Instruct: Given a question, retrieve passages that can help answer the question.
Query: Who first identified oxygen?
Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele, in Uppsala, in 1773 or earlier, and Joseph Priestley in Wiltshire, in 1774. Priority is often given for Priestley because his work was published first. Priestley, however, called oxygen "dephlogisticated air", and did not recognize it as a chemical element. The name "oxygen" was coined in 1777 by Antoine Lavoisier, who first recognized oxygen as a chemical element and correctly characterized the role it plays in combustion.
The amount of oxygen in the atmosphere has fluctuated over the last 600 million years, reaching a peak of about 30% around 280 million years ago, significantly higher than today's 21%. Two main processes govern changes in the atmosphere: Plants use carbon dioxide from the atmosphere, releasing oxygen. Breakdown of pyrite and volcanic eruptions release sulfur into the atmosphere, which oxidizes and hence reduces the amount of oxygen in the atmosphere. However, volcanic eruptions also release carbon dioxide, which plants can convert to oxygen. The exact cause of the variation of the amount of oxygen in the atmosphere is not known. Periods with much oxygen in the atmosphere are associated with rapid development of animals. Today's atmosphere contains 21% oxygen, which is great enough for this rapid development of animals.
Oganesson is a synthetic chemical element with symbol Og and atomic number 118. It was first synthesized in 2002 at the Joint Institute for Nuclear Research (JINR) in Dubna, near Moscow in Russia, by a joint team of Russian and American scientists. In December 2015, it was recognized as one of four new elements by the Joint Working Party of the international scientific bodies IUPAC and IUPAP. It was formally named on 28 November 2016. The name is in line with the tradition of honoring a scientist, in this case the nuclear physicist Yuri Oganessian, who has played a leading role in the discovery of the heaviest elements in the periodic table. It is one of only two elements named after a person who was alive at the time of naming, the other being seaborgium; it is also the only element whose namesake is alive today.
The common allotrope of elemental oxygen on Earth, , is generally known as oxygen, but may be called "dioxygen", "diatomic oxygen", "molecular oxygen", or "oxygen gas" to distinguish it from the element itself and from the triatomic allotrope "ozone," . As a major component (about 21% by volume) of Earth's atmosphere, elemental oxygen is most commonly encountered in the diatomic form. Aerobic organisms utilize atmospheric dioxygen as the terminal oxidant in cellular respiration. The ground state of dioxygen is known as triplet oxygen, O, because it has two unpaired electrons. The first excited state, singlet oxygen, ""O has no unpaired electrons and is metastable.
Dmitri Mendeleev published a periodic table of the chemical elements in 1869 based on properties that appeared with some regularity as he laid out the elements from lightest to heaviest. When Mendeleev proposed his periodic table, he noted gaps in the table and predicted that as-then-unknown elements existed with properties appropriate to fill those gaps. He named them eka-boron, eka-aluminium and eka-silicon with atomic masses 44, 68 and 72 respectively.
An important breakthrough in making sense of the list of known chemical elements (as well as in understanding the internal structure of atoms) was Dmitri Mendeleev's development of the first modern periodic table, or the periodic classification of the elements. Mendeleev, a Russian chemist, felt that there was some type of order to the elements and he spent more than thirteen years of his life collecting data and assembling the concept, initially with the idea of resolving some of the disorder in the field for his students. Mendeleev found that, when all the known chemical elements were arranged in order of increasing atomic weight, the resulting table displayed a recurring pattern, or periodicity, of properties within groups of elements. Mendeleev's law allowed him to build up a systematic periodic table of all the 66 elements then known based on atomic mass, which he published in "Principles of Chemistry" in 1869. His first Periodic Table was compiled on the basis of arranging the elements in ascending order of atomic weight and grouping them by similarity of properties.
