VII (the standard modification being Si–I). Silicon boils at 3265 °C: this, while high, is still lower than the temperature at which its lighter congener [[carbon]] sublimes (3642 °C) and silicon similarly has a lower [[heat of vaporisation]] than carbon, consistent with the fact that the Si–Si bond is weaker than the C–C bond.
Gschneider and Daane (1988) attribute the trend in melting point which increases across the series, (lanthanum (920 °C) – lutetium (1622 °C)) to the extent of hybridization of the 6s, 5d, and 4f orbitals. The hybridization is believed to be at its greatest for cerium, which has the lowest melting point of all, 795 °C.
The lanthanide metals are soft; their hardness increases across the series. Europium stands out, as it has the lowest density in the series at 5.24 g/cm and the largest metallic radius in the series at 208.4 pm. It can be compared to barium, which has a metallic radius of 222 pm. It is believed that the metal contains the larger Eu ion and that there are only two electrons in the conduction band. Ytterbium also has a large metallic radius, and a similar explanation is suggested.
The resistivities of the lanthanide metals are relatively high, ranging from 29 to 134 μΩ·cm. These values can be compared to a good conductor such as aluminium, which has a resistivity of 2.655 μΩ·cm.
With the exceptions of La, Yb, and Lu (which have no unpaired f electrons), the lanthanides are strongly paramagnetic, and this is reflected in their magnetic susceptibilities. Gadolinium becomes ferromagnetic at below 16 °C (Curie point). The other heavier lanthanides – terbium, dysprosium, holmium, erbium, thulium, and ytterbium – become ferromagnetic at much lower temperatures.
Silicon nitride is difficult to produce as a bulk material—it cannot be heated over 1850 °C, which is well below its melting point, due to dissociation to silicon and nitrogen. Therefore, application of conventional hot press sintering techniques is problematic. Bonding of silicon nitride powders can be achieved at lower temperatures through adding additional materials (sintering aids or "binders") which commonly induce a degree of liquid phase sintering. A cleaner alternative is to use spark plasma sintering where heating is conducted very rapidly (seconds) by passing pulses of electric current through the compacted powder. Dense silicon nitride compacts have been obtained by this techniques at temperatures 1500–1700 °C.
The alkali metals are among the most electropositive elements on the periodic table and thus tend to bond ionically to the most electronegative elements on the periodic table, the halogens (fluorine, chlorine, bromine, iodine, and astatine), forming salts known as the alkali metal halides. The reaction is very vigorous and can sometimes result in explosions. All twenty stable alkali metal halides are known; the unstable ones are not known, with the exception of sodium astatide, because of the great instability and rarity of astatine and francium. The most well-known of the twenty is certainly sodium chloride, otherwise known as common salt. All of the stable alkali metal halides have the formula MX where M is an alkali metal and X is a halogen. They are all white ionic crystalline solids that have high melting points. All the alkali metal halides are soluble in water except for lithium fluoride (LiF), which is insoluble in water due to its very high lattice enthalpy. The high lattice enthalpy of lithium fluoride is due to the small sizes of the Li and F ions, causing the electrostatic interactions between them to be strong: a similar effect occurs for magnesium fluoride, consistent with the diagonal relationship between lithium and magnesium.
At elevated temperatures all metals react with hot gases. The most common high temperature gaseous mixture is air, and oxygen is the most reactive component of air. Carbon steel is limited to ~ in air. Chromium in stainless steel reacts with oxygen to form a chromium oxide scale which reduces oxygen diffusion into the material. The minimum 10.5% chromium in stainless steels provides resistance to ~, while 26% chromium provides resistance up to ~. Type 304, the most common grade of stainless steel with 18% chromium is resistant to ~. Other gases such as sulfur dioxide, hydrogen sulfide, carbon monoxide, chlorine, etc. also attack stainless steel. Resistance to other gases is dependent on the type of gas, the temperature and the alloying content of the stainless steel.
