Hierarchical Li4Ti5O12/TiO2 composite tubes with regular structural imperfection for lithium ion storage
Hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes composed of ultrathin nanoflakes have been successfully fabricated via the calcination of the hydrothermal product of a porous amorphous TiO 2 precursor and lithium hydroxide monohydrate. The hierarchical tubes are characterized by powder X-ray diffraction, nitrogen adsorption/ desorption, scanning electron microscopy and transmission electron microscopy techniques. These nanoflakes exhibit a quite complex submicroscopic structure with regular structural imperfection, including a huge number of grain boundaries and dislocations. The lithium ion storage property of these tubes is evaluated by galvanostatic discharge/charge experiment. The product shows initial discharge capacities of 420, 225, and 160 mAh g 21 at 0.01, 0.1, and 1.0 A g 21 , respectively. After 100 cycles, the discharge capacity is 139 mAh g 21 at 1.0 A g 21 with a capacity retention of 87%, demonstrating good high-rate performance and good cycleability. The high electrochemical performance is attributed to unique structure and morphology of the tubes. The regular structural imperfection existed in the nanoflakes also benefit to lithium ion storage property of these tubes. The hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes are a promising anode material for lithium-ion batteries with high power and energy densities. Rechargeable lithium ion batteries have been successfully adopted as power sources for portable electronic devices because of their high energy density and long cycle life 1 , whereas the practical application of lithium ion batteries to (hybrid) electric vehicles and stationary electric energy storage largely depends on the electrochemical performance of the electrode materials, such as large specific capacities, high rate capability and good cycling stability. It is envisaged that the introduction of a nanostructure and the increase of crystallographic defect concentration and grain boundary (GB) density are feasible strategies to improve the electrochemical performance of electrode materials. Nanostructured materials with small particle size and large specific surface area can provide relatively shortened mass and charge transport pathways and charming surface activities, resulting in enhanced rate capabilities 2 . The research on structural imperfection derived from crystallographic defects is a very active and rapidly developing area in solid-state chemistry 3 . Crystallographic defects can bring forth rich structural chemistry and unexpected properties to the crystalline materials. For example, the smooth mass transfer in a solid-state reaction can be achieved only when the reactants have certain defect concentration. Oxygen-deficient ferrites with a spinel structure can efficiently decompose CO 2 into carbon through the transfer of oxygen to the oxygen vacancies 4 . The presence of defects in the crystal structures may enhance the lithium ion transport properties and electronic conductivity of the electrode materials [5][6][7][8][9][10][11][12][13] . Therefore, it is promising to enhance the rate performance of lithium ion batteries to a great extent by introducing defects to the electrode materials.A large number of lithium ions can be stored on the interfacial area of the nanostructured materials with a high grain boundary density, increasing the specific capacities of these materials 14,15 . It is of interest that the capacity introduced by the interfacial lithium storage is almost independent on the charge-discharge rate due to its thermodynamic characteristics 16,17 . Dual-and multi-phase materials are expected to provide increased grain boundary density. Recently, the interface in dual-phase Li 4 Ti 5 O 12 /TiO 2 materials is demonstrated to be superior for storing the extra lithium [18][19][20][21] .Herein, the synergistic effect of nanostructure, crystallographic defect and grain boundary on the lithium ion storage properties of electrode materials is observed for dual-phase hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes prepared via the calcination of a lithium titanium oxide hydrate, which is the hydrothermal product of a porous amorphous TiO 2 precursor and lithium hydroxide monohydrate. The hierarchical tubes are composed of ultrathin nanoflakes with an ordered defect structure. Plenty of grain boundaries are present within the Li 4 Ti 5 O 12 crystallites,
