The emission wavelength can be lowered by substituting the anthracene core by halogens or alkyls. Free alkyls occur as neutral compounds, as anions, or as cations. Many homogeneous catalysts operate via the intermediacy of metal alkyls. Mixed ligand, or heteroleptic, complexes containing alkyls are numerous. They are mixture of different alkyls as the term implies, e.g. sodium lauryl sulfate. Alkyls are commonly observed in mass spectrometry of organic compounds. These are related to the superbases which are mixtures of metal alkoxides and alkyls. The simplest organozirconium compounds are the homoleptic alkyls. Large amount of TEAL and related aluminium alkyls are used in Ziegler-Natta catalysis. The Shilov system involves platinum based complexes to produce metal alkyls. The compound also reacts easily with metal alkyls. In MOCVD, group III alkyls are already partially dissociated in the gas stream. On a smaller scale, ethyltoluene, ethylanilines, 1,4-hexadiene, and aluminium alkyls.