The E. G. Budd Company of Philadelphia recognized the important metallurgical characteristics of 18/8 stainless steel (known today as SAE 304 austenitic stainless steel) and developed a spot welding process to take advantage of the oxidized layer on the surface of stainless steel. Heat treating the 18-8 stainless steel leaves the metal with non-magnetic and ductile properties. Repeatedly reheating the metal to 1000–1100 °C impairs the mechanical and chemical properties of the metal. The metal becomes susceptible to corrosion due to carbide precipitation, and loses fatigue resistance. The important factor in controlling the metal's properties is the dwell time at those temperatures. Using a controlled time element and recorder, a power supply with smooth current, and very brief high currents, a satisfactory spot weld may be produced.
Pure platinum is a lustrous, ductile, and malleable, silver-white metal. Platinum is more ductile than gold, silver or copper, thus being the most ductile of pure metals, but it is less malleable than gold. The metal has excellent resistance to corrosion, is stable at high temperatures and has stable electrical properties. Platinum does oxidize, forming PtO, at 500 °C; this oxide can be easily removed thermally. It reacts vigorously with fluorine at to form platinum tetrafluoride. It is also attacked by chlorine, bromine, iodine, and sulfur. Platinum is insoluble in hydrochloric and nitric acid, but dissolves in hot "aqua regia" (A mixture of nitric and hydrochloric acids), to form chloroplatinic acid, HPtCl.
The basic components needed for the exploding wire method are a thin conductive wire and a capacitor. The wire is typically gold, aluminum, iron or platinum, and is usually less than 0.5 mm in diameter. The capacitor has an energy consumption of about 25 kWh/kg and discharges a pulse of charge density 10 - 10 A/mm, leading to temperatures up to 100,000 K. The phenomenon occurs over a time period of only 10 - 10 seconds.
The extremely high temperatures of lava flows (1200 °C; 2200 °F) cause sea water to decompose into hydrogen and oxygen. The hydrogen combines with chloride ions dissolved in sea water, forming hydrogen chloride gas (hydrochloric acid). The rapidly rising plume of gas also carries with it fine particles of volcanic glass. The hydrochloric acid and other contaminants can precipitate out rapidly and the plume may become relatively safe a few hundred meters away, however, laze plumes should be shown a degree of respect as they can and have killed people who come in contact with them. The USGS has reported that, in 2000, two people were killed by exposure to laze clouds.
The dissolution of the different crystalline phases of calcium sulfate in water is exothermic and release heat (decrease in Enthalpy: ΔH < 0). As an immediate consequence, to proceed, the dissolution reaction needs to evacuate this heat that can be considered as a product of reaction. If the system is cooled, the dissolution equilibrium will evolve towards the right according to the Le Chatelier principle and calcium sulfate will dissolve more easily. The solubility of calcium sulfate increases thus when the temperature decreases. If the temperature of the system is raised, the reaction heat cannot dissipate and the equilibrium will regress towards the left according to Le Chatelier principle. The solubility of calcium sulfate decreases thus when temperature increases. This contra-intuitive solubility behaviour is called retrograde solubility. It is less common than for most of the salts whose dissolution reaction is endothermic (i.e., the reaction consumes heat: increase in Enthalpy: ΔH > 0) and whose solubility increases with temperature. Another calcium compound, calcium hydroxide (Ca(OH), portlandite) also exhibits a retrograde solubility for the same thermodynamic reason: because its dissolution reaction is also exothermic and releases heat. So, to dissolve higher amounts of calcium sulfate or calcium hydroxide in water, it is necessary to cool down the solution close to its freezing point instead of increasing its temperature.
The previous members of group 8 have relatively high melting points (Fe, 1538 °C; Ru, 2334 °C; Os, 3033 °C). Much like them, hassium is predicted to be a solid at room temperature, although the melting point of hassium has not been precisely calculated. Hassium should crystallize in the hexagonal close-packed structure (/ = 1.59), similarly to its lighter congener osmium. Pure metallic hassium is calculated to have a bulk modulus (resistance to uniform compression) comparable to that of diamond (442 GPa). Hassium is expected to have a bulk density of 40.7 g/cm, the highest of any of the 118 known elements and nearly twice the density of osmium, the most dense measured element, at 22.61 g/cm. This results from hassium's high atomic weight, the lanthanide and actinide contractions, and relativistic effects, although production of enough hassium to measure this quantity would be impractical, and the sample would quickly decay. Osmium is the densest element of the first 6 periods, and its heavier congener hassium is expected to be the densest element of the first 7 periods.
