Instruct: Given a question, retrieve relevant documents that answer the question.
Query: Who invented the carbon nanotube?
The true identity of the discoverers of carbon nanotubes is a subject of some controversy. A 2006 editorial written by Marc Monthioux and Vladimir Kuznetsov in the journal "Carbon" described the interesting and often-misstated origin of the carbon nanotube. A large percentage of academic and popular literature attributes the discovery of hollow, nanometer-size tubes composed of graphitic carbon to Sumio Iijima of NEC in 1991. He published a paper describing his discovery which initiated a flurry of excitement and could be credited by inspiring the many scientists now studying applications of carbon nanotubes. Though Iijima has been given much of the credit for discovering carbon nanotubes, it turns out that the timeline of carbon nanotubes goes back much further than 1991.
Graphene was discovered at the University of Manchester in 2004 under Prof Sir Andre Geim and Sir Konstantin Novoselov.
At the Calico Printers' Association in Manchester in 1941, John Rex Whinfield and James Tennant Dickson discovered polyethylene terephthalate, known as PET, a common polyester compound found in plastic bottles and food, and also known as Terylene or Dacron. Cheslene and Crepes of Macclesfield discovered crimplene (the fabric that is now referred to as polyester). ICI Dyestuffs at Hexagon House, in Blackley in north Manchester, discovered Procion dyes. At the Winnington Laboratory on 27 March 1933, Eric Fawcett and Reginald Gibson discovered polythene in an ICI laboratory in Northwich, when reacting benzaldehyde with ethene at a pressure of 2,000 atmospheres; the process was improved in 1935 by Sir Michael Perrin.
The theory of graphene was first explored by Wallace in 1947 as a starting point for understanding the electronic properties of 3D graphite. The emergent massless Dirac equation was first pointed out by Semenoff, DiVincenzo and Mele. The earliest TEM images of few-layer graphite were published by Ruess and Vogt in 1948. An early, detailed study on few-layer graphite dates to 1962 when Boehm and colleagues reported producing monolayer flakes of reduced graphene oxide. Efforts to make thin films of graphite by mechanical exfoliation started in 1990, but nothing thinner than 50 to 100 layers was produced before 2004. Initial attempts to make atomically thin graphitic films employed exfoliation techniques similar to the drawing method. Multilayer samples down to 10 nm in thickness were obtained.
The chemist Hermann Staudinger first proposed that polymers consisted of long chains of atoms held together by covalent bonds, which he called macromolecules. His work expanded the chemical understanding of polymers and was followed by an expansion of the field of polymer chemistry during which such polymeric materials as neoprene, nylon and polyester were invented. Before Staudinger, polymers were thought to be clusters of small molecules (colloids), without definite molecular weights, held together by an unknown force. Staudinger received the Nobel Prize in Chemistry in 1953. Wallace Carothers invented the first synthetic rubber called neoprene in 1931, the first polyester, and went on to invent nylon, a true silk replacement, in 1935. Paul Flory was awarded the Nobel Prize in Chemistry in 1974 for his work on polymer random coil configurations in solution in the 1950s. Stephanie Kwolek developed an aramid, or aromatic nylon named Kevlar, patented in 1966. Karl Ziegler and Giulio Natta received a Nobel Prize for their discovery of catalysts for the polymerization of alkenes. Alan J. Heeger, Alan MacDiarmid, and Hideki Shirakawa were awarded the 2000 Nobel Prize in Chemistry for the development of polyacetylene and related conductive polymers. Polyacetylene itself did not find practical applications, but organic light-emitting diodes (OLEDs) emerged as one application of conducting polymers.
In 1884 Hilaire de Chardonnet started the first artificial fiber plant based on regenerated cellulose, or viscose rayon, as a substitute for silk, but it was very flammable. In 1907 Leo Baekeland invented the first synthetic polymer, a thermosetting phenol-formaldehyde resin called Bakelite. Around the same time, Hermann Leuchs reported the synthesis of amino acid N-carboxyanhydrides and their high molecular weight products upon reaction with nucleophiles, but stopped short of referring to these as polymers, possibly due to the strong views espoused by Emil Fischer, his direct supervisor, denying the possibility of any covalent molecule exceeding 6,000 daltons. Cellophane was invented in 1908 by Jocques Brandenberger who treated sheets of viscose rayon with acid.
The first microphone that enabled proper voice telephony was the (loose-contact) carbon microphone (then called transmitter). This was independently developed around 1878 by David Edward Hughes in England and Emile Berliner and Thomas Edison in the US. Although Edison was awarded the first patent in mid-1877, Hughes had demonstrated his working device in front of many witnesses some years earlier, and most historians credit him with its invention.