The amount of oxygen in the atmosphere has fluctuated over the last 600 million years, reaching a peak of 35% during the Carboniferous period, significantly higher than today's 21%. Two main processes govern changes in the atmosphere: plants use carbon dioxide from the atmosphere, releasing oxygen and the breakdown of pyrite and volcanic eruptions release sulfur into the atmosphere, which oxidizes and hence reduces the amount of oxygen in the atmosphere. However, volcanic eruptions also release carbon dioxide, which plants can convert to oxygen. The exact cause of the variation of the amount of oxygen in the atmosphere is not known. Periods with much oxygen in the atmosphere are associated with rapid development of animals. Today's atmosphere contains 21% oxygen, which is high enough for rapid development of animals.The climate of the late Precambrian showed some major glaciation events spreading over much of the earth. At this time the continents were bunched up in the Rodinia supercontinent. Massive deposits of tillites and anomalous isotopic signatures are found, which gave rise to the Snowball Earth hypothesis. As the Proterozoic Eon drew to a close, the Earth started to warm up. By the dawn of the Cambrian and the Phanerozoic, life forms were abundant in the Cambrian explosion with average global temperatures of about 22 °C.
Hydrogen is found in the first group and first period in the periodic table, i.e. it is the first element on the periodic table, making it the lightest element. Since hydrogen gas is so light, it rises in the atmosphere and is therefore rarely found in its pure form, H. In a flame of pure hydrogen gas, burning in air, the hydrogen (H) reacts with oxygen (O) to form water (HO) and releases energy.
In 1869, Dmitri Mendeleev published a periodic table of all known elements (he predicted several new elements to complete the table, and corrected some atomic weights). A few months later, Meyer published a revised and expanded version of his 1864 table independently, which was similar to that published by Mendeleev (Meyer had been sent a copy of Mendeleev's table earlier; Mendeleev had sent it to many well-known chemists of his day) and a paper showing graphically the periodicity of the elements as a function of atomic weight. Meyer, as well as other chemists, was doubtful about Mendeleev's periodic law, and he criticized Mendeleev for "changing existing elements' atomic weights, only regarding possibility of periodical law in its structure". However, Mendeleev's work received significant support, when the new elements were found as predicted and atomic weights accordingly.
Three of the chalcogens (sulfur, selenium, and tellurium) were part of the discovery of periodicity, as they are among a series of triads of elements in the same group that were noted by Johann Wolfgang Döbereiner as having similar properties. Around 1865 John Newlands produced a series of papers where he listed the elements in order of increasing atomic weight and similar physical and chemical properties that recurred at intervals of eight; he likened such periodicity to the octaves of music. His version included a "group b" consisting of oxygen, sulfur, selenium, tellurium, and osmium.
At first the periodic system did not raise interest among chemists. However, with the discovery of the predicted elements, notably gallium in 1875, scandium in 1879, and germanium in 1886, it began to win wide acceptance. The subsequent proof of many of his predictions within his lifetime brought fame to Mendeleev as the founder of the periodic law. This organization surpassed earlier attempts at classification by Alexandre-Émile Béguyer de Chancourtois, who published the telluric helix, an early, three-dimensional version of the periodic table of the elements in 1862, John Newlands, who proposed the law of octaves (a precursor to the periodic law) in 1864, and Lothar Meyer, who developed an early version of the periodic table with 28 elements organized by valence in 1864. Mendeleev's table did not include any of the noble gases, however, which had not yet been discovered. Gradually the periodic law and table became the framework for a great part of chemical theory. By the time Mendeleev died in 1907, he enjoyed international recognition and had received distinctions and awards from many countries.
Although precursors to this table exist, its invention is generally credited to Russian chemist Dmitri Mendeleev in 1869. Mendeleev invented the table to illustrate recurring ("periodic") trends in the properties of the elements. The layout of the table has been refined and extended over time, as new elements have been discovered, and new theoretical models have been developed to explain chemical behavior.
The organization of the periodic table can be used to derive relationships between the various element properties, and also to predict chemical properties and behaviours of undiscovered or newly synthesized elements. Russian chemist Dmitri Mendeleev published the first recognizable periodic table in 1869, developed mainly to illustrate periodic trends of the then-known elements. He also predicted some properties of unidentified elements that were expected to fill gaps within the table. Most of his forecasts proved to be correct. Mendeleev's idea has been slowly expanded and refined with the discovery or synthesis of further new elements and the development of new theoretical models to explain chemical behaviour. The modern periodic table now provides a useful framework for analyzing chemical reactions, and continues to be widely used in chemistry, nuclear physics and other sciences.
