What was the first instrument used to measure time?
History of timekeeping devices
obelisks
The  Egyptians divided the day into two 12-hour periods, and used large obelisks to track the movement of the sun. They also developed water clocks, which were probably first used in the Precinct of Amun-Re, and later outside Egypt as well; they were employed frequently by the Ancient Greeks, who called them clepsydrae. The Zhou dynasty is believed to have used the outflow water clock around the same time, devices which were introduced from Mesopotamia as early as 2000BC.