The transistor is the fundamental building block of modern electronic devices, and is ubiquitous in modern electronic systems. Julius Edgar Lilienfeld patented a field-effect transistor in 1926 but it was not possible to actually construct a working device at that time. The first practically implemented device was a point-contact transistor invented in 1947 by American physicists John Bardeen, Walter Brattain, and William Shockley. The transistor revolutionized the field of electronics, and paved the way for smaller and cheaper radios, calculators, and computers, among other things. The transistor is on the list of IEEE milestones in electronics, and Bardeen, Brattain, and Shockley shared the 1956 Nobel Prize in Physics for their achievement.
The first widely used solid-state negative resistance device was the tunnel diode, invented in 1957 by Japanese physicist Leo Esaki. Because they have lower parasitic capacitance than vacuum tubes due to their small junction size, diodes can function at higher frequencies, and tunnel diode oscillators proved able to produce power at microwave frequencies, above the range of ordinary vacuum tube oscillators. Its invention set off a search for other negative resistance semiconductor devices for use as microwave oscillators, resulting in the discovery of the IMPATT diode, Gunn diode, TRAPATT diode, and others. In 1969 Kurokawa derived conditions for stability in negative resistance circuits. Currently negative differential resistance diode oscillators are the most widely used sources of microwave energy, and many new negative resistance devices have been discovered in recent decades.
He shared the 2008 EPS Europhysics Prize with Novoselov "for discovering and isolating a single free-standing atomic layer of carbon (graphene) and elucidating its remarkable electronic properties". In 2009 he received the Körber European Science Award. The US National Academy of Sciences honoured him with the 2010 John J. Carty Award for the Advancement of Science "for his experimental realisation and investigation of graphene, the two-dimensional form of carbon". He was awarded one of six Royal Society 2010 Anniversary Research Professorships. The Royal Society added its 2010 Hughes Medal "for his revolutionary discovery of graphene and elucidation of its remarkable properties". He was awarded honorary doctorates from Delft University of Technology, ETH Zürich, the University of Antwerp and the University of Manchester. In 2010, Geim was appointed as Knight Commander of the Order of the Netherlands Lion for his contribution to Dutch Science.
Polyvinyl chloride (PVC) was discovered by French physicist Henri Victor Regnault, and German physicist Eugen Baumann. Klatte designed the production process, although never successfully commercialised it. Klatte is sometimes incorrectly attributed to be the discoverer or inventor of PVC.
The development of transistors in 1948 by Bell Laboratories led to major improvements to the hearing aid. The transistor was invented by John Bardeen, Walter Brattain, and William Shockley. Transistors were created to replace vacuum tubes; they were small, required less battery power and had less distortion and heat than their predecessor. These vacuum tubes were typically hot and fragile, so the transistor was the ideal replacement.The 1952 Sonotone 1010 used a transistor stage along with vacuum tubes, to extend battery life. The size of these transistors led to developments in miniature, carbon microphones. These microphones could be mounted on various items, even eyeglasses. In 1951, Raytheon manufactured the transistor and was one of the first companies to mass-produce transistors to throughout America. Raytheon realized that their hearing aid only lasted short-term and began to sell the vacuum-tube hearing aids again along with transistor hearing aids.
From November 17, 1947, to December 23, 1947, John Bardeen and Walter Brattain at AT&T's Bell Labs in Murray Hill, New Jersey of the United States performed experiments and observed that when two gold point contacts were applied to a crystal of germanium, a signal was produced with the output power greater than the input. Solid State Physics Group leader William Shockley saw the potential in this, and over the next few months worked to greatly expand the knowledge of semiconductors. The term "transistor" was coined by John R. Pierce as a contraction of the term "transresistance". According to Lillian Hoddeson and Vicki Daitch, authors of a biography of John Bardeen, Shockley had proposed that Bell Labs' first patent for a transistor should be based on the field-effect and that he be named as the inventor. Having unearthed Lilienfeld’s patents that went into obscurity years earlier, lawyers at Bell Labs advised against Shockley's proposal because the idea of a field-effect transistor that used an electric field as a "grid" was not new. Instead, what Bardeen, Brattain, and Shockley invented in 1947 was the first point-contact transistor. In acknowledgement of this accomplishment, Shockley, Bardeen, and Brattain were jointly awarded the 1956 Nobel Prize in Physics "for their researches on semiconductors and their discovery of the transistor effect".