Russian chemistry professor Dmitri Mendeleev and German chemist Julius Lothar Meyer independently published their periodic tables in 1869 and 1870, respectively. Mendeleev's table was his first published version; that of Meyer was an expanded version of his (Meyer's) table of 1864. They both constructed their tables by listing the elements in rows or columns in order of atomic weight and starting a new row or column when the characteristics of the elements began to repeat.
In 1761, Russian polymath Mikhail Lomonosov observed an arc of light surrounding the part of Venus off the Sun's disc at the beginning of the egress phase of the transit and concluded that Venus has an atmosphere. In 1940, Rupert Wildt calculated that the amount of CO in the Venusian atmosphere would raise surface temperature above the boiling point for water. This was confirmed when Mariner 2 made radiometer measurements of the temperature in 1962. In 1967, Venera 4 confirmed that the atmosphere consisted primarily of carbon dioxide.
In 1751, the Swedish mineralogist Axel Fredrik Cronstedt discovered a heavy mineral from the mine at Bastnäs, later named cerite. Thirty years later, the fifteen-year-old Vilhelm Hisinger, from the family owning the mine, sent a sample of it to Carl Scheele, who did not find any new elements within. In 1803, after Hisinger had become an ironmaster, he returned to the mineral with Jöns Jacob Berzelius and isolated a new oxide which they named "ceria" after the dwarf planet Ceres, which had been discovered two years earlier. Ceria was simultaneously independently isolated in Germany by Martin Heinrich Klaproth. Between 1839 and 1843, ceria was shown to be a mixture of oxides by the Swedish surgeon and chemist Carl Gustaf Mosander, who lived in the same house as Berzelius: he separated out two other oxides which he named "lanthana" and "didymia". He partially decomposed a sample of cerium nitrate by roasting it in air and then treating the resulting oxide with dilute nitric acid. Since lanthanum's properties differed only slightly from those of cerium, and occurred along with it in its salts, he named it from the Ancient Greek "λανθάνειν" [lanthanein] (lit. "to lie hidden"). Relatively pure lanthanum metal was first isolated in 1923.
Les Frères Robert were two French brothers. Anne-Jean Robert (1758–1820) and Nicolas-Louis Robert (1760–1820) were the engineers who built the world's first hydrogen balloon for professor Jacques Charles, which flew from central Paris on August 27, 1783. They went on to build the world's first manned hydrogen balloon, and on 1 December 1783 Nicolas-Louis accompanied Jacques Charles on a 2-hour, 5-minute flight. Their barometer and thermometer made it the first balloon flight to provide meteorological measurements of the atmosphere above the Earth's surface.
Early airships used hydrogen as their lifting gas, which is the lightest available. Typically, hydrogen was generated during the filling process, by reacting dilute sulphuric acid with metal filings. The first hydrogen balloon in 1783 used iron filings, while the British Nulli Secundus of 1907 used zinc.
Oganesson has the highest atomic number and highest atomic mass of all known elements. The radioactive oganesson atom is very unstable, and since 2005, only five (possibly six) atoms of the nuclide Og have been detected. Although this allowed very little experimental characterization of its properties and possible compounds, theoretical calculations have resulted in many predictions, including some surprising ones. For example, although oganesson is a member of group 18 – the first synthetic element to be so – it may be significantly reactive, unlike all the other elements of that group (the noble gases). It was formerly thought to be a gas under normal conditions but is now predicted to be a solid due to relativistic effects. On the periodic table of the elements it is a p-block element and the last one of the 7th period.
The name "hassium" was proposed by Peter Armbruster and his colleagues, the officially recognised German discoverers, in September 1992. It is derived from the Latin name "Hassia" for the German state of Hesse where the institute is located. In 1994, IUPAC Commission on Nomenclature of Inorganic Chemistry recommended that element 108 be named "hahnium" (Hn) after the German physicist Otto Hahn so that elements named after Hahn and Lise Meitner (meitnerium) would be next to each other, honoring their joint discovery of nuclear fission. This was because they felt that Hesse did not merit an element being named after it. GSI protested saying that this contradicted the long-standing convention to give the discoverer the right to suggest a name; the American Chemical Society supported the GSI. IUPAC relented and the name "hassium" (Hs) was adopted internationally in 1997.
