Instruct: Given a question, retrieve documents that can help answer the question.
Query: Who wrote the laws of thermodynamics?
The second law of thermodynamics may be expressed in many specific ways, the most prominent classical statements being the statement by Rudolf Clausius (1854), the statement by Lord Kelvin (1851), and the statement in axiomatic thermodynamics by Constantin Carathéodory (1909). These statements cast the law in general physical terms citing the impossibility of certain processes. The Clausius and the Kelvin statements have been shown to be equivalent.
Engineers such as John Smeaton, Peter Ewart, , Gustave-Adolphe Hirn and Marc Seguin recognized that conservation of momentum alone was not adequate for practical calculation and made use of Leibniz's principle. The principle was also championed by some chemists such as William Hyde Wollaston. Academics such as John Playfair were quick to point out that kinetic energy is clearly not conserved. This is obvious to a modern analysis based on the second law of thermodynamics, but in the 18th and 19th centuries the fate of the lost energy was still unknown.
Before there was the thermometer, there was the earlier and closely related thermoscope, best described as a thermometer without a temperature scale. A thermoscope only showed the differences in temperatures, for example, it could show something was getting hotter. However, the thermoscope did not measure all the data that a thermometer could, for example an exact temperature in degrees. What can be considered the first modern thermometer, the mercury thermometer with a standardized scale, was invented by German-Dutch scientist Daniel Gabriel Fahrenheit (who had settled in Amsterdam in 1701) in 1714. Fahrenheit invented the first truly accurate thermometer using mercury instead of alcohol and water mixtures. He began constructing his own thermometers in 1714, and it was in these that he used mercury for the first time.
The thermoscope, or Galileo thermometer, was constructed by Galileo Galilei in 1607. In 1643, Evangelista Torricelli invented the mercury barometer. Blaise Pascal (in 1648) rediscovered that atmospheric pressure decreases with height, and deduced that there is a vacuum above the atmosphere.
Invented in 1892 by Sir James Dewar, a scientist at Oxford University, the "vacuum flask" was not manufactured for commercial use until 1904, when two German glass blowers, "Reinhold Burger" and "Albert Aschenbrenner," formed Thermos GmbH. They held a contest to name the "vacuum flask" and a resident of Munich submitted "Thermos," which came from the Greek word "therme," meaning "heat."
A thermostat is a device for regulating the temperature of a system so that the system's temperature is maintained near a desired setpoint temperature. The thermostat does this by switching heating or cooling devices on or off, or regulating the flow of a heat transfer fluid as needed, to maintain the correct temperature. The thermostat was invented in 1883 by Warren S. Johnson.
Modern thermostat control was developed in the 1830s by Andrew Ure (1778–1857), a Scottish chemist, who invented the bi-metallic thermostat. The textile mills of the time needed a constant and steady temperature to operate optimally, so to achieve this Ure designed the bimetallic thermostat, which would bend as one of the metals expanded in response to the increased temperature and cut off the energy supply.
The mercury-in-glass or mercury thermometer was invented by physicist Daniel Gabriel Fahrenheit in Amsterdam (1714). It consists of a bulb containing mercury attached to a glass tube of narrow diameter; the volume of mercury in the tube is much less than the volume in the bulb. The volume of mercury changes slightly with temperature; the small change in volume drives the narrow mercury column a relatively long way up the tube. The space above the mercury may be filled with nitrogen gas or it may be at less than atmospheric pressure, a partial vacuum.
For some types of thermometer the relationship between the property observed (e.g., length of a mercury column) and temperature, is close to linear, so for most purposes a linear scale is sufficient, without point-by-point calibration. For others a calibration curve or equation is required. The mercury thermometer, invented before the thermodynamic temperature was understood, originally "defined" the temperature scale; its linearity made readings correlate well with true temperature, i.e. the "mercury" temperature scale was a close fit to the true scale.
Although they were written in several different cities and kingdoms, these early laws have a number of formulae in common. Most contain both an epilogue and a prologue, which usually explain the purpose of composing the laws, invoke divine authority, and command the reader to abide by them. They are always imposed or 'enacted' in the name of a ruler, be it a prince or king, and show no sign of being the result of legislative bodies.
In 1918 it was proved that the law of conservation of energy is the direct mathematical consequence of the translational symmetry of the quantity conjugate to energy, namely time. That is, energy is conserved because the laws of physics do not distinguish between different moments of time (see Noether's theorem).
The syllogistic logic developed by Aristotle predominated in the West until the mid-19th century, when interest in the foundations of mathematics stimulated the development of symbolic logic (now called mathematical logic). In 1854, George Boole published "An Investigation of the Laws of Thought on Which are Founded the Mathematical Theories of Logic and Probabilities", introducing symbolic logic and the principles of what is now known as Boolean logic. In 1879, Gottlob Frege published "Begriffsschrift", which inaugurated modern logic with the invention of quantifier notation. From 1910 to 1913, Alfred North Whitehead and Bertrand Russell published "Principia Mathematica" on the foundations of mathematics, attempting to derive mathematical truths from axioms and inference rules in symbolic logic. In 1931, Gödel raised serious problems with the foundationalist program and logic ceased to focus on such issues.