The thermal decomposition of bulk SiC was first reported in 1965 by Badami. He annealed the SiC in vacuum to around 2180 °C for an hour to obtain a graphite lattice. In 1975, Bommel et al. then achieved to form monolayer graphite on the C-face as well as the Si-face of hexagonal SiC. The experiment was carried out under UHV with a temperature of 800 °C and hints for a graphene structure could be found in LEED patterns and the change in the carbon Auger peak from a carbided character to a graphite character.
New insights in the electronic and physical properties of graphene like the Dirac nature of the charge carriers, fractional quantum Hall effect or the observation of the 2D electron gas behaviour were first measured on multilayer graphene from de Heer et al. at the Georgia Institute of Technology in 2004.
Still, the Nobel Prize in Physics ″for groundbreaking experiments regarding the two-dimensional material graphene″ in 2010 was awarded to Andre Geim and Konstantin Novoselov. An official online document of the Royal Swedish Academy of Sciences about this awarding got under fire. Walter de Heer mentions several objections about the work of Geim and Novoselov who apparently have measured on many-layer graphene, also called graphite, which has different electronic and mechanical properties.
Emtsev et al. improved the whole procedure in 2009 by annealing the SiC-samples at high temperatures over 1650 °C in an argon environment to obtain morphologically superior graphene.
Venus could also be cooled by placing reflectors in the atmosphere. Reflective balloons floating in the upper atmosphere could create shade. The number and/or size of the balloons would necessarily be great. Geoffrey A. Landis has suggested that if enough floating cities were built, they could form a solar shield around the planet, and could simultaneously be used to process the atmosphere into a more desirable form, thus combining the solar shield theory and the atmospheric processing theory with a scalable technology that would immediately provide living space in the Venusian atmosphere. If made from carbon nanotubes or graphene (a sheet-like carbon allotrope), then the major structural materials can be produced using carbon dioxide gathered "in situ" from the atmosphere. The recently synthesised amorphous carbonia might prove a useful structural material if it can be quenched to Standard Temperature and Pressure (STP) conditions, perhaps in a mixture with regular silica glass. According to Birch's analysis, such colonies and materials would provide an immediate economic return from colonizing Venus, funding further terraforming efforts.
Academics working at the university include Sir Tim Berners-Lee, inventor of the World Wide Web, Wendy Hall, inventor of Microcosm (hypermedia system) a predecessor of the World Wide Web, founding director of the Web Science Trust between the University of Southampton and MIT, José Antonio Bowen, President of Goucher College and a Fellow of the Royal Society of Arts, Erich Zepler, who made leading contributions to radio receiver development, David Payne, who invented EDFA for use in fibre optics cables, Sir Barry Cunliffe, a pioneer of modern British archaeology, Ray Monk, the biographer of Ludwig Wittgenstein, Albie Sachs, former Judge of the Constitutional Court of South Africa, and Tim Holt, former President of the Royal Statistical Society and Office for National Statistics.
About 20 years later, John Ambrose Fleming (scientific adviser to the Marconi Company
and former Edison employee) realized that the Edison effect could be used as a radio detector. Fleming patented the first true thermionic diode, the Fleming valve, in Britain on November 16, 1904 (followed by in November 1905).
PVC was accidentally synthesized in 1872 by German chemist Eugen Baumann. The polymer appeared as a white solid inside a flask of vinyl chloride that had been left exposed to sunlight. In the early 20th century the Russian chemist Ivan Ostromislensky and Fritz Klatte of the German chemical company Griesheim-Elektron both attempted to use PVC in commercial products, but difficulties in processing the rigid, sometimes brittle polymer thwarted their efforts. Waldo Semon and the B.F. Goodrich Company developed a method in 1926 to plasticize PVC by blending it with various additives. The result was a more flexible and more easily processed material that soon achieved widespread commercial use.
High-quality sheets of few-layer graphene exceeding in area have been synthesized via CVD on thin nickel films using multiple techniques. First the film is exposed to argon gas at 900–1000 degrees Celsius. Methane is then mixed into the gas, and the methane's disassociated carbon is absorbed into the film. The solution is then cooled and the carbon diffuses out of the nickel to form graphene films. CVD grown graphene on Ni(111) surface forms (1 x 1) structure, i.e. the lattice constants of Ni and graphene matches and no moiré pattern is formed. There are still different possible adsorption sites for carbon atoms on nickel, at least top, hcp hollow, fcc hollow and bridge sites have been reported [17].
