Instruct: Given a question, retrieve passages that answer the question.
Query: When was the first graphene production technique developed?
The theory of graphene was first explored by Wallace in 1947 as a starting point for understanding the electronic properties of 3D graphite. The emergent massless Dirac equation was first pointed out by Semenoff, DiVincenzo and Mele. The earliest TEM images of few-layer graphite were published by Ruess and Vogt in 1948. An early, detailed study on few-layer graphite dates to 1962 when Boehm and colleagues reported producing monolayer flakes of reduced graphene oxide. Efforts to make thin films of graphite by mechanical exfoliation started in 1990, but nothing thinner than 50 to 100 layers was produced before 2004. Initial attempts to make atomically thin graphitic films employed exfoliation techniques similar to the drawing method. Multilayer samples down to 10 nm in thickness were obtained.
The thermal decomposition of bulk SiC was first reported in 1965 by Badami. He annealed the SiC in vacuum to around 2180 °C for an hour to obtain a graphite lattice. In 1975, Bommel et al. then achieved to form monolayer graphite on the C-face as well as the Si-face of hexagonal SiC. The experiment was carried out under UHV with a temperature of 800 °C and hints for a graphene structure could be found in LEED patterns and the change in the carbon Auger peak from a carbided character to a graphite character.
New insights in the electronic and physical properties of graphene like the Dirac nature of the charge carriers, fractional quantum Hall effect or the observation of the 2D electron gas behaviour were first measured on multilayer graphene from de Heer et al. at the Georgia Institute of Technology in 2004.
Still, the Nobel Prize in Physics ″for groundbreaking experiments regarding the two-dimensional material graphene″ in 2010 was awarded to Andre Geim and Konstantin Novoselov. An official online document of the Royal Swedish Academy of Sciences about this awarding got under fire. Walter de Heer mentions several objections about the work of Geim and Novoselov who apparently have measured on many-layer graphene, also called graphite, which has different electronic and mechanical properties.
Emtsev et al. improved the whole procedure in 2009 by annealing the SiC-samples at high temperatures over 1650 °C in an argon environment to obtain morphologically superior graphene.
Iijima's discovery of multi-walled carbon nanotubes in the insoluble material of arc-burned graphite rods in 1991 and Mintmire, Dunlap, and White's independent prediction that if single-walled carbon nanotubes could be made, then they would exhibit remarkable conducting properties helped create the initial buzz that is now associated with carbon nanotubes. Nanotube research accelerated greatly following the independent discoveries by Bethune at IBM and Iijima at NEC of "single-walled" carbon nanotubes and methods to specifically produce them by adding transition-metal catalysts to the carbon in an arc discharge. The arc discharge technique was well-known to produce the famed Buckminster fullerene on a preparative scale, and these results appeared to extend the run of accidental discoveries relating to fullerenes. The discovery of nanotubes remains a contentious issue. Many believe that Iijima's report in 1991 is of particular importance because it brought carbon nanotubes into the awareness of the scientific community as a whole.
He shared the 2008 EPS Europhysics Prize with Novoselov "for discovering and isolating a single free-standing atomic layer of carbon (graphene) and elucidating its remarkable electronic properties". In 2009 he received the Körber European Science Award. The US National Academy of Sciences honoured him with the 2010 John J. Carty Award for the Advancement of Science "for his experimental realisation and investigation of graphene, the two-dimensional form of carbon". He was awarded one of six Royal Society 2010 Anniversary Research Professorships. The Royal Society added its 2010 Hughes Medal "for his revolutionary discovery of graphene and elucidation of its remarkable properties". He was awarded honorary doctorates from Delft University of Technology, ETH Zürich, the University of Antwerp and the University of Manchester. In 2010, Geim was appointed as Knight Commander of the Order of the Netherlands Lion for his contribution to Dutch Science.