<!>Results<!>Preparation of hierarchical
<p>and among Li 4 Ti 5 O 12 and TiO 2 crystallites in the nanoflakes. These hierarchical tubes exhibit large reversible capacities and good cycling performance.</p><!><p>The X-ray diffraction (XRD) pattern of the produced tubes is shown in Figure 1a The broadened peaks located at 18.44u, 35.59u, 43.40u, and 62.92u can be readily indexed to the (111), (311), (400), and (440) diffractions, respectively, of Li 4 Ti 5 O 12 with a cubic spinel structure (JCPDS No. 49-0207). The additional peaks at 25.34u, 38.03u, 47.99u, 54.25u, and 55.04u are ascribed to the (101), (004), ( 200), (105), and (211) diffractions, respectively, of anatase TiO 2 (JCPDS No. 21-1272). The XRD analysis indicates that both spinel Li 4 Ti 5 O 12 and anatase TiO 2 exist in the sample obtained, generating a dual-phase Li 4 Ti 5 O 12 /TiO 2 composite material. The anatase TiO 2 may arise from the crystallization of residual amorphous titania surviving the hydrothermal treatment. The content of spinel Li 4 Ti 5 O 12 in the composite is approximately 64 wt% based on the XRD analysis. The morphology of the Li 4 Ti 5 O 12 /TiO 2 composite is revealed by SEM and TEM observation (Figure 1b, c). The Li 4 Ti 5 O 12 /TiO 2 exhibits a tube-like morphology assembled by interleaving ultrathin nanoflakes. The diameter of the tubes ranges from 0.5 to 2.0 mm with a length of 5-20 mm. The nanoflakes with a smooth surface are approximately 1 mm in length and 200-400 nm in width. As observed in the TEM image, plenty of void space exists among the nanoflakes, forming a three-dimensional (3D) channel system which facilitates the transportation of the electrolyte and lithium ions. The inner side of the nanoflakes is fused together to form the wall of the tubes, ensuring the good electronic contact of these flakes.</p><p>Figure 2 shows further structural feature of the hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes. A schematic illustration of the individual nanoflake is drawn to show the regions revealed by the HRTEM observation (Figure 2a). The HRTEM image of the nanoflake taken in region I clearly exhibits a periodic arrangement of fringes with an average distance of approximately 1.7 nm, obviously larger than the lattice fringe spacings of Li 4 Ti 5 O 12 and TiO 2 (Figure 2b). The latticefringe-like periodic pattern is believed to be derived from defects, demonstrating the regular structural imperfection of these nanoflakes. However, the corresponding selected area electron diffraction (SAED) (inset in Figure 2b) along the [011] zone axis (perpendicular to the nanoflake surface) exhibits a series of spot pattern, characteristic for a single-crystal-like structure. All of the diffraction spots can be well indexed to the spinel Li 4 Ti 5 O 12 with a cubic structure in which the direction [hkl] is perpendicular to the (hkl) plane. Therefore, it can be concluded that the Li 4 Ti 5 O 12 nanoflakes are bound by (011) facets on both the top and bottom surfaces. The HRTEM images (Figure 2c, d) of the nanoflake in region I and II are taken along the direction that almost parallels with the nanoflake plane. As shown in Figure 2c, the lattice fringes with a spacing of 0.50 nm attributing to the (111) plane of spinel Li 4 Ti 5 O 12 with a lattice fluctuation are clearly observed. A careful examination of the HRTEM image indicates that structural imperfection is derived from the interlacing of two or three closely packed parallel (111) planes. This layer-by-layer-like stacking can be clearly observed in the TEM images viewing along or perpendicular to the surface of the nanoflakes (Figure 2d, e). The interlayer spacing of the lattice-fringelike structural imperfection is approximately 1.7 nm, consistent with that observed in Figure 2b. For a cubic structure, the dihedral angle between the (111) planes is 70.5u. Distinct lattice fringes with a distance of approximately 0.48 nm are observed, corresponding to the (111) planes of spinel Li 4 Ti 5 O 12 (Figure 2e). The angle between these lattice fringes is approximately 70.5u, consistent with the cubic structure of Li 4 Ti 5 O 12 . It is interesting that plenty of grain boundaries exist among the crystalline domains in the nanoflakes (Figure 2f).   