The ductile–brittle transition temperature (DBTT), nil ductility temperature (NDT), or nil ductility transition temperature of a metal is the temperature at which the fracture energy passes below a predetermined value (for steels typically 40 J for a standard Charpy impact test). DBTT is important since, once a material is cooled below the DBTT, it has a much greater tendency to shatter on impact instead of bending or deforming. For example, zamak 3 exhibits good ductility at room temperature but shatters when impacted at sub-zero temperatures. DBTT is a very important consideration in selecting materials that are subjected to mechanical stresses. A similar phenomenon, the glass transition temperature, occurs with glasses and polymers, although the mechanism is different in these amorphous materials.
While, the solubility of most inorganic salts (NaCl, KCl, ...) increases with temperature (endothermic dissolution reaction) , some inorganic salts such as calcium carbonate and calcium sulfate have also a retrograde solubility, i.e., their solubility decreases with temperature. In the case of calcium carbonate, it is due to the degassing of CO whose solubility decreases with temperature as it is the case for most of the gases (exothermic dissolution reaction in water). In the case of calcium sulfate, the reason is that the dissolution reaction of calcium sulfate itself is exothermic and therefore is favored when the temperature decreases (then, the dissolution heat is more easily evacuated, see Le Chatelier's principle). In other terms, the solubility of calcium carbonate and calcium sulfate increases at low temperature and decreases at high temperature, as it is also the case for calcium hydroxide (portlandite) often referred as a didactic case study to explain the reason of retrograde solubility.
Partial melting occurs where the solidus and liquidus temperatures are different. For single minerals this can happen when they exhibit solid solution, for example in olivines between iron and magnesium. In rocks made up of several different minerals, some will melt at lower temperatures than others.
Partial melting is an important process in geology with respect to the chemical differentiation of crustal rocks. On the Earth, partial melting of the mantle at mid-ocean ridges produces oceanic crust, and partial melting of the mantle and oceanic crust at subduction zones creates continental crust. In all these places partial melting is often associated with volcanism, although some melts do not make it to the surface. Partial melts are thought to play an important role in enriching old parts of the continental lithosphere in incompatible elements. Partial melts produced at depth move upwards due to the compaction of the surrounding matrix.
Aluminum can be brazed or soldered to almost any material including concrete, ceramics, or wood. Brazing and soldering can be applied manually or through an automated technique. Manual aluminum brazing can be difficult due to no observable color change before melting. Similar to other techniques, aluminum's strong oxide can prevent proper bonding. Strong acids and bases can be used to weaken the oxide or aggressive fluxes may be used. Brazing alloys for aluminum must have a relatively low melting temperature which is below aluminum's melting temperature (660 °C). In addition, aluminum alloys with high magnesium content can "poison" fluxes and depress the melting temperature which can result in a weak joint. In some cases, the aluminum parts can be clad with a different material and brazed with a more common technique and filler material. Brazed joints require overlapping of parts. The amount of overlap can greatly affect the strength of the joint.
With the aluminium and zinc containing alloys, and particularly those with the higher aluminium contents such as AZM and AZ855 difficulties arise at high speeds due to hot-shortness.
Under conditions approaching equilibrium magnesium is capable of dissolving about 12 per cent aluminium, but in cast billets 4-5 per cent usually represents the limit of solubility. Alloys containing 6 per cent Al or more therefore contain Mg4Al3, which forms a eutectic melting at 435 C. The extrusion temperature may vary from , but at the higher values speeds are restricted to about 12 ft. per minute. Continuous casting improves the homogeneity of these alloys and water cooling of the dies or taper heating of the billets further facilities their extrusion.
In 2011, a study conducted at the Georgia Institute of Technology revealed the presence of magnesium perchlorate on the planet Mars. Being a drying agent, magnesium perchlorate retains water from the atmosphere and may release it when conditions are favorable and temperature is above 250K. Because briny solutions that contain magnesium perchlorate have a lower melting point than that of pure water, their abundance on Mars could serve as evidence that liquid water may exist on its surface, where temperature and pressure conditions would ordinarily cause water to freeze.