At first the periodic system did not raise interest among chemists. However, with the discovery of the predicted elements, notably gallium in 1875, scandium in 1879, and germanium in 1886, it began to win wide acceptance. The subsequent proof of many of his predictions within his lifetime brought fame to Mendeleev as the founder of the periodic law. This organization surpassed earlier attempts at classification by Alexandre-Émile Béguyer de Chancourtois, who published the telluric helix, an early, three-dimensional version of the periodic table of the elements in 1862, John Newlands, who proposed the law of octaves (a precursor to the periodic law) in 1864, and Lothar Meyer, who developed an early version of the periodic table with 28 elements organized by valence in 1864. Mendeleev's table did not include any of the noble gases, however, which had not yet been discovered. Gradually the periodic law and table became the framework for a great part of chemical theory. By the time Mendeleev died in 1907, he enjoyed international recognition and had received distinctions and awards from many countries.
Notable German physicists before the 20th century include Hermann von Helmholtz, Joseph von Fraunhofer and Gabriel Daniel Fahrenheit, among others. Albert Einstein introduced the special relativity and general relativity theories for light and gravity in 1905 and 1915 respectively. Along with Max Planck, he was instrumental in the introduction of quantum mechanics, in which Werner Heisenberg and Max Born later made major contributions. Wilhelm Röntgen discovered X-rays. Otto Hahn was a pioneer in the fields of radiochemistry and discovered nuclear fission, while Ferdinand Cohn and Robert Koch were founders of microbiology. Numerous mathematicians were born in Germany, including Carl Friedrich Gauss, David Hilbert, Bernhard Riemann, Gottfried Leibniz, Karl Weierstrass, Hermann Weyl, Felix Klein and Emmy Noether.
Mass and energy can be seen as two names (and two measurement units) for the same underlying, conserved physical quantity. Thus, the laws of conservation of energy and conservation of (total) mass are equivalent and both hold true. Einstein elaborated in a 1946 essay that "the principle of the conservation of mass [...] proved inadequate in the face of the special theory of relativity. It was therefore merged with the energy conservation principle—just as, about 60 years before, the principle of the conservation of mechanical energy had been combined with the principle of the conservation of heat [thermal energy]. We might say that the principle of the conservation of energy, having previously swallowed up that of the conservation of heat, now proceeded to swallow that of the conservation of mass—and holds the field alone."
The most influential publication of the Enlightenment was the "" ("Encyclopaedia"). Published between 1751 and 1772 in thirty-five volumes, it was compiled by Diderot, d'Alembert (until 1759) and a team of 150 scientists and philosophers. It helped spread the ideas of the Enlightenment across Europe and beyond. Other landmark publications were Voltaire's "Dictionnaire philosophique" ("Philosophical Dictionary"; 1764) and "Letters on the English" (1733); Rousseau's "Discourse on Inequality" (1754) and "The Social Contract" (1762); Adam Smith's "The Theory of Moral Sentiments" (1759) and "The Wealth of Nations" (1776); and Montesquieu's "The Spirit of the Laws" (1748). The ideas of the Enlightenment played a major role in inspiring the French Revolution, which began in 1789. After the Revolution, the Enlightenment was followed by the intellectual movement known as Romanticism.
Russian chemistry professor Dmitri Mendeleev and German chemist Julius Lothar Meyer independently published their periodic tables in 1869 and 1870, respectively. Mendeleev's table was his first published version; that of Meyer was an expanded version of his (Meyer's) table of 1864. They both constructed their tables by listing the elements in rows or columns in order of atomic weight and starting a new row or column when the characteristics of the elements began to repeat.
In 1750, John Michell stated that magnetic poles attract and repel in accordance with an inverse square law. Charles-Augustin de Coulomb experimentally verified this in 1785 and stated explicitly that the north and south poles cannot be separated. Building on this force between poles, Siméon Denis Poisson (1781–1840) created the first successful model of the magnetic field, which he presented in 1824. In this model, a magnetic -field is produced by 'magnetic poles' and magnetism is due to small pairs of north/south magnetic poles.
Three discoveries challenged this foundation of magnetism, though. First, in 1819, Hans Christian Ørsted discovered that an electric current generates a magnetic field encircling it. Then in 1820, André-Marie Ampère showed that parallel wires with currents attract one another if the currents are in the same direction and repel if they are in opposite directions. Finally, Jean-Baptiste Biot and Félix Savart discovered the Biot–Savart law in 1820, which correctly predicts the magnetic field around any current-carrying wire.