The discovery of carbon nanotubes is largely attributed to Sumio Iijima of NEC in 1991, although carbon nanotubes have been produced and observed under a variety of conditions prior to 1991. Iijima's discovery of multi-walled carbon nanotubes in the insoluble material of arc-burned graphite rods in 1991 and Mintmire, Dunlap, and White's independent prediction that if single-walled carbon nanotubes could be made, then they would exhibit remarkable conducting properties helped create the initial buzz that is now associated with carbon nanotubes. Nanotube research accelerated greatly following the independent discoveries by Bethune at IBM and Iijima at NEC of "single-walled" carbon nanotubes and methods to specifically produce them by adding transition-metal catalysts to the carbon in an arc discharge.
The chip design started in April 1970, when Federico Faggin joined Intel, and was completed under his leadership in January 1971. The first commercial sale of the fully operational 4004 occurred in March 1971 to Busicom Corp. of Japan for which it was originally designed and built as a custom chip. In mid-November of the same year, with the prophetic ad "Announcing a new era in integrated electronics", the 4004 was made commercially available to the general market. The 4004 was the first commercially available monolithic processor, fully integrated in one small chip. Such a feat of integration was made possible by the use of the then-new silicon gate technology for integrated circuits, originally developed by Faggin (with Tom Klein) at Fairchild Semiconductor in 1968, which allowed twice the number of random-logic transistors and an increase in speed by a factor of five compared to the incumbent MOS aluminum gate technology. Faggin also invented the bootstrap load with silicon gate and the “buried contact”, improving speed and circuit density compared with aluminum gate.
The first genetically modified crop plant was produced in 1982, an antibiotic-resistant tobacco plant. The first field trials of genetically engineered plants occurred in France and the USA in 1986, tobacco plants were engineered to be resistant to herbicides. In 1987 Plant Genetic Systems, founded by Marc Van Montagu and Jeff Schell, was the first company to genetically engineer insect-resistant plants by incorporating genes that produced insecticidal proteins from Bacillus thuringiensis (Bt) into tobacco.
Such an effect was first observed in a copper–cuprous-oxide interface by Chauncey Starr in the 1930s. Beginning in 2002, theoretical models were proposed to explain this effect. In 2006 the first microscopic solid-state thermal diodes were built. In April 2015 Italian researchers at CNR announced development of a working thermal diode, publishing results in Nature Nanotechnology.
The Graphics Group, which was one-third of the Computer Division of Lucasfilm, was launched in 1979 with the hiring of Catmull from NYIT, where he was in charge of the Computer Graphics Lab. He was then reunited with Smith, who also made the journey from NYIT to Lucasfilm, and was made director of The Graphics Group. At NYIT, the researchers pioneered many of the CG foundation techniques—in particular the invention of the alpha channel (by Catmull and Smith). Years later, the CGL produced a few frames of an experimental film called "The Works". After moving to Lucasfilm, the team worked on creating the precursor to RenderMan, called REYES (for "renders everything you ever saw") and developed a number of critical technologies for CG—including "particle effects" and various animation tools.
Invention of the carbon nanotube is credited to Sumio Iijima in 1991, but Figure 8 in Bacon’s paper shows a carbon nanotube derived from a whisker subjected to heavy current that caused the outer layers to explode. Iijima's invention is a seamless tube of diameter <30 nm, as opposed to Bacon's scrolled sheet.
PVC was accidentally synthesized in 1872 by German chemist Eugen Baumann. The polymer appeared as a white solid inside a flask of vinyl chloride that had been left exposed to sunlight. In the early 20th century the Russian chemist Ivan Ostromislensky and Fritz Klatte of the German chemical company Griesheim-Elektron both attempted to use PVC in commercial products, but difficulties in processing the rigid, sometimes brittle polymer thwarted their efforts. Waldo Semon and the B.F. Goodrich Company developed a method in 1926 to plasticize PVC by blending it with various additives. The result was a more flexible and more easily processed material that soon achieved widespread commercial use.