The textural feature of the hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes is characterized by nitrogen adsorption/desorption measurements (Supplementary Figure 1). The isotherms are identified as of type IV with an H3 hysteresis loop, indicating the presence of slit-like pores. This is consistent with the SEM and TEM observation. A hysteresis loop with a sharp capillary condensation is presented at a relative pressure of 0.80 to 0.97, which is due to the existence of macroporous structures. The pore size distribution shows feature characteristic for hierarchical materials. The specific Brunauer-Emmett-Teller (BET) surface area and the pore volume are determined to be 107 m 2 g 21 and 0.52 cm 3 g 21 , respectively.</p><p>Cyclic voltammetry (CV) was used to investigate the electrochemical behavior of the hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes with regular structural imperfection. Figure 3 shows the CV curves of the hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes at a scan rate of 0.2 mV s 21 in the potential range from 2.5 to 1.0 V. In the first cycle, three pairs of peaks were observed. Two pairs of cathodic/anodic peaks located at 1.43/1.65 V, and 1.64/2.06 V versus Li 1 /Li are associated with lithium ion insertion/extraction within the spinel Li 4 Ti 5 O 12 and anatase TiO 2 lattices, respectively. An extraordinary pair of peaks located at 1.27/1.78 V versus Li 1 /Li are distinctly observed, denoted as S peaks. It is generally accepted that the S peaks are related to the surface-confined charge-transfer processes with the presence of amorphous phase in the organized skeleton 22,23 . The S peaks have been well documented in the literature to explain the electrochemical behavior of Ti-based compounds, such as TiO 2 (B) 24 , anatase 22    the discharge process, two potential plateaus at potentials of approximately 1.75 and 1.55 V are clearly observed. The first plateau at 1.75 V is ascribed to the phase transition from anatase TiO 2 to orthorhombic Li x TiO 2 upon lithium ion insertion. The plateau at 1.55 V is attributed to the generation of a rocksalt-structured Li 7 Ti 5 O 12 , resulting from the lithium ion insertion into the spinel Li 4 Ti 5 O 12 . A long sloped region observed from 1.55 to 1.0 V can be assigned to the pseudocapacitive lithium storage behavior of the Li 4 Ti 5 O 12 /TiO 2 tubes, characteristic of the electrochemical reactions involving surface-confined charge-transfer or interfacial storage processes [14][15][16]25 . At 0.01 A/g, the discharge capacity of the first cycle can reach a high lithiation capacity of 420 mAh g 21 and a de-lithiation capacity of 315 mAh g 21  Cycling performance of the hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes at the discharge/charge current density of 0.1 and 1.0 A g 21 is shown in Figure 4b. Cycled at 0.1 A g 21 , a reversible capacity of 146 mAh g 21 is observed for the 100 th cycle, giving a capacity retention rate of approximately 65%. Cycled at a current density of 1.0 A g 21 , the hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes show a discharge capacity of 160 mAh g 21 in the first cycle. Good capacity retention is realized over extended cycling. A charge capacity of 139 mAh g 21 , approximately 87% of its initial charge capacity is retained after 100 cycles. After 800 cycles, the discharge capacity of the hierarchical Li 4 Ti 5 O 12 / TiO 2 tubes is still of 134 mAh g 21 (Supplementary Figure 2b). The cycling stability for the hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes at a large current density is distinctly superior to those for the related composite materials described in the literature [18][19][20][21] . Thus, the high cycling stability of the Li 4 Ti 5 O 12 /TiO 2 tubes is mainly ascribed to their unique hierarchical tubular structure built up by thin nanoflakes.</p><p>The high specific capacity, good cycleability of the hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes constructed by nanoflakes are attributed to the synergistic effect of the hierarchical nanostructure, the ordered fringe-like crystallographic defect and the large number of grain boundaries among the spinel Li 4 Ti 5 O 12 and anatase TiO 2 nanocrystals. First, the 3D porous channel system of the composite material facilitates the transport of electrolyte and lithium ions within the electrode and the small thickness of the nanoflakes shortens the diffusion distance for both electron and lithium ions. Second, the fringe-like structural imperfection, abundant grain boundaries and phase interfaces in the hierarchical Li 4 Ti 5 O 12 /TiO 2 composite favor the storage of extra lithium ions, increasing the specific capacity of the composite material. In addition, the abundant phase interfaces are also favorable for the fast electrochemical lithium-ion insertion and extraction processes, improving the kinetics of the electrode. Third, the tubular structure and thin nanoflakes effectively buffer the stress induced during the discharge/charge process, contributing to the cycling performance improvement of the composite. Because of these structural features, the hierarchical Li 4 Ti 5 O 12 /TiO 2 composite exhibits large specific capacities and good cycling stability.