The vacuum flask was designed and invented by Scottish scientist Sir James Dewar in 1892 as a result of his research in the field of cryogenics and is sometimes called a Dewar flask in his honour. While performing experiments in determining the specific heat of the element palladium, Dewar made a brass chamber that he enclosed in another chamber to keep the palladium at its desired temperature. He evacuated the air between the two chambers, creating a partial vacuum to keep the temperature of the contents stable. Through the need for this insulated container James Dewar created the vacuum flask, which became a significant tool for chemical experiments and also became a common household item. The flask was later developed using new materials such as glass and aluminum; however, Dewar refused to patent his invention.
One of the first patents pertaining to the production of graphene was filed in October 2002 and granted in 2006. It detailed one of the first large scale graphene production processes. Two years later, in 2004 Geim and Novoselov extracted single-atom-thick crystallites from bulk graphite. They pulled graphene layers from graphite and transferred them onto thin silicon dioxide () on a silicon wafer in a process called either micromechanical cleavage or the Scotch tape technique. The electrically isolated the graphene and weakly interacted with it, providing nearly charge-neutral graphene layers. The silicon beneath the could be used as a "back gate" electrode to vary the charge density in the graphene over a wide range. , filed in 2002, describes how to process expanded graphite to achieve a graphite thickness of one hundred-thousandth of an inch (0.25 nm). The key to success was high-throughput visual recognition of graphene on a properly chosen substrate that provides a small but noticeable optical contrast.
To the extent that cultural contributions comprise invention, innovation, and progress, Springfield has been, historically, one of the nation's most innovative cities. In 1819, inventor Thomas Blanchard invented the lathe in Springfield, which would catalyze manufacturing developments now known the world over as interchangeable parts and the assembly line. In 1825, Blanchard also built the first American car, a "horseless carriage," which was powered by steam. In 1844, inventor Charles Goodyear perfected and patented his process for making vulcanized rubber in Springfield - as of 2011, as it has been for many years previous, Goodyear's name is known the world over for rubber production. In 1868, inventor Margaret E. Knight invented a machine for folding and gluing flat-bottomed paper bags.
First studies on oxidation of carbon nanotubes involved a gas-phase reactions with nitric acid vapor in air, which indiscriminately functionalized the carbon nanotubes with carboxylic, carbonyl or hydroxyl groups. In liquid-phase reactions, carbon nanotubes were treated with oxidizing solutions of nitric acid or a combination of nitric and sulfuric acid to the same effect. However, overoxidation may occur causing the carbon nanotube to break up into fragments, which are known as carbonaceous fragments. Xing et al. revealed sonication assisted oxidation, with sulfuric and nitric acid, of carbon nanotubes and produced carbonyl and carboxyl groups. After the oxidation reaction in acidic solution, treatment with hydrogen peroxide limited the damage on the carbon nanotube network. Single-walled carbon nanotubes can be shortened in a scalable manner using oleum (100% HSO with 3% SO) and nitric acid. The nitric acid cuts carbon nanotubes while the oleum creates a channel.
Single-walled carbon nanotubes can also be synthesized by a thermal plasma method, first invented in 2000 at INRS (Institut national de la recherche scientifique) in Varennes, Canada, by Olivier Smiljanic. In this method, the aim is to reproduce the conditions prevailing in the arc discharge and laser ablation approaches, but a carbon-containing gas is used instead of graphite vapors to supply the necessary carbon. Doing so, the growth of SWNT is more efficient (decomposing the gas can be 10 times less energy-consuming than graphite vaporization). The process is also continuous and low cost. A gaseous mixture of argon, ethylene and ferrocene is introduced into a microwave plasma torch, where it is atomized by the atmospheric pressure plasma, which has the form of an intense 'flame'. The fumes created by the flame contain SWNT, metallic and carbon nanoparticles and amorphous carbon.
This process was developed by Dr. Richard Smalley and co-workers at Rice University, who at the time of the discovery of carbon nanotubes, were blasting metals with a laser to produce various metal molecules. When they heard of the existence of nanotubes they replaced the metals with graphite to create multi-walled carbon nanotubes. Later that year the team used a composite of graphite and metal catalyst particles (the best yield was from a cobalt and nickel mixture) to synthesize single-walled carbon nanotubes.
The interaction between carbon nanotubes and biomolecules has been widely studied because of their potential to be used in
biological applications. The modification of the carbon nanotubes with proteins, carbohydrates, and nucleic acids are built with the bottom-up technique. Proteins have high affinity to carbon nanotubes due to their diversity of amino acids being hydrophobic or hydrophilic. Polysaccharides have been successfully been used to modify carbon nanotubes forming stable hybrids. To make carbon nanotubes soluble in water, phospholipids such as lysoglycerophospholipids have been used. The single phospholipid tail wraps around the carbon nanotube, but the double tailed phospholipids did not have the same ability.