Fairchild's strategy for competing in the transistor market was to be fast and flexible. Rather than tying their research and development to lengthy 1-3 year military contracts, they financed development through Fairchild Camera. This enabled them to focus on promising ideas and develop them quickly. IBM was interested in obtaining transistors for a navigation computer for the B-70 bomber. Fairchild contracted to provide transistors to meet the specifications for IBM's core-memory driver. They developed complementary NPN and PNP transistors which could be used as a matched pair in a variety of circuit applications. Gordon Moore and David Allison worked on the NPN transistor, while Jean Hoerni developed the PNP transistor using boron diffusion. Scaling up to production of components in quantity presented major technological challenges, and Moore's NPN transistor was ready for production before Hoerni's PNP transistor. By August 1958, within 8 months of the company's creation, Fairchild was delivering Mesa transistors to IBM. Once it became available, the mesa transistor was desired for a wide variety of military applications. The speed with which it had been developed gave Fairchild a virtual monopoly on the fast-growing market for the next year. The most significant contract came from Autonetics, which was developing the navigation and control computer for the Minuteman ICBM.
In the same year, Dr. Julian W. Hill, another member of the Carothers team, began work again on attempting to produce a polyester with a molecular weight of above 4,000. His efforts were soon met with great success when he produced a synthetic polymer with a molecular weight of about 12,000. The high molecular weight allowed the melted polymer to be stretched out into strings of fiber. Thus was created the first synthetic silk, described by the chemists as a superpolyester.
In 1884 Hilaire de Chardonnet started the first artificial fiber plant based on regenerated cellulose, or viscose rayon, as a substitute for silk, but it was very flammable. In 1907 Leo Baekeland invented the first synthetic polymer, a thermosetting phenol-formaldehyde resin called Bakelite. Around the same time, Hermann Leuchs reported the synthesis of amino acid N-carboxyanhydrides and their high molecular weight products upon reaction with nucleophiles, but stopped short of referring to these as polymers, possibly due to the strong views espoused by Emil Fischer, his direct supervisor, denying the possibility of any covalent molecule exceeding 6,000 daltons. Cellophane was invented in 1908 by Jocques Brandenberger who treated sheets of viscose rayon with acid.
Dr. Joseph Cecil Patrick (August 28, 1892 – April 12, 1965) invented Thiokol, America's first synthetic rubber in the early 1920s. While seeking a formulation for automotive antifreeze, he attempted to hydrolyze ethylene dichloride with sodium polysulfide. In doing so, he produced a brown, insoluble gum that later became known as Thiokol. He solved commercial production problems by inventing the suspension polymerization process, and solved compounding problems by degrading high molecular weight polymer to a low molecular weight liquid polymer. This material is one of the principal binders for rocket propellant.
The first genetically modified crop, an antibiotic-resistant tobacco plant, was produced in 1982. China was the first country to commercialize transgenic plants, introducing a virus-resistant tobacco in 1992. In 1994 Calgene attained approval to commercially release the Flavr Savr tomato, the first genetically modified food. Also in 1994, the European Union approved tobacco engineered to be resistant to the herbicide bromoxynil, making it the first genetically engineered crop commercialised in Europe. An insect resistant Potato was approved for release in the US in 1995, and by 1996 approval had been granted to commercially grow 8 transgenic crops and one flower crop (carnation) in 6 countries plus the EU.
In July 1954, the Cabinet decided to develop the hydrogen bomb. The United Kingdom Atomic Energy Authority Atomic Weapons Research Establishment at Aldermaston produced three designs: Orange Herald, a large boosted fission weapon; Green Bamboo, an interim thermonuclear design; and Green Granite, a true thermonuclear weapon. The first test series consisted of three tests in May and June 1957. In the first, Grapple 1, a version of Green Granite known as Short Granite was dropped from a Vickers Valiant bomber flown by Wing Commander Kenneth Hubbard. The bomb's yield was estimated at , far below its designed capability. Despite its failure, the test was hailed as a successful thermonuclear explosion, and the government did not confirm or deny reports that the UK had become a third thermonuclear power. The second test was Grapple 2, of Orange Herald. Its yield made it technically a megaton weapon. It was the largest ever achieved by a single stage device. Grapple 3 tested Purple Granite, a Short Granite with some fixes. Its yield was a very disappointing .