</p><p>In summary, hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes composed of nanoflakes have been successfully fabricated through the conversion of a lithium titanium oxide hydrate upon calcination at 400uC. The structural imperfection formed in the nanoflakes during the phase transformation from lithium titanium oxide hydrate to spinel Li 4 Ti 5 O 12 has proved to be advantageous for lithium ion storage of these tubes. The obtained hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes exhibit a high initial discharge capacity of 420 mAh g 21 at 0.01 A g 21 . Cycling at 1.0 A g 21 , a capacity of 139 mAh g 21 is retained even after 100 cycles, indicating good cycling stability. The high electrochemical performance of the tubes is attributed to their unique nanostructure, including the 3D porous channel system, the structural imperfection in Li 4 Ti 5 O 12 nanoflakes and the high grain boundary density among the nanoparticles. The 3D porous channel system facilitates the mass transport of the electrolyte and lithium ions and provides sufficient void space to accommodate the volume change during the discharge/ charge process, ensuring the good cycling performance. Such elaborate combination of crystal structure and architectural mode could be helpful for designing new high rate composite electrodes.  (Supplementary Figure 3a-b). A mixture of the amorphous titania (240 mg, 3.00 mmol) and lithium hydroxide monohydrate (111 mg, 2.65 mmol) was added to 24 mL of ditilled water with continuous stirring. The obtained suspension was transferred into a 30 mL Teflon-lined stainless-steel autoclave, which was then heated at 130uC for 7 d. The white precipitate of layered hydrous lithium titanate was collected by filtration, washed with ethanol thoroughly, and dried naturally at room temperature (Supplementary Figure 3c-d). The final product of hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes was generated by the calcination of the layered hydrous lithium titanate at 400uC for 1.5 h.</p><!><p>Characterization. Powder X-ray diffraction (XRD) patterns were recorded on a Rigaku Dmax-2200 diffractometer (Rigaku, Japan) with Cu Ka radiation (l 5 1.5418 A ˚). The morphology of the sample was observed with a scanning electron microscope (SEM, JSM-7401F, JEOL, Japan). The microstructure of the sample was characterized by using transmission electron microscope (TEM, JEM-2100F, JEOL, Japan) and high resolution transmission electron microscope (HRTEM, JEM-2100F, JEOL, Japan), operating at 200 kV. The specific surface areas of the samples were measured on a Micromeritics ASAP 2010 M 1 C nitrogen adsorption instrument (Micrometritices Inc., USA) at 77 K.</p><p>Electrochemical properties of the hierarchical Li 4 Ti 5 O 12 /TiO 2 tubes were evaluated with CR2016 coin cells. The working electrode was prepared on an aluminum foil by using a doctor-blade method with a slurry composed of 75 wt.% active materials (TiO 2 ), 15 wt.% conductivity agent (acetylene black), and 10 wt.% binder (polyvinylidene fluoride, PVDF). Lithium metal foil was used as both the counter and reference electrodes. A microporous polypropylene membrane (Celgard 2500) was used as the separator. Coin cells were assembled in an argon filled glove box with both moisture and oxygen contents below 1.0 ppm. The electrolyte was 1.0 M of LiClO 4 in ethylene carbonate/dimethyl carbonate (EC/DEC, 151 by volume). The galvanostatic charge and discharge experiment was performed with a battery tester LAND-CT2001A in the voltage range of 1.0-2.5 V at room temperature. Cyclic voltammograms (CV) measurement was conducted by using an electrochemical cell with a three-electrode configuration. Li metal foil was selected as the reference and counter electrode. The electrolyte was 1 M LiClO 4 in ethylene carbonate/dimethyl carbonate (EC/DEC, 151 by volume). The cyclic voltammograms (CV) were conducted on a CHI 660B electrochemical workstation at a scanning rate of 0.2 mV s 21 in a potential range of 2.5-1.0 V (vs Li 1 /Li).</p>