Gottfried Leibniz, in memoranda not published before the late 19th and early 20th centuries, invented Boolean logic. His notation was isomorphic to that of "LoF": concatenation read as conjunction, and "non-("X")" read as the complement of "X". Leibniz's pioneering role in algebraic logic was foreshadowed by Lewis (1918) and Rescher (1954). But a full appreciation of Leibniz's accomplishments had to await the work of Wolfgang Lenzen, published in the 1980s and reviewed in Lenzen (2004).
The world's first fully synthetic plastic was bakelite, invented in New York in 1907 by Leo Baekeland who coined the term 'plastics'. Many chemists have contributed to the materials science of plastics, including Nobel laureate Hermann Staudinger who has been called "the father of polymer chemistry" and Herman Mark, known as "the father of polymer physics".
The chemist Hermann Staudinger first proposed that polymers consisted of long chains of atoms held together by covalent bonds, which he called macromolecules. His work expanded the chemical understanding of polymers and was followed by an expansion of the field of polymer chemistry during which such polymeric materials as neoprene, nylon and polyester were invented. Before Staudinger, polymers were thought to be clusters of small molecules (colloids), without definite molecular weights, held together by an unknown force. Staudinger received the Nobel Prize in Chemistry in 1953. Wallace Carothers invented the first synthetic rubber called neoprene in 1931, the first polyester, and went on to invent nylon, a true silk replacement, in 1935. Paul Flory was awarded the Nobel Prize in Chemistry in 1974 for his work on polymer random coil configurations in solution in the 1950s. Stephanie Kwolek developed an aramid, or aromatic nylon named Kevlar, patented in 1966. Karl Ziegler and Giulio Natta received a Nobel Prize for their discovery of catalysts for the polymerization of alkenes. Alan J. Heeger, Alan MacDiarmid, and Hideki Shirakawa were awarded the 2000 Nobel Prize in Chemistry for the development of polyacetylene and related conductive polymers. Polyacetylene itself did not find practical applications, but organic light-emitting diodes (OLEDs) emerged as one application of conducting polymers.
These ideas may be regarded as helping to clarify the physical meaning of the usual statement of the zeroth law of thermodynamics. It is the opinion of Lieb and Yngvason (1999) that the derivation from statistical mechanics of the law of entropy increase is a goal that has so far eluded the deepest thinkers. Thus the idea remains open to consideration that the existence of heat and temperature are needed as coherent primitive concepts for thermodynamics, as expressed, for example, by Maxwell and Planck. On the other hand, Planck in 1926 clarified how the second law can be stated without reference to heat or temperature, by referring to the irreversible and universal nature of friction in natural thermodynamic processes.
According to Arnold Sommerfeld, Ralph H. Fowler invented the title 'the zeroth law of thermodynamics' when he was discussing the 1935 text of Saha and Srivastava. They write on page 1 that "every physical quantity must be measurable in numerical terms". They presume that temperature is a physical quantity and then deduce the statement "If a body A is in temperature equilibrium with two bodies B and C, then B and C themselves will be in temperature equilibrium with each other". They then in a self-standing paragraph italicize as if to state their basic postulate: ""Any of the physical properties of A which change with the application of heat may be observed and utilised for the measurement of temperature."" They do not themselves here use the term 'zeroth law of thermodynamics'. There are very many statements of these physical ideas in the physics literature long before this text, in very similar language. What was new here was just the label 'zeroth law of thermodynamics'. Fowler, with co-author Edward A. Guggenheim, wrote of the zeroth law as follows:
In 1840, Germain Hess stated a conservation law for the so-called 'heat of reaction' for chemical reactions. His law was later recognized as a consequence of the first law of thermodynamics, but Hess's statement was not explicitly concerned with the relation between energy exchanges by heat and work.
Gibbs first contributed to mathematical physics with two papers published in 1873 in the "Transactions of the Connecticut Academy of Arts and Sciences" on "Graphical Methods in the Thermodynamics of Fluids," and "Method of Geometrical Representation of the Thermodynamic Properties of Substances by means of Surfaces." His subsequent and most important publication was "On the Equilibrium of Heterogeneous Substances" (in two parts, 1876 and 1878). In this monumental, densely woven, 300-page treatise, the first law of thermodynamics, the second law of thermodynamics, the fundamental thermodynamic relation, are applied to the predication and quantification of thermodynamic reaction tendencies in any thermodynamic system in a visual, three-dimensional graphical language of Lagrangian calculus and phase transitions, among others. As stated by Henri Louis Le Chatelier, it "founded a new department of chemical science that is becoming comparable in importance to that created by Lavoisier." This work was translated into German by W. Ostwald (who styled its author the "founder of chemical energetics") in 1891 and into French by H. le Chatelier in 1899.