Swiss electrical engineer George de Mestral invented his first touch fastener when, in 1941, he went for a walk in the woods and wondered why Burdock seeds clung to his coat and dog. He discovered it could be turned into something useful. He patented it in 1955 and subsequently refined and developed its practical manufacture until its commercial introduction in the late 1950s.
On December 29, 2011, chemists at Harvard University reported the creation of an artificial cell membrane.
The carbon microphone was independently developed around 1878 by David Edward Hughes in England and Emile Berliner and Thomas Edison in the US. Although Edison was awarded the first patent in mid-1877, Hughes had demonstrated his working device in front of many witnesses some years earlier, and most historians credit him with its invention.
In August 1961, at the International Congress of Biochemistry in Moscow, Nirenberg presented his paper. The experimentation with synthetic RNA in a cell-free system was a key technical innovation. In 1961, when they announced their methods for decoding the relationship of mRNA to amino acids, there was still a lot of experimentation required before the entire code was deciphered. The scientists had to determine which bases made up each codon, then determine the sequence of bases in the codons. This proved to be a tremendous amount of work.
Producing graphene via intercalation splits graphite into single layer graphene by inserting guest molecules/ions between the graphite layers. Graphite was first intercalated in 1841 using a strong oxidizing or reducing agent that damaged the material's desirable properties. Kovtyukhova developed a widely used oxidative intercalation method in 1999. In 2014, she was able to achieve intercalation using non-oxidizing Brønsted acids (phosphoric, sulfuric, dichloroacetic and alkylsulfonic acids), but without oxidizing agents. The new method has yet to achieve output sufficient for commercialization.
One of the first patents pertaining to the production of graphene was filed in October 2002 and granted in 2006. Two years later, in 2004 Geim and Novoselov extracted single-atom-thick crystallites from bulk graphite and transferred them onto thin silicon dioxide () on a silicon wafer, which electrically isolated the graphene. The cleavage technique led directly to the first observation of the anomalous quantum Hall effect in graphene, which provided direct evidence of graphene's theoretically predicted Berry's phase of massless Dirac fermions. The effect was reported by Geim's group and by Kim and Zhang, whose papers appeared in "Nature" in 2005. Geim and Novoselov received awards for their pioneering research on graphene, notably the 2010 Nobel Prize in Physics.
One of the first patents pertaining to the production of graphene was filed in October 2002 and granted in 2006. It detailed one of the first large scale graphene production processes. Two years later, in 2004 Geim and Novoselov extracted single-atom-thick crystallites from bulk graphite. They pulled graphene layers from graphite and transferred them onto thin silicon dioxide () on a silicon wafer in a process called either micromechanical cleavage or the Scotch tape technique. The electrically isolated the graphene and weakly interacted with it, providing nearly charge-neutral graphene layers. The silicon beneath the could be used as a "back gate" electrode to vary the charge density in the graphene over a wide range. , filed in 2002, describes how to process expanded graphite to achieve a graphite thickness of one hundred-thousandth of an inch (0.25 nm). The key to success was high-throughput visual recognition of graphene on a properly chosen substrate that provides a small but noticeable optical contrast.
Commercialization of graphene proceeded rapidly once commercial scale production was demonstrated. In 2014 two North East England commercial manufacturers, Applied Graphene Materials and Thomas Swan Limited (with Trinity College, Dublin researchers), began manufacturing. In East Anglia Cambridge Nanosystems operates a graphene powder production facility. By 2017, 13 years after creation of the first laboratory graphene electronic device, an integrated graphene electronics chip was produced commercially and marketed to pharmaceutical researchers by Nanomedical Diagnostics in San Diego.