Wilhelm Röntgen discovered and named X-rays. After experimenting with high voltages applied to an evacuated tube on 8 November 1895, he noticed a fluorescence on a nearby plate of coated glass. In one month, he discovered X-rays' main properties.
At the University of Sheffield, Krebs and William Johnson investigated cellular respiration by which oxygen was consumed to produce energy from the breakdown of glucose. Krebs had earlier suggested to Warburg while they worked together in Germany that by using a manometer it could be possible to detect the oxygen consumption and identify the chemical reaction in glucose metabolism. Warburg had flatly rejected the idea. In Sheffield Krebs vigorously worked to identify a possible chemical reaction and came up with numerous hypothetical pathways. Using the manometer he tested those hypotheses one by one. One hypothesis involving succinate, fumarate, and malate proved to be useful because all these molecules increased oxygen consumption in the pigeon breast muscle. In 1937 German biochemists Franz Koop and Carl Martinus had demonstrated a series of reactions using citrate that produced oxaloacetate. Krebs realised that these molecules could be the missing intermediates for such reaction. After four months of experimental works to fill in the gaps, Krebs and Johnson succeeded in establishing the sequence of the chemical cycle, which they called the "citric acid cycle". It is also known as the "Krebs cycle" or "tricarboxylic acid (TCA) cycle".
Neon was discovered in 1898 by the British chemists Sir William Ramsay (1852–1916) and Morris W. Travers (1872–1961) in London. Neon was discovered when Ramsay chilled a sample of air until it became a liquid, then warmed the liquid and captured the gases as they boiled off. The gases nitrogen, oxygen, and argon had been identified, but the remaining gases were isolated in roughly their order of abundance, in a six-week period beginning at the end of May 1898. First to be identified was krypton. The next, after krypton had been removed, was a gas which gave a brilliant red light under spectroscopic discharge. This gas, identified in June, was named "neon", the Greek analogue of the Latin "novum" ('new') suggested by Ramsay's son. The characteristic brilliant red-orange color emitted by gaseous neon when excited electrically was noted immediately. Travers later wrote: "the blaze of crimson light from the tube told its own story and was a sight to dwell upon and never forget."
The element iodine was discovered by French chemist Bernard Courtois in 1811. Courtois gave samples to his friends, Charles Bernard Desormes (1777–1862) and Nicolas Clément (1779–1841), to continue research. He also gave some of the substance to Gay-Lussac and to physicist André-Marie Ampère. On December 6, 1813, Gay-Lussac announced that the new substance was either an element or a compound of oxygen. It was Gay-Lussac who suggested the name ""iode"", from the Greek word ιώδες (iodes) for violet (because of the color of iodine vapor). Ampère had given some of his sample to Humphry Davy. Davy did some experiments on the substance and noted its similarity to chlorine. Davy sent a letter dated December 10 to the Royal Society of London stating that he had identified a new element. Arguments erupted between Davy and Gay-Lussac over who identified iodine first, but both scientists acknowledged Courtois as the first to isolate the element.
Priestley assembled his oxygen paper and several others into a second volume of "Experiments and Observations on Air", published in 1776. He did not emphasise his discovery of "dephlogisticated air" (leaving it to Part III of the volume) but instead argued in the preface how important such discoveries were to rational religion. His paper narrated the discovery chronologically, relating the long delays between experiments and his initial puzzlements; thus, it is difficult to determine when exactly Priestley "discovered" oxygen. Such dating is significant as both Lavoisier and Swedish pharmacist Carl Wilhelm Scheele have strong claims to the discovery of oxygen as well, Scheele having been the first to isolate the gas (although he published after Priestley) and Lavoisier having been the first to describe it as purified "air itself entire without alteration" (that is, the first to explain oxygen